-
1
-
-
0037391206
-
Current mechanistic understanding of thiamin diphosphate-dependent enzymatic reactions
-
A very good overview of the state-of-the-art in catalysis and mechanisms of ThDP-dependent enzymes.
-
Jordan F. Current mechanistic understanding of thiamin diphosphate-dependent enzymatic reactions. Nat Prod Rep. 20:2003;184-201 A very good overview of the state-of-the-art in catalysis and mechanisms of ThDP-dependent enzymes.
-
(2003)
Nat Prod Rep
, vol.20
, pp. 184-201
-
-
Jordan, F.1
-
2
-
-
0042628455
-
Thiamin-diphosphate-dependent enzymes: New aspects of asymmetric C-C bond formation
-
Comprises recent advances in enzymatic asymmetric carboligation and provides an outlook on further ThDP-dependent enzymes, which could potentially be useful for asymmetric synthesis but require more detailed characterization.
-
Pohl M., Lingen B., Müller M. Thiamin-diphosphate-dependent enzymes: new aspects of asymmetric C-C bond formation. Chemistry. 8:2002;5288-5295 Comprises recent advances in enzymatic asymmetric carboligation and provides an outlook on further ThDP-dependent enzymes, which could potentially be useful for asymmetric synthesis but require more detailed characterization.
-
(2002)
Chemistry
, vol.8
, pp. 5288-5295
-
-
Pohl, M.1
Lingen, B.2
Müller, M.3
-
3
-
-
3543141561
-
Thiamine-dependent enzymes as catalysts of C-C bonding reactions: The role of 'orphan' enzymes.
-
Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.;
-
Müller M, Sprenger GA: Thiamine-dependent enzymes as catalysts of C-C bonding reactions: the role of 'orphan' enzymes. In Thiamine: Catalytic Mechanisms in Normal and Disease States. Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.; 2004:77-92.
-
(2004)
Thiamine: Catalytic Mechanisms in Normal and Disease States
, pp. 77-92
-
-
Müller, M.1
Sprenger, G.A.2
-
4
-
-
3543127490
-
Structure of the α-carbanion/enamine reaction intermediate in the active site of transketolase, determined by kinetic crystallography
-
Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.;
-
Sandalova T, Fiedler E, Thorell S, Golbik R, König S, Schneider G: Structure of the α-carbanion/enamine reaction intermediate in the active site of transketolase, determined by kinetic crystallography. In Thiamine: Catalytic Mechanisms in Normal and Disease States. Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.; 2004:159-172.
-
(2004)
Thiamine: Catalytic Mechanisms in Normal and Disease States
, pp. 159-172
-
-
Sandalova, T.1
Fiedler, E.2
Thorell, S.3
Golbik, R.4
König, S.5
Schneider, G.6
-
5
-
-
3543094854
-
Exploring the substrate specificity of benzoylformate decarboxylase, pyruvate decarboxylase, and benzaldehyde lyase
-
Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.;
-
Siegert P, Pohl M, Keen MM, Pogozheva ID, Kenyon GL, McLeish MJ: Exploring the substrate specificity of benzoylformate decarboxylase, pyruvate decarboxylase, and benzaldehyde lyase. In Thiamine: Catalytic Mechanisms in Normal and Disease States. Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.; 2004:275-290.
