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Volumn , Issue 13, 2007, Pages 2136-2138

Indium-bipyridine catalyzed, enantioselective aminolysis of meso-epoxides

Author keywords

Amine; Asymmetric catalysis; Bipyridine; Epoxides; Indium

Indexed keywords

1,2 AMINO ALCOHOL; ALCOHOL DERIVATIVE; BIPYRIDINE; EPOXIDE; INDIUM 111; UNCLASSIFIED DRUG;

EID: 34548190827     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-984902     Document Type: Article
Times cited : (55)

References (50)
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    • For previous reports on non-enantioselective indium(III)-catalyzed aminolyses of epoxides, see: (a) Rajender Reddy, R.; Arjun Reddy, M.; Bhanumathi, N.; Rama Rao, K. New J. Chem. 2001, 25, 221.
    • For previous reports on non-enantioselective indium(III)-catalyzed aminolyses of epoxides, see: (a) Rajender Reddy, R.; Arjun Reddy, M.; Bhanumathi, N.; Rama Rao, K. New J. Chem. 2001, 25, 221.
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    • For selected recent reports on enantioselective, indium-catalyzed transformations, see: a
    • For selected recent reports on enantioselective, indium-catalyzed transformations, see: (a) Harada, S.; Takita, R.; Ohshima, T.; Matsunaga, S.; Shibasaki, M. Chem. Commun. 2007, 948.
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    • For the first synthesis and application of ligand 2a in asymmetric catalysis, see: Bolm, C.; Zehnder, M.; Bur, D. Angew. Chem., Int. Ed. Engl. 1990, 29, 191;
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    • We have made the same observation in the related indium(III)-bipyridine 2a catalyzed thiolysis of meso-epoxides ref. 9
    • We have made the same observation in the related indium(III)-bipyridine 2a catalyzed thiolysis of meso-epoxides (ref. 9).
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    • 2 (1 mL) and treated with epoxide (0.50 mmol) and amine (1.00 mmol) at r.t. The reaction mixture was stirred for 48 h at r.t. whereupon it was concentrated in vacuo and purified by silica gel chromatography. For analytical and spectroscopic details of the products, see ref. 8b.
    • 2 (1 mL) and treated with epoxide (0.50 mmol) and amine (1.00 mmol) at r.t. The reaction mixture was stirred for 48 h at r.t. whereupon it was concentrated in vacuo and purified by silica gel chromatography. For analytical and spectroscopic details of the products, see ref. 8b.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.