메뉴 건너뛰기




Volumn 125, Issue 18, 2003, Pages 5501-5510

Asymmetric alternating copolymerization of cyclohexene oxide and CO2 with dimeric zinc complexes

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CHEMICAL BONDS; COMPLEXATION; COPOLYMERIZATION; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EID: 0037616543     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028666b     Document Type: Article
Times cited : (186)

References (70)
  • 1
    • 0003445429 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York
    • (a) Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999.
    • (1999) Comprehensive Asymmetric Catalysis
  • 4
    • 0038417408 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, Chapter 36
    • (b) Coates, G. W. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Vol. III, Chapter 36.
    • (1999) Comprehensive Asymmetric Catalysis , vol.3
    • Coates, G.W.1
  • 22
    • 0035940792 scopus 로고    scopus 로고
    • and references cited therein
    • (b) Kumagai, T.; Itsuno, S. Macromolecules 2001, 34, 7624 and references cited therein.
    • (2001) Macromolecules , vol.34 , pp. 7624
    • Kumagai, T.1    Itsuno, S.2
  • 24
    • 0019665947 scopus 로고
    • 2, see: (a) Rokicki, A.; Kuran, W. J. Macromol. Sci., Rev. Macromol. Chem. 1981, C21, 135. (b) Inoue, S. Carbon Dioxide as a Source of Carbon: Aresta, M., Forti, G., Eds.; Reidel Publishing Co.: Dordrecht, Germany. 1987; p 331. (c) Darensbourg, D. J.; Holtcamp, M. W. Coord. Chem. Rev. 1996, 153, 155. (d) Super, M.; Beckmann, E. J. Trends Polym. Sci. 1997, 5, 236.
    • (1981) J. Macromol. Sci., Rev. Macromol. Chem. , vol.C21 , pp. 135
    • Rokicki, A.1    Kuran, W.2
  • 25
    • 0002711848 scopus 로고
    • Aresta, M., Forti, G., Eds.; Reidel Publishing Co.: Dordrecht, Germany
    • 2, see: (a) Rokicki, A.; Kuran, W. J. Macromol. Sci., Rev. Macromol. Chem. 1981, C21, 135. (b) Inoue, S. Carbon Dioxide as a Source of Carbon: Aresta, M., Forti, G., Eds.; Reidel Publishing Co.: Dordrecht, Germany. 1987; p 331. (c) Darensbourg, D. J.; Holtcamp, M. W. Coord. Chem. Rev. 1996, 153, 155. (d) Super, M.; Beckmann, E. J. Trends Polym. Sci. 1997, 5, 236.
    • (1987) Carbon Dioxide as a Source of Carbon , pp. 331
    • Inoue, S.1
  • 26
    • 0030547180 scopus 로고    scopus 로고
    • 2, see: (a) Rokicki, A.; Kuran, W. J. Macromol. Sci., Rev. Macromol. Chem. 1981, C21, 135. (b) Inoue, S. Carbon Dioxide as a Source of Carbon: Aresta, M., Forti, G., Eds.; Reidel Publishing Co.: Dordrecht, Germany. 1987; p 331. (c) Darensbourg, D. J.; Holtcamp, M. W. Coord. Chem. Rev. 1996, 153, 155. (d) Super, M.; Beckmann, E. J. Trends Polym. Sci. 1997, 5, 236.
    • (1996) Coord. Chem. Rev. , vol.153 , pp. 155
    • Darensbourg, D.J.1    Holtcamp, M.W.2
  • 27
    • 0001477966 scopus 로고    scopus 로고
    • 2, see: (a) Rokicki, A.; Kuran, W. J. Macromol. Sci., Rev. Macromol. Chem. 1981, C21, 135. (b) Inoue, S. Carbon Dioxide as a Source of Carbon: Aresta, M., Forti, G., Eds.; Reidel Publishing Co.: Dordrecht, Germany. 1987; p 331. (c) Darensbourg, D. J.; Holtcamp, M. W. Coord. Chem. Rev. 1996, 153, 155. (d) Super, M.; Beckmann, E. J. Trends Polym. Sci. 1997, 5, 236.
    • (1997) Trends Polym. Sci. , vol.5 , pp. 236
    • Super, M.1    Beckmann, E.J.2
  • 42
    • 0003268468 scopus 로고    scopus 로고
    • The theoretical study of the copolymerization catalyzed by (β-diiminato)-ZnOR complexes was also investigated; see: Liu, Z.; Torrent, M.; Morokuma, K. Organometallics 2002, 21, 1056.
    • (2002) Organometallics , vol.21 , pp. 1056
    • Liu, Z.1    Torrent, M.2    Morokuma, K.3
  • 47
    • 0037741339 scopus 로고    scopus 로고
    • note
    • For an example of the optical purity determination of the polymer with main-chain chirality by degrading into chiral repeating units, see ref 7a.
  • 50
    • 0038417412 scopus 로고    scopus 로고
    • note