-
(2004)
Thiamine: Catalytic Mechanisms in Normal and Disease States
, pp. 275-290
-
-
Siegert, P.1
Pohl, M.2
Keen, M.M.3
Pogozheva, I.D.4
Kenyon, G.L.5
McLeish, M.J.6
-
6
-
-
0037687314
-
Crystal structure of thiamindiphosphate-dependent indolepyruvate decarboxylase from Enterobacter cloacae, an enzyme involved in the biosynthesis of the plant hormone indole-3-acetic acid
-
Schütz A., Sandalova T., Ricagno S., Hübner G., König S., Schneider G. Crystal structure of thiamindiphosphate-dependent indolepyruvate decarboxylase from Enterobacter cloacae, an enzyme involved in the biosynthesis of the plant hormone indole-3-acetic acid. Eur J Biochem. 270:2003;2312-2321
-
(2003)
Eur J Biochem
, vol.270
, pp. 2312-2321
-
-
Schütz, A.1
Sandalova, T.2
Ricagno, S.3
Hübner, G.4
König, S.5
Schneider, G.6
-
7
-
-
0038025249
-
Studies on structure-function relationships of indolepyruvate decarboxylase from Enterobacter cloacae, a key enzyme of the indole acetic acid pathway
-
Schütz A., Golbik R., Tittmann K., Svergun D.I., Koch M.H., Hübner G., König S. Studies on structure-function relationships of indolepyruvate decarboxylase from Enterobacter cloacae, a key enzyme of the indole acetic acid pathway. Eur J Biochem. 270:2003;2322-2331
-
(2003)
Eur J Biochem
, vol.270
, pp. 2322-2331
-
-
Schütz, A.1
Golbik, R.2
Tittmann, K.3
Svergun, D.I.4
Koch, M.H.5
Hübner, G.6
König, S.7
-
8
-
-
0042029541
-
Identification and characterization of phenylpyruvate decarboxylase genes in Saccharomyces cerevisiae
-
Vuralhan Z., Morais M.A., Tai S.L., Piper M.D., Pronk J.T. Identification and characterization of phenylpyruvate decarboxylase genes in Saccharomyces cerevisiae. Appl Environ Microbiol. 69:2003;4534-4541
-
(2003)
Appl Environ Microbiol
, vol.69
, pp. 4534-4541
-
-
Vuralhan, Z.1
Morais, M.A.2
Tai, S.L.3
Piper, M.D.4
Pronk, J.T.5
-
9
-
-
0344754095
-
Structural and kinetic analysis of catalysis by a thiamin diphosphate-dependent enzyme, benzoylformate decarboxylase
-
Polovnikova E.S., McLeish M.J., Sergienko E.A., Burgner J.T., Anderson N.L., Bera A.K., Jordan F., Kenyon G.L., Hasson M.S. Structural and kinetic analysis of catalysis by a thiamin diphosphate-dependent enzyme, benzoylformate decarboxylase. Biochemistry. 42:2003;1820-1830
-
(2003)
Biochemistry
, vol.42
, pp. 1820-1830
-
-
Polovnikova, E.S.1
McLeish, M.J.2
Sergienko, E.A.3
Burgner, J.T.4
Anderson, N.L.5
Bera, A.K.6
Jordan, F.7
Kenyon, G.L.8
Hasson, M.S.9
-
10
-
-
0142103330
-
The phosphonopyruvate decarboxylase from Bacteroides fragilis
-
Zhang G., Dai J., Lu Z., Dunaway-Mariano D. The phosphonopyruvate decarboxylase from Bacteroides fragilis. J Biol Chem. 278:2003;41302-41308
-
(2003)
J Biol Chem
, vol.278
, pp. 41302-41308
-
-
Zhang, G.1
Dai, J.2
Lu, Z.3
Dunaway-Mariano, D.4
-
11
-
-
0033893841
-
Identification of the gene encoding sulfopyruvate decarboxylase, an enzyme involved in biosynthesis of coenzyme M
-
Graupner M., Xu H., White R.H. Identification of the gene encoding sulfopyruvate decarboxylase, an enzyme involved in biosynthesis of coenzyme M. J Bacteriol. 182:2000;4862-4867
-
(2000)
J Bacteriol
, vol.182
, pp. 4862-4867
-
-
Graupner, M.1
Xu, H.2
White, R.H.3
-
12
-
-
0037870806
-
Increased pyruvate efficiency in enzymatic production of (R)-phenylacetylcarbinol
-
Rosche B., Breuer M., Hauer B., Rogers P.L. Increased pyruvate efficiency in enzymatic production of (R)-phenylacetylcarbinol. Biotechnol Lett. 25:2003;847-851
