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Volumn 18, Issue 4, 1996, Pages 223-247

Early-transition-metal silyl complexes free of anionic π-ligands. A comparison of alkyl and silyl ligands

Author keywords

Alkyl; Alkylidene; Alkylidyne complexes; Early transition metals; Silyl complexes; hydrogen abstraction

Indexed keywords


EID: 0030552361     PISSN: 02603594     EISSN: None     Source Type: Journal    
DOI: 10.1080/02603599608032723     Document Type: Article
Times cited : (30)

References (104)
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    • For leading reviews or highlights, see (a) T. D. Tilley, in The Silicon-Heteroatom Bond, eds. S. Patai and Z. Rappoport (Wiley, New York, 1991), p. 245 and p. 309.
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    • (m) K. M. Mackay and B. K. Nicholson, in Comprehensive Organometallic Chemistry, Vol. 6, eds. G. Wilkinson, F. G. A. Stone and E. W. Abel (Pergamon Press, Oxford, 1982), p. 1043 and references therein.
    • (1982) Comprehensive Organometallic Chemistry , vol.6 , pp. 1043
    • Mackay, K.M.1    Nicholson, B.K.2
  • 31
    • 0001483907 scopus 로고
    • The following are reports of a few other early-transition-metal silyl complexes with carbonyl, alkoxide or phosphine ligands: (a) E. E. Isaacs and W. A. G. Graham, Can. J. Chem. 53, 467 (1975).
    • (1975) Can. J. Chem. , vol.53 , pp. 467
    • Isaacs, E.E.1    Graham, W.A.G.2
  • 35
    • 85033765694 scopus 로고
    • Ph.D. Thesis, University of Alberta, Canada
    • (e) J. K. Hoyano, Ph.D. Thesis, University of Alberta, Canada (1971).
    • (1971)
    • Hoyano, J.K.1
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    • 85033735902 scopus 로고    scopus 로고
    • private communication
    • 4 were observed. M. Spencer and G. S. Girolami, private communication.
    • Spencer, M.1    Girolami, G.S.2
  • 50
    • 0011028801 scopus 로고
    • 3, was found to crystalize into linear symmetric chains with -Zr-Cl-Zr-Cl units. L. K. Hoyt, J. L. Pollitte and Z. Xue, Inorg. Chem. 33, 2497 (1994). See also J. H. Wengrovius and R. R. Schrock, J. Organomet. Chem. 205, 319 (1981).
    • (1994) Inorg. Chem. , vol.33 , pp. 2497
    • Hoyt, L.K.1    Pollitte, J.L.2    Xue, Z.3
  • 51
    • 0001097476 scopus 로고
    • 3, was found to crystalize into linear symmetric chains with -Zr-Cl-Zr-Cl units. L. K. Hoyt, J. L. Pollitte and Z. Xue, Inorg. Chem. 33, 2497 (1994). See also J. H. Wengrovius and R. R. Schrock, J. Organomet. Chem. 205, 319 (1981).
    • (1981) J. Organomet. Chem. , vol.205 , pp. 319
    • Wengrovius, J.H.1    Schrock, R.R.2
  • 53
    • 84885736777 scopus 로고
    • For Schrock-type alkylidene compounds, see (a) R. R. Schrock, J. Am. Chem. Soc. 96, 6796 (1974).
    • (1974) J. Am. Chem. Soc. , vol.96 , pp. 6796
    • Schrock, R.R.1
  • 56
    • 0002838494 scopus 로고
    • ed. P. S. Braterman Plenum, New York
    • (d) R. R. Schrock, in Reactions of Coordinated Ligands, ed. P. S. Braterman (Plenum, New York, 1986), Vol. 1, p. 221.
    • (1986) Reactions of Coordinated Ligands , vol.1 , pp. 221
    • Schrock, R.R.1
  • 62
    • 85033744049 scopus 로고
    • eds. G. Wilkinson, F. G. A. Stone and E. W. Abel Pergamon, New York, Chapter 54
    • (j) R. H. Grubbs, in Comprehensive Organometallic Chemistry, Vol. 8, eds. G. Wilkinson, F. G. A. Stone and E. W. Abel (Pergamon, New York, 1982), Chapter 54.
    • (1982) Comprehensive Organometallic Chemistry , vol.8
    • Grubbs, R.H.1
  • 74
    • 85033757761 scopus 로고
    • thesis, Massachusetts Institute of Technology
    • G. A. Rupprecht, thesis, Massachusetts Institute of Technology (1979).
    • (1979)
    • Rupprecht, G.A.1
  • 75
    • 0004289283 scopus 로고
    • VCH, New York
    • For leading reviews of the Schrock-type alkylidyne complexes, see: (a) J. S. Murdzek and R. R. Schrock, in Carbyne Complexes (VCH, New York, 1988).
    • (1988) Carbyne Complexes
    • Murdzek, J.S.1    Schrock, R.R.2
  • 77
    • 0001797628 scopus 로고
    • eds. S. Patai and Z. Rappoport Wiley, New York, Chapter 2
    • Y. Apeloig, in The Chemistry of Organic Silicon Compounds, eds. S. Patai and Z. Rappoport (Wiley, New York, 1989), Chapter 2, p. 57.
    • (1989) The Chemistry of Organic Silicon Compounds , pp. 57
    • Apeloig, Y.1
  • 89
    • 85033769567 scopus 로고    scopus 로고
    • note
    • 2Ta(=CHCMe3)Cl" at a faster rate.
  • 92
    • 85033742591 scopus 로고    scopus 로고
    • note
    • 2 contains two bridging halide ligands: formula presented
  • 96
    • 85033761443 scopus 로고    scopus 로고
    • In the Berry pseudorotation, the two axial and two of the three equatorial ligands are involved in an exchange. See Ref. 28, p. 240
    • In the Berry pseudorotation, the two axial and two of the three equatorial ligands are involved in an exchange. See Ref. 28, p. 240.
  • 100
    • 0040067701 scopus 로고
    • The following intra-molecular alkyl transfers have been reported in complexes containing late transition metal atoms with direct metal-metal bonding, (a) F. Antwi-Nsiah and M. Cowie, Organometallics 11, 3157 (1992).
    • (1992) Organometallics , vol.11 , pp. 3157
    • Antwi-Nsiah, F.1    Cowie, M.2


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