Amide-silyl ligand exchanges and equilibria among group 4 amide and silyl complexes

Inorganic Chemistry

Volumn 46, Issue 19, 2007, Pages 8071-8078

  Cai, Hu ^a,c   Yu, Xianghua ^a   Chen, Shujian ^a   Qiu, He ^a   Guzei, Ilia A ^b   Xue, Zi Ling ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

^c NANCHANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34948837821     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7010293     Document Type: Article

References (86)

1. (a) Tilley, T. D. In The Silicon-Heteroatom Bond; Patai, S., Rappoport, Z.; Eds.; Wiley: New York, 1991; p 245 and 309.
2. (b) Eisen, M. S. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1998; Vol. 2, Part 3, p 2037.
3. (c) Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175.
4. (d) Marschner, C. Organometallics 2006, 25, 2110.
5. (e) Shimada, S.; Tanaka, M. Coord. Chem. Rev. 2006, 250, 991.
6. (f) Lerner, H. W. Coord. Chem. Rev. 2005, 249, 781.
7. (g) Sharma, H. K.; Pannell, K. H. Chem. Rev. 1995, 95, 1351.
8. (h) Yu, X.; Morton, L. A.; Xue, Z. Organometallics 2004, 23, 2210.
9. (i) Xue, Z.-L. Comments Inorg. Chem. 1996, 18, 223.
10. (j) Corey, J. Y. Adv. Organomet. Chem. 2004, 51, 1.
11. (k) Gauvin, F.; Harrod, J. F.; Woo, H. G. Adv. Organomet. Chem. 1998, 42, 363.
12. (l) Ustinov, M. V.; Bravo-Zhivotoskii, D. A.; Kalikhman, I. D.; Vitkovskii, V. Y.; Vyazankin, N. S.; Voronkov, M. G. Organomet. Chem. USSR 1989, 2, 664.
13. (a) Colomer, E.; Corriu, R. J. P. J. Organomet. Chem. 1977, 133, 159.
14. (b) Corriu, R. J. P.; Guerin, C. Adv. Organomet. Chem. 1982, 20, 265.
15. (a) Moedritzer, K. Organomet. React. 1971, 2, 1.
16. (b) Harrod, J. F. Coord. Chem. Rev. 2000, 206-207, 493.
17. (c) Edwards, D. A. Organomet. Chem. 1986, 14, 196.
18. (d) Lubben, T. V.; Wolczanski, P. T. J. Am. Chem. Soc. 1987, 109, 424.
19. (e) Bryndza, H. E.; Tarn, W. Chem. Rev. 1988, 88, 1163.
20. For example, see: (a) Schaper, F.; Geyer, A.; Brintzinger, H. H. Organometallics 2002, 21, 473.
21. (b) Poulton, J. T.; Hauger, B. E.; Kuhlman, R. L.; Caulton, K. G. Inorg. Chem. 1994, 33, 3325.
22. (c) Fischer, H.; Seitz, F. J. Organomet. Chem. 1984, 268, 247.
23. (d) Hunt, C. T.; Balch, A. L. Inorg. Chem. 1982, 21, 1641.
24. (e) Palmer, G. T.; Basolo, F.; Kool, L. B.; Rausch, M. D. J. Am. Chem. Soc. 1986, 108, 4417.
25. (f) Chisholm, M. H.; McInnes, J. M. J. Chem. Soc., Dalton Trans. 1997, 2735.
26. (g) Simms, R. W.; Drewitt, M. J.; Baird, M. C. Organometallics 2002, 21, 2958.
27. (h) Holland, P. L.; Andersen, R. A.; Bergman, R. G.; Huang, J.; Nolan, S. P. J. Am. Chem. Soc. 1997, 119, 12800.
28. (i) Jordan, R. F. J. Organomet. Chem. 1985, 294, 321.
29. (a) Henkel, S.; Klinkhammer, K. W.; Schwarz, W. Angew. Chem., Int. Ed. Engl. 1994, 33, 68.
30. (b) Klinkhammer, K. W.; Schwarz, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 1334.
31. (c) Wiberg, N.; Lerner, H.-W.; Noth, H.; Ponikwar, W. Angew. Chem., Int. Ed. 1999, 38, 1103.
32. (d) Wiberg, N.; Lerner, H.-W.; Vasisht, S.-K.; Wagner, S.; Karaghiosoff, K.; Noth, H.; Ponikwar, W. Eur. J. Inorg. Chem. 1999, 1211.
33. 2. For example, see: (a) Bulls, A. R.; Bercaw, J. E.; Manriquez, J. M.; Thompson, M. E. Polyhedron 1988, 7, 1409.
34. (b) Selmeczy, A. D.; Jones, W. D.; Osman, R.; Perutz, R. N. Organometallics 1995, 14, 5677.
35. (c) Ittel, S. D.; Tolman, C. A.; English, A. D.; Jesson, J. P. J. Am. Chem. Soc. 1976, 98, 6073.
36. (d) Wang, W. D.; Eisenberg, R. Organometallics 1992, 11, 908.
37. (e) Dioumaev, V. K.; Procopio, L. J.; Carroll, P. J.; Berry, D. H. J. Am. Chem. Soc 2003, 125, 8043.
38. (f) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679.
39. (g) Nishihara, Y.; Takemura, M.; Osakada, K. Organometallics 2002, 21, 825.
40. (h) Thorn, D. L.; Harlow, R. L. Inorg. Chem. 1990, 29, 2017.
41. (i) Thorman, J. L.; Guzei, I. A.; Young, V. G.; Jr.; Woo, L. K. Inorg. Chem. 1999, 38, 3814.
42. (j) Fleischer, H.; Dienes, Y.; Schollmeyer, D. Eur. J. Inorg. Chem. 2002, 2073.
43. (a) Xue, Z.-L.; Li, L.-T.; Hoyt, L. K.; Diminnie. J. B.; Pollitte, J. L. J. Am. Chem. Soc. 1994, 116, 2169.
44. (b) McAlexander, L. H.; Hung, M.; Li, L.-T.; Diminnie, J. B.; Xue, Z.-L.; Yap, G. P. A.; Rheingold, A. L. Organometallics 1996, 15, 5231.
45. (c) Wu, Z.-Z.; McAlexander, L. H.; Diminnie, J. B.; Xue, Z.-L. Organometallics 1998, 17, 4853.
46. (d) Li, L.-T.; Diminnie, J. B.; Liu, X-Z.; Pollitte, J. L.; Xue, Z.-L. Organometallics 1996, 15, 3520.
47. (e) Chen, T.-N.; Wu, Z.-Z.; Li, L.-T.; Sorasaenee, K. R.; Diminnie, J. B.; Pan, H.-J.; Guzei, I. A.; Rheingold, A. L.; Xue, Z.-L. J. Am. Chem. Soc. 1998, 120, 13519.
48. (f) Wu, Z.-Z.; Diminnie, J. B.; Xue, Z.-L. Inorg. Chem. 1998, 37, 6366.
49. (g) Choi, S.-H.; Lin, Z.-Y.; Xue, Z.-L. Organometallics 1999, 18, 5488.
50. (h) Wu, Z.-Z.; Xue, Z.-L. Organometallics 2000, 19, 4191.
51. (i) Wu, Z.-Z.; Diminnie, J. B.; Xue, Z.-L. J. Am. Chem. Soc. 1999, 121, 4300.
52. (j) Wu, Z.-Z.; Diminnie, J. B.; Xue, Z.-L. Organometallics 1998, 17, 2917.
53. (k) Wu, Z.-Z.; Cai, H.; Yu, X.-H.; Blanton, J. R.; Diminnie, J. B.; Pan, H.-J.; Xue, Z.-L. Organometallics 2002, 21, 3973.
54. (l) Yu, X.; Bi, S.; Guzei, I. A.; Lin, Z.; Xue, Z. Inorg. Chem. 2004, 43, 7111.
55. (m) Cai, H.; Yu, X.-H.; Chen, T.; Chen, X.-T.; You, X.-Z.; Xue, Z. Can. J. Chem. 2003, 81, 1398.
56. (n) Qiu, H.; Cai, H.; Woods, J. B.; Wu, Z.-Z.; Chen, T.-N.; Yu, X.-H.; Xue, Z.-L. Organometallics 2005, 24, 4190.
57. (o) Qiu, H.; Chen, S.; Xue, Z.-L. Inorg. Chem. 2007, 46, 6178.
58. (a) Bradley, D. C.; Thomas, I. M. J. Chem. Soc. 1960, 3857.
59. (b) Chandra, G.; Lappert, M. F. J. Chem. Soc. A 1968, 1940.
60. (a) Chisholm, M. H.; Hammond, C. E.; Huffman, J. C. Polyhedron 1988, 7, 2515.
61. (b) Diamond, G. M.; Jordan, R. F.; Petersen, J. L. J. Am. Chem. Soc. 1996, 118, 8024.
62. (a) Campion, B. K.; Heyn, R. H.; Tilley, T. D. Organometallics 1993, 12, 2584.
63. (b) Gutekunst, G.; Brook, A. G. J. Organomet. Chem. 1982, 225, 1.
64. Preliminary results were published in a Communication. Yu, X.; Cai, H.; Guzei, I. A.; Xue, Z.-L. J. Am. Chem. Soc. 2004, 126, 4472.
65. (a) Heeres, H. J.; Meetsma, A.; Teuben, J. H.; Rogers, R. D. Organometallics 1989, 8, 2637.
66. (b) Weingarten, H.; Van Wazer, J. R. J. Am. Chem. Soc. 1965, 87, 724.
67. (c) Wieser, U.; Babushkin, D.; Brintzinger, H.-H. Organometallics 2002, 21, 920.
68. (d) Lappert, M. F.; Power, P. P.; Sanger, A. R.; Srivastava, R. C. Metal and Metalloid Amide, Synthesis, Structures, and Physical and Chemical Properties; Wiley: New York, 1980.
69. Kawaguchi, H.; Tatsumi, K.; Cramer, R. E. Inorg. Chem. 1996, 35, 4391.
70. 3 [Heyn, R. H.; Tilley, T. D. Inorg. Chem. 1989, 28, 1768],
71. 3) [Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Buchwald, S. L. Organometallics 1991, 10, 4031] ,
72. 3)Cl [Muir, K. J. Chem. Soc. A 1971, 2663] ,
73. 2) [Tilley, T. D. Organometallics 1985, 4, 1452],
74. 7n
75. Appleton, T. G.; Clark, H. C.; Manzer, L. E. Coord. Chem. Rev. 1973, 10, 355.
76. 2.
77. See Supporting Information for details.
78. (a) Arnold, J.; Roddick, D. M.; Tilley, T. D.; Rheingold, A. L.; Geib, S. J. Inorg. Chem. 1988, 27, 3510.
79. (b) Casty, G. L.; Lugmair, C. G.; Radu, N. S.; Tilley, T. D.; Walzer, J. F.; Zargarian. D. Organometallics 1997, 16, 8.
80. (c) Frank, D.; Baumgartner, J.; Marschner, C. Chem. Commun. 2002, 1190.
81. 8, decomposing to unknown species. Its formation in this reaction (eq 7) could thus not be confirmed.
82. (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 1994.
83. (b) Wilkinson, R. G. Kinetics and Mechanism of Reactions of Transition Metal Complexes; VCH: New York, 1991.
84. (c) Jordan, R. B. Reaction Mechanism of Inorganic and Organometallic Systems; Oxford University Press: New York, 1991.
85. (a) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area Detector Data; University of Göttingen: Göttingen, Germany, 2000.
86. (b) Sheldrick, G. M. SHELXL-97, A Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany, 1997.