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Volumn 111, Issue 34, 2007, Pages 10095-10108

Revisiting ether-derivatized imidazolium-based ionic liquids

Author keywords

[No Author keywords available]

Indexed keywords

DENSITY FUNCTIONAL THEORY; ETHERS; HALIDE MINERALS; MELTING POINT; SALTS; SUPRAMOLECULAR CHEMISTRY;

EID: 34548598494     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0734191     Document Type: Article
Times cited : (122)

References (81)
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    • Reactions for all the methoxymethyl halides with 1-methylimidazole are highly exothermic. Diethyl ether or toluene is recommended to be used as a cosolvent to help dissipate the heat.
    • Reactions for all the methoxymethyl halides with 1-methylimidazole are highly exothermic. Diethyl ether or toluene is recommended to be used as a cosolvent to help dissipate the heat.
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    • The structure of 1-butyl-3-methylimidazolium iodide has been studied by wide-angle X-ray scattering, and Raman, spectroscopy. See: Katayanagi, H.; Hayashi, S.; Hamaguchi, H.-o.; Nishikawa, K. Chem. Phys. Lett. 2004, 392, 460.
    • The structure of 1-butyl-3-methylimidazolium iodide has been studied by wide-angle X-ray scattering, and Raman, spectroscopy. See: Katayanagi, H.; Hayashi, S.; Hamaguchi, H.-o.; Nishikawa, K. Chem. Phys. Lett. 2004, 392, 460.
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    • For single crystal X-ray diffraction analysis of 1-butyl-3- methylimidazolium iodide, see: Nakakoshi, M.; Shiro, M.; Fujimoto, T.; Machinami, T.; Seki, H.; Tashiro, M.; Nishikawa, K. Chem. Lett. 2006, 35, 1400.
    • For single crystal X-ray diffraction analysis of 1-butyl-3- methylimidazolium iodide, see: Nakakoshi, M.; Shiro, M.; Fujimoto, T.; Machinami, T.; Seki, H.; Tashiro, M.; Nishikawa, K. Chem. Lett. 2006, 35, 1400.
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    • The commercially obtained precursor contains traces of hydrogen bromide. It is important to evacuate the starting material before reaction to remove this impurity. A slight excess of the precursor of 2-(methoxyethoxy)-ethyl bromide is required.
    • The commercially obtained precursor contains traces of hydrogen bromide. It is important to evacuate the starting material before reaction to remove this impurity. A slight excess of the precursor of 2-(methoxyethoxy)-ethyl bromide is required.
  • 53
    • 0035942911 scopus 로고    scopus 로고
    • 2N] was determined as 29.0 cp in our experiment at 21.0 °C.
    • 2N] was determined as 29.0 cp in our experiment at 21.0 °C.
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    • Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A.;. Vreven, T., Jr.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G., Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, Revision B.05; Gaussian, Inc.: Wallingford CT, 2004.


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