-
(2003)
Biotechnol Lett
, vol.25
, pp. 847-851
-
-
Rosche, B.1
Breuer, M.2
Hauer, B.3
Rogers, P.L.4
-
13
-
-
0037629044
-
Screening of yeasts for cell-free production of (R)-phenylacetylcarbinol
-
Rosche B., Breuer M., Hauer B., Rogers P.L. Screening of yeasts for cell-free production of (R)-phenylacetylcarbinol. Biotechnol Lett. 25:2003;841-845
-
(2003)
Biotechnol Lett
, vol.25
, pp. 841-845
-
-
Rosche, B.1
Breuer, M.2
Hauer, B.3
Rogers, P.L.4
-
14
-
-
18144450522
-
Enhanced production of R-phenylacetylcarbinol (R-PAC) through enzymatic biotransformation
-
Rosche B., Sandford V., Breuer M., Hauer B., Rogers P.L. Enhanced production of R-phenylacetylcarbinol (R-PAC) through enzymatic biotransformation. J Molec Catal B-Enzymatic. 19:2002;109-115
-
(2002)
J Molec Catal B-Enzymatic
, vol.19
, pp. 109-115
-
-
Rosche, B.1
Sandford, V.2
Breuer, M.3
Hauer, B.4
Rogers, P.L.5
-
15
-
-
0037120881
-
Development of a donor-acceptor concept for enzymatic cross-coupling reactions of aldehydes: The first asymmetric cross-benzoin condensation
-
Describes the donor-acceptor concept for catalytic asymmetric cross-benzoin condensation, which has been applied to other enzymatic and non-enzymatic acyl anion transformations.
-
Dünkelmann P., Kolter-Jung D., Nitsche A., Demir A.S., Siegert P., Lingen B., Baumann M., Pohl M., Müller M. Development of a donor-acceptor concept for enzymatic cross-coupling reactions of aldehydes: the first asymmetric cross-benzoin condensation. J Am Chem Soc. 124:2002;12084-12085 Describes the donor-acceptor concept for catalytic asymmetric cross-benzoin condensation, which has been applied to other enzymatic and non-enzymatic acyl anion transformations.
-
(2002)
J Am Chem Soc
, vol.124
, pp. 12084-12085
-
-
Dünkelmann, P.1
Kolter-Jung, D.2
Nitsche, A.3
Demir, A.S.4
Siegert, P.5
Lingen, B.6
Baumann, M.7
Pohl, M.8
Müller, M.9
-
16
-
-
39649098799
-
Enantioselective synthesis of hydroxyketones via benzaldehyde lyase and benzoylformate decarboxylase catalyzed C-C bond formation
-
Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.;
-
Lingen B, Pohl M, Liese A, Demir AS, Müller M: Enantioselective synthesis of hydroxyketones via benzaldehyde lyase and benzoylformate decarboxylase catalyzed C-C bond formation. In Thiamine: Catalytic Mechanisms in Normal and Disease States. Edited by Jordan F, Patel MS. New York: Marcel Dekker, Inc.; 2004:113-130.
-
(2004)
Thiamine: Catalytic Mechanisms in Normal and Disease States
, pp. 113-130
-
-
Lingen, B.1
Pohl, M.2
Liese, A.3
Demir, A.S.4
Müller, M.5
-
17
-
-
0041977179
-
Alteration of the substrate specificity of benzoylformate decarboxylase from Pseudomonas putida by directed evolution
-
Lingen B., Kolter-Jung D., Dünkelmann P., Feldmann R., Grötzinger J., Pohl M., Müller M. Alteration of the substrate specificity of benzoylformate decarboxylase from Pseudomonas putida by directed evolution. ChemBioChem. 4:2003;721-726
-
(2003)
ChemBioChem
, vol.4
, pp. 721-726
-
-
Lingen, B.1
Kolter-Jung, D.2
Dünkelmann, P.3
Feldmann, R.4
Grötzinger, J.5
Pohl, M.6
Müller, M.7
-
18
-
-
0347717810
-
The crystal structures of Klebsiella pneumoniae acetolactate synthase with enzyme-bound cofactor and with an unusual intermediate
-
Describes a new ThDP intermediate and suggests a novel mechanism for ALS catalysis related to a non-planar thiazolium ring.
-
Pang S.S., Duggleby R.G., Schowen R.L., Guddat L.W. The crystal structures of Klebsiella pneumoniae acetolactate synthase with enzyme-bound cofactor and with an unusual intermediate. J Biol Chem. 279:2004;2242-2253 Describes a new ThDP intermediate and suggests a novel mechanism for ALS catalysis related to a non-planar thiazolium ring.
-
(2004)
J Biol Chem
, vol.279
, pp. 2242-2253
-
-
Pang, S.S.1
Duggleby, R.G.2
Schowen, R.L.3
Guddat, L.W.4
-
19
-
-
0037707718
-
Systematic characterization of mutations in yeast acetohydroxyacid synthase. Interpretation of herbicide-resistance data
-
Duggleby R.G., Pang S.S., Yu H., Guddat L.W. Systematic characterization of mutations in yeast acetohydroxyacid synthase. Interpretation of herbicide-resistance data. Eur J Biochem. 270:2003;2895-2904
-
(2003)
Eur J Biochem
, vol.270
, pp. 2895-2904
-
-
Duggleby, R.G.1
Pang, S.S.2
Yu, H.3
Guddat, L.W.4
-
20
-
-
0036295208
-
Crystal structure of yeast acetohydroxyacid synthase: A target for herbicidal inhibitors
-
Pang S.S., Duggleby R.G., Guddat L.W. Crystal structure of yeast acetohydroxyacid synthase: a target for herbicidal inhibitors. J Mol Biol. 317:2002;249-262
-
(2002)
J Mol Biol
, vol.317
, pp. 249-262
-
-
Pang, S.S.1
Duggleby, R.G.2
Guddat, L.W.3
-
21
-
-
0042932500
-
Acetohydroxyacid synthase: A new enzyme for chiral synthesis of R-phenylacetylcarbinol
-
Describes a hitherto unknown ability of AHAS to use benzaldehyde as an acceptor for carboligation. This paper is a very good illustration of our opinion that classification of enzymes according to certain activities should not restrict the view on alternative reactions.
-
Engel S., Vyazmensky M., Geresh S., Barak Z., Chipman D.M. Acetohydroxyacid synthase: a new enzyme for chiral synthesis of R-phenylacetylcarbinol. Biotechnol Bioeng. 83:2003;833-840 Describes a hitherto unknown ability of AHAS to use benzaldehyde as an acceptor for carboligation. This paper is a very good illustration of our opinion that classification of enzymes according to certain activities should not restrict the view on alternative reactions.
-
(2003)
Biotechnol Bioeng
, vol.83
, pp. 833-840
-
-
Engel, S.1
Vyazmensky, M.2
Geresh, S.3
Barak, Z.4
Chipman, D.M.5
-
22
-
-
0141519562
-
Benzaldehyde lyase-catalyzed enantioselective carboligation of aromatic aldehydes with mono- and dimethoxy acetaldehyde
-
Demir A.S., Sesenoglu O., Dünkelmann P., Müller M. Benzaldehyde lyase-catalyzed enantioselective carboligation of aromatic aldehydes with mono- and dimethoxy acetaldehyde. Org Lett. 5:2003;2047-2050
-
(2003)
Org Lett
, vol.5
, pp. 2047-2050
-
-
Demir, A.S.1
Sesenoglu, O.2
Dünkelmann, P.3
Müller, M.4
-
23
-
-
0242526077
-
Mixed aromatic acyloin condensations with recombinant benzaldehyde lyase: Synthesis of α-hydroxydihydrochalcones and related α-hydroxy ketones
-
Sanches-Gonzalez M., Rosazza J.P.N. Mixed aromatic acyloin condensations with recombinant benzaldehyde lyase: synthesis of α- hydroxydihydrochalcones and related α-hydroxy ketones. Adv Synth Catal. 345:2003;819-824
-
(2003)
Adv Synth Catal
, vol.345
, pp. 819-824
-
-
Sanches-Gonzalez, M.1
Rosazza, J.P.N.2
-
24
-
-
0345686436
-
Steady-state kinetics and molecular evolution of Escherichia coli MenD [(1R,6R)-2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase], an anomalous thiamin diphosphate-dependent decarboxylase-carboligase
-
Bhasin M., Billinsky J.L., Palmer D.R. Steady-state kinetics and molecular evolution of Escherichia coli MenD [(1R,6R)-2-succinyl-6-hydroxy-2,4- cyclohexadiene-1-carboxylate synthase], an anomalous thiamin diphosphate-dependent decarboxylase-carboligase. Biochemistry. 42:2003;13496-13504
-
(2003)
Biochemistry
, vol.42
, pp. 13496-13504
-
-
Bhasin, M.1
Billinsky, J.L.2
Palmer, D.R.3
-
25
-
-
0037019628
-
A highly enantioselective catalytic intramolecular Stetter reaction
-
Kerr M.S., de Alaniz J.R., Rovis T. A highly enantioselective catalytic intramolecular Stetter reaction. J Am Chem Soc. 124:2002;10298-10299
-
(2002)
J Am Chem Soc
, vol.124
, pp. 10298-10299
-
-
Kerr, M.S.1
De Alaniz, J.R.2
Rovis, T.3
-
26
-
-
1542375011
-
The thiazolium-catalyzed Sila-Stetter reaction: Conjugate addition of acylsilanes to unsaturated esters and ketones
-
Mattson A.E., Bharadwaj A.R., Scheidt K.A. The thiazolium-catalyzed Sila-Stetter reaction: conjugate addition of acylsilanes to unsaturated esters and ketones. J Am Chem Soc. 126:2002;2314-2315
-
(2002)
J Am Chem Soc
, vol.126
, pp. 2314-2315
-
-
Mattson, A.E.1
Bharadwaj, A.R.2
Scheidt, K.A.3
-
27
-
-
0032545041
-
Biosynthesis of yersiniose: Attachment of the two-carbon branched-chain is catalyzed by a thiamine pyrophosphate-dependent flavoprotein
-
Chen H., Guo Z., Liu H-W. Biosynthesis of yersiniose: attachment of the two-carbon branched-chain is catalyzed by a thiamine pyrophosphate-dependent flavoprotein. J Am Chem Soc. 120:1998;11796-11797
-
(1998)
J Am Chem Soc
, vol.120
, pp. 11796-11797
-
-
Chen, H.1
Guo, Z.2
Liu, H.-W.3
-
28
-
-
0038375618
-
Catalytic intramolecular crossed aldehyde-ketone benzoin reaction: A novel synthesis of functionalized preanthraquinones
-
Hachisu Y., Bode J.W., Suzuki K. Catalytic intramolecular crossed aldehyde-ketone benzoin reaction: a novel synthesis of functionalized preanthraquinones. J Am Chem Soc. 125:2003;8432-8433
-
(2003)
J Am Chem Soc
, vol.125
, pp. 8432-8433
-
-
Hachisu, Y.1
Bode, J.W.2
Suzuki, K.3
-
29
-
-
0037063549
-
Kanosamine biosynthesis: A likely source of the aminoshikimate pathway's nitrogen atom
-
Guo J., Frost J.W. Kanosamine biosynthesis: a likely source of the aminoshikimate pathway's nitrogen atom. J Am Chem Soc. 124:2002;10642-10643
-
(2002)
J Am Chem Soc
, vol.124
, pp. 10642-10643
-
-
Guo, J.1
Frost, J.W.2
-
30
-
-
2942611657
-
Catalyzed reactions of acyl anion equivalents
-
Johnson J. Catalyzed reactions of acyl anion equivalents. Angew Chem Int Ed Engl. 43:2004;1326-1328
-
(2004)
Angew Chem Int Ed Engl
, vol.43
, pp. 1326-1328
-
-
Johnson, J.1
-
31
-
-
0036801379
-
New reactions in clavulanic acid biosynthesis
-
Townsend C.A. New reactions in clavulanic acid biosynthesis. Curr Opin Chem Biol. 6:2002;583-589
-
(2002)
Curr Opin Chem Biol
, vol.6
, pp. 583-589
-
-
Townsend, C.A.1
-
33
-
-
0037440030
-
Sulphoacetaldehyde acetyltransferase yields acetyl phosphate: Purification from Alcaligenes defragrans and gene clusters in taurine degradation
-
Ruff J., Denger K., Cook A.M. Sulphoacetaldehyde acetyltransferase yields acetyl phosphate: purification from Alcaligenes defragrans and gene clusters in taurine degradation. Biochem J. 369:2003;275-285
-
(2003)
Biochem J
, vol.369
, pp. 275-285
-
-
Ruff, J.1
Denger, K.2
Cook, A.M.3
-
35
-
-
0037010723
-
Fructose 6-phosphate aldolase and 1-deoxy-D-xylulose 5-phosphate synthase from Escherichia coli as tools in enzymatic synthesis of 1-deoxysugars
-
Schürmann M., Sprenger G.A. Fructose 6-phosphate aldolase and 1-deoxy-D-xylulose 5-phosphate synthase from Escherichia coli as tools in enzymatic synthesis of 1-deoxysugars. J Molec Catal B-Enzymatic. 19:2002;247-252
-
(2002)
J Molec Catal B-Enzymatic
, vol.19
, pp. 247-252
-
-
Schürmann, M.1
Sprenger, G.A.2
-
36
-
-
0035930716
-
Crystal structure of the free radical intermediate of pyruvate: Ferredoxin oxidoreductase
-
Chabriere E., Vernede C., Guigliarelli B., Charon M.H., Hatchikian E.C., Fontecilla-Camps J.C. Crystal structure of the free radical intermediate of pyruvate: ferredoxin oxidoreductase. Science. 294:2001;2559-2563
-
(2001)
Science
, vol.294
, pp. 2559-2563
-
-
Chabriere, E.1
Vernede, C.2
Guigliarelli, B.3
Charon, M.H.4
Hatchikian, E.C.5
Fontecilla-Camps, J.C.6
-
38
-
-
0000430035
-
A novel asymmetriv benzoin reaction catalyzed by a chiral triazolium salt
-
Enders D., Breuer K., Teles J.H. A novel asymmetriv benzoin reaction catalyzed by a chiral triazolium salt. Helv Chim Acta. 79:1996;1217-1221
-
(1996)
Helv Chim Acta
, vol.79
, pp. 1217-1221
-
-
Enders, D.1
Breuer, K.2
Teles, J.H.3
-
39
-
-
0036263823
-
An efficient nucleophilic carbene catalyst for the asymmetric benzoin condensation
-
Describes the application of a triazolium precatalyst, resulting in the formation of highly enantioenriched (S)-acyloins.
-
Enders D., Kallfass U. An efficient nucleophilic carbene catalyst for the asymmetric benzoin condensation. Angew Chem Int Ed Engl. 41:2002;1743-1745 Describes the application of a triazolium precatalyst, resulting in the formation of highly enantioenriched (S)-acyloins.
-
(2002)
Angew Chem Int Ed Engl
, vol.41
, pp. 1743-1745
-
-
Enders, D.1
Kallfass, U.2
-
40
-
-
0038409903
-
Alpha-oxidation of 3-methyl-substituted fatty acids and its thiamine dependence
-
Casteels M., Foulon V., Mannaerts G.P., Van Veldhoven P.P. Alpha-oxidation of 3-methyl-substituted fatty acids and its thiamine dependence. Eur J Biochem. 270:2003;1619-1627
-
(2003)
Eur J Biochem
, vol.270
, pp. 1619-1627
-
-
Casteels, M.1
Foulon, V.2
Mannaerts, G.P.3
Van Veldhoven, P.P.4
-
41
-
-
0030630059
-
Protein design on pyruvate decarboxylase (PDC) by site-directed mutagenesis
-
Pohl M. Protein design on pyruvate decarboxylase (PDC) by site-directed mutagenesis. Adv Biochem Eng Biotechnol. 58:1997;15-43
-
(1997)
Adv Biochem Eng Biotechnol
, vol.58
, pp. 15-43
-
-
Pohl, M.1
-
42
-
-
0036885791
-
Dissimilation of the C-2 sulfonates
-
Cook A.M., Denger K. Dissimilation of the C-2 sulfonates. Arch Microbiol. 179:2002;1-6
-
(2002)
Arch Microbiol
, vol.179
, pp. 1-6
-
-
Cook, A.M.1
Denger, K.2
|