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Volumn 25, Issue 9, 2006, Pages 2110-2125

Preparation and reactions of polysilanyl anions and dianions

Author keywords

[No Author keywords available]

Indexed keywords

NEGATIVE IONS; POTASSIUM COMPOUNDS; REACTION KINETICS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 33646398328     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0509793     Document Type: Review
Times cited : (78)

References (134)
  • 7
    • 33646389189 scopus 로고    scopus 로고
    • note
    • In eq 1 and most of the following equations and schemes, anionic silicon compounds are drawn with a conventional bond between the negatively charged silicon atom and the metal counterion. It should be noted that it cannot be assumed that this interaction is therefore covalent. While the exact nature of the silicon-potassium bond is still a matter of investigation, reasons of convenience caused me to draw simple bonds between silicon and alkali-metal atoms: in particular, potassium. In addition, here it also should be noted that the equations and schemes do not reflect that potassium ions in fact are mostly coordinated by either ethereal (THF, DME, crown ether) or aromatic (benzene, toluene) solvent molecules. In cases of isolation without any donor molecules, the solid-state structures showed dimerization and coordination of the potassium ion to neighboring trimethylsilyl groups.
  • 25
    • 33646432974 scopus 로고    scopus 로고
    • Dissertation, Technical University Graz
    • Kayser, C. Dissertation, Technical University Graz, 2001.
    • (2001)
    • Kayser, C.1
  • 48
    • 33646429150 scopus 로고    scopus 로고
    • Dissertation, Technical University Graz
    • Wallner, A. Dissertation, Technical University Graz, 2005.
    • (2005)
    • Wallner, A.1
  • 51
    • 33646393756 scopus 로고    scopus 로고
    • Dissertation, Technical University Graz, ongoing
    • Gaderbauer, W. Dissertation, Technical University Graz, ongoing.
    • Gaderbauer, W.1
  • 53
    • 33646400232 scopus 로고    scopus 로고
    • Dissertation, Technical University Graz
    • Fischer, J. Dissertation, Technical University Graz, 2005.
    • (2005)
    • Fischer, J.1
  • 64
    • 0142112113 scopus 로고    scopus 로고
    • Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany
    • (a) Fischer, R.; Marschner, C. In Organosilicon Chemistry V; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; pp 190-194.
    • (2003) Organosilicon Chemistry V , pp. 190-194
    • Fischer, R.1    Marschner, C.2
  • 76
    • 33646386353 scopus 로고    scopus 로고
    • Marschner, C. Unpublished results
    • Marschner, C. Unpublished results.
  • 93
  • 124
    • 33646404290 scopus 로고    scopus 로고
    • Fischer, J.; Zirngast, M.; Marschner, C. Unpublished results
    • Fischer, J.; Zirngast, M.; Marschner, C. Unpublished results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.