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Volumn 349, Issue 10, 2007, Pages 1624-1628

Stabilization of palladium nanoparticles by polyoxometalates appended with alkylthiol tethers and their use as binary catalysts for liquid phase aerobic oxydehydrogenation

Author keywords

Dehydrogenation; Homogeneous catalysis; Oxidation; Oxygen; Palladium; Polyoxometalates

Indexed keywords


EID: 34547208115     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200600613     Document Type: Article
Times cited : (37)

References (41)
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    • Catalysts for Fine Chemical Synthesis
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    • d) I. V. Kozhevnikov, Catalysts for Fine Chemical Synthesis, Vol. 2, Catalysis by Polyoxometalates, Wiley, Weinheim. 2002.
    • (2002) Catalysis by Polyoxometalates , vol.2
    • Kozhevnikov, I.V.1
  • 24
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    • a) G. Schmid, Chem. Rev. 1992, 92, 1709-1727;
    • (1992) Chem. Rev , vol.92 , pp. 1709-1727
    • Schmid, G.1
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    • 0037911022 scopus 로고
    • b) L. N. Lewis, Chem. Rev. 1993, 93, 2693-2730;
    • (1993) Chem. Rev , vol.93 , pp. 2693-2730
    • Lewis, L.N.1
  • 35
    • 0003946143 scopus 로고    scopus 로고
    • B. Cornils, W. A. Herrmann, R. Schlögl, C-H. Wong, Eds, Wiley-VCH, Weinheim
    • B. Cornils, W. A. Herrmann, R. Schlögl, C-H. Wong, (Eds.), Catalysis from A to Z. A Concise Encyclopedia, Wiley-VCH, Weinheim, 2000.
    • (2000) Catalysis from A to Z. A Concise Encyclopedia
  • 39
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    • The reports in the almost exclusively patent literature on the selectivity of dehydrogenation of vinylcylohexene are ambiguous; most patents show low selectivity to styrene. In a single paper in the open literature Pd/Al2O3 was shown to give styrene at selectivities ranging broadly from 7-70% depending significantly on pretreatment of the catalyst, see: A. Castellan, G. R. Tauszik, J. Catal. 1977, 50, 172-175
    • 3 was shown to give styrene at selectivities ranging broadly from 7-70% depending significantly on pretreatment of the catalyst, see: A. Castellan, G. R. Tauszik, J. Catal. 1977, 50, 172-175.
  • 40
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    • We have reported that a redox reactive polyoxometalate, Na 5PV2Mo10O40 on carbon, can catalyze the oxydehydrogenation of 4-vinylcyclohexene but only to ethylbenzene: R. Neumann, M. Levin, J. Org. Chem. 1991, 56, 5707-5710
    • 40 on carbon, can catalyze the oxydehydrogenation of 4-vinylcyclohexene but only to ethylbenzene: R. Neumann, M. Levin, J. Org. Chem. 1991, 56, 5707-5710.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.