    • 8 at 20 °C. The disappearance of the signals may result from the overlapping with other signals or the signal broadening.
  • 51
    • 0040514974 scopus 로고
    • 2Zn and a β-amino alcohol: (a) Kitamura, M.; Okada, S.; Suga, S.; Noyori, R. J. Am. Chem. Soc. 1989, 111, 4028. (b) Kitamura, M.; Suga, S.; Niwa, M.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 4832. (c) Kitamura, M.; Yamakawa, M.; Oka, H.; Suga, S.; Noyori, R. Chem. - Eur. J. 1996, 2, 1173.
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 4028
    • Kitamura, M.1    Okada, S.2    Suga, S.3    Noyori, R.4
  • 52
    • 0001678004 scopus 로고
    • 2Zn and a β-amino alcohol: (a) Kitamura, M.; Okada, S.; Suga, S.; Noyori, R. J. Am. Chem. Soc. 1989, 111, 4028. (b) Kitamura, M.; Suga, S.; Niwa, M.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 4832. (c) Kitamura, M.; Yamakawa, M.; Oka, H.; Suga, S.; Noyori, R. Chem. - Eur. J. 1996, 2, 1173.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 4832
    • Kitamura, M.1    Suga, S.2    Niwa, M.3    Noyori, R.4
  • 53
    • 27844450624 scopus 로고    scopus 로고
    • 2Zn and a β-amino alcohol: (a) Kitamura, M.; Okada, S.; Suga, S.; Noyori, R. J. Am. Chem. Soc. 1989, 111, 4028. (b) Kitamura, M.; Suga, S.; Niwa, M.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 4832. (c) Kitamura, M.; Yamakawa, M.; Oka, H.; Suga, S.; Noyori, R. Chem. - Eur. J. 1996, 2, 1173.
    • (1996) Chem. - Eur. J. , vol.2 , pp. 1173
    • Kitamura, M.1    Yamakawa, M.2    Oka, H.3    Suga, S.4    Noyori, R.5
  • 56
    • 0033532884 scopus 로고    scopus 로고
    • (b) Rijnberg, E.; Hovestad, N. J.; Kleij, A. W.; Jastrzebski, J. T. B. H.; Boersma, J.; Jassen, M. D.; Spek, A. L.; van Koten, G. Organometallics 1997, 16, 2847. Aminoalkolato ligand: Mimoun, H.; Laumer, J. Y. S.; Giannini, L.; Scopelliti, R.; Floriani, C. J. Am. Chem. Soc. 1999, 121, 6158. Pyridylalkolato ligand: Bolm, C.; Schlingloff, G.; Harms, K. Chem. Ber. 1992, 125, 1191.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 6158
    • Mimoun, H.1    Laumer, J.Y.S.2    Giannini, L.3    Scopelliti, R.4    Floriani, C.5
  • 57
    • 84985653959 scopus 로고
    • (b) Rijnberg, E.; Hovestad, N. J.; Kleij, A. W.; Jastrzebski, J. T. B. H.; Boersma, J.; Jassen, M. D.; Spek, A. L.; van Koten, G. Organometallics 1997, 16, 2847. Aminoalkolato ligand: Mimoun, H.; Laumer, J. Y. S.; Giannini, L.; Scopelliti, R.; Floriani, C. J. Am. Chem. Soc. 1999, 121, 6158. Pyridylalkolato ligand: Bolm, C.; Schlingloff, G.; Harms, K. Chem. Ber. 1992, 125, 1191.
    • (1992) Chem. Ber. , vol.125 , pp. 1191
    • Bolm, C.1    Schlingloff, G.2    Harms, K.3
  • 59
    • 0000907544 scopus 로고    scopus 로고
    • For reviews on mass spectrometry of synthetic polymers, see: (a) Nielen, M. W. Mass Spectrom. Rev. 1999, 18, 309. (b) Hanton, S. D. Chem. Rev. 2001, 101, 527.
    • (1999) Mass Spectrom. Rev. , vol.18 , pp. 309
    • Nielen, M.W.1
  • 60
    • 0035246226 scopus 로고    scopus 로고
    • For reviews on mass spectrometry of synthetic polymers, see: (a) Nielen, M. W. Mass Spectrom. Rev. 1999, 18, 309. (b) Hanton, S. D. Chem. Rev. 2001, 101, 527.
    • (2001) Chem. Rev. , vol.101 , pp. 527
    • Hanton, S.D.1
  • 65
    • 0037741343 scopus 로고    scopus 로고
    • note
    • 2] complexes are second order in [Zn(OR)(BDI)], which suggests the participation of di-zinc species in the enchainment of monomer. See ref 13c. At present, the possibility for the further aggregation of 3a-OR cannot be omitted.
  • 67
    • 0037741341 scopus 로고    scopus 로고
    • note
    • 2Zn and 1a-H afforded the copolymer of 55% ee in 67% yield. This result was almost the same when isolated complex 2a was used.
  • 68
    • 0038755480 scopus 로고    scopus 로고
    • note
    • See Supporting Information.
  • 70
    • 0037741342 scopus 로고    scopus 로고
    • note
    • 2Zn and 1 did not give the suitable single crystals for X-ray analysis.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.