α-Oxygenated crotyltitanium and dyotropic rearrangement in the total synthesis of discodermolide

Angewandte Chemie - International Edition

Volumn 46, Issue 11, 2007, Pages 1917-1921

  De Lemos, Elsa ^a   Porée, François Hugues ^a   Commerçon, Alain ^b   Betzer, Jean François ^a   Pancrazi, Ange ^a   Ardisson, Janick ^a  

^a UNIVERSITÉ DE CERGY PONTOISE   (France)

^b SANOFI   (France)

Author keywords

Allylation; Metalation; Natural products; Rearrangement; Total synthesis

Indexed keywords

CHEMICAL BONDS; PHASE TRANSITIONS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

ALLYLATION; DISCODERMOLIDE; METALATION; NATURAL PRODUCTS; STEREOCONTROLLED GENERATION; SYN-ANTI STEREOTRIADS;

TITANIUM COMPOUNDS;

ALKANE; ALLYL COMPOUND; ANTINEOPLASTIC AGENT; CARBAMIC ACID DERIVATIVE; DISCODERMOLIDE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; LACTONE; ORGANOMETALLIC COMPOUND; PYRONE DERIVATIVE; TITANIUM;

ANIMAL; ARTICLE; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; SPONGE (PORIFERA); STEREOISOMERISM; SYNTHESIS;

ALKANES; ALLYL COMPOUNDS; ANIMALS; ANTINEOPLASTIC AGENTS; CARBAMATES; INDICATORS AND REAGENTS; LACTONES; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PORIFERA; PYRONES; STEREOISOMERISM; TITANIUM;

EID: 34249672439     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200604629     Document Type: Article

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