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(a) Trnka, T. M.; Morgan, J. P.; Sanford, M. S.; Wilhelm, T. E.; Scholl, M.; Choi, T-L.; Ding, S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 2546-2558.
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Trnka, T.M.1
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Ding, S.7
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(b) Michrowska, A.; Bujok, R.; Harutyunyan, S.; Sashuk, V.; Dolgonos, G.; Grela, K. J. Am. Chem. Soc. 2004, 126, 9318-9325.
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Williams, J. E.; Harner, M. J.; Sponsler, M. B. Organometallics 2005, 24, 2013-2015.
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Schrock, R.R.1
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2(=CHPh): Nieczypor, P.; van Leeuwen, P. W. N. M.; Mol, J. C.; Lutz, M.; Spek, A. L. J. Organomet. Chem. 2001, 625, 58-66.
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2(=CHPh): Nieczypor, P.; van Leeuwen, P. W. N. M.; Mol, J. C.; Lutz, M.; Spek, A. L. J. Organomet. Chem. 2001, 625, 58-66.
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(a) Fomine, S.; Vargas, S. M.; Tlenkopatchev, M. A. Organometallics 2003, 22, 93-99.
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Love, J. A.; Morgan, J. P.; Truka, T. M.; Grubbs, R. H. Angew. Chem., Int. Ed. 2002, 41, 4035-4037.
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Morgan, J.P.2
Truka, T.M.3
Grubbs, R.H.4
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23
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34249086606
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α Fischer carbene peaks for 2a,b are 13.76 ppm (J = 3.7 Hz) and 13.72 ppm (J = 3.9 Hz), respectively.
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α Fischer carbene peaks for 2a,b are 13.76 ppm (J = 3.7 Hz) and 13.72 ppm (J = 3.9 Hz), respectively.
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25
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0033593413
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Chloroform causes faster decomposition, presumably due to radical Kharasch reactions. See for example
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Chloroform causes faster decomposition, presumably due to radical Kharasch reactions. See for example: Tallarico, J. A.: Malnick, L. M.; Snapper, M. L. J. Org. Chem. 1999, 64, 344-345.
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(1999)
J. Org. Chem
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Tallarico, J.A.1
Malnick, L.M.2
Snapper, M.L.3
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26
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0034814443
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(a) Sanford, M. S.; Love, J. A.; Grubbs, R. H. J. Am. Chem. Soc. 2001, 123, 6543-6554.
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(2001)
J. Am. Chem. Soc
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Sanford, M.S.1
Love, J.A.2
Grubbs, R.H.3
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28
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34249005600
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Magnetization transfer experiments have been used to determine the rates of degenerate phosphine exchange reactions in similar systems.7,15a In this specific case, the volatility of PMe3 and the relatively slow rate make this experiment impractical
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3 and the relatively slow rate make this experiment impractical.
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30
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0035937915
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A detailed account of our analysis can be found in the Supporting Information
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(b) Caravan, P.; Comuzzi, C.; Crