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In eq 1 and most of the following equations and schemes, anionic silicon compounds are drawn with a conventional bond between the negatively charged silicon atom and the metal counterion. It should be noted that it cannot be assumed that this interaction is therefore covalent. While the exact nature of the silicon-potassium bond is still a matter of investigation, reasons of convenience caused me to draw simple bonds between silicon and alkali-metal atoms: in particular, potassium. In addition, here it also should be noted that the equations and schemes do not reflect that potassium ions in fact are mostly coordinated by either ethereal (THF, DME, crown ether) or aromatic (benzene, toluene) solvent molecules. In cases of isolation without any donor molecules, the solid-state structures showed dimerization and coordination of the potassium ion to neighboring trimethylsilyl groups.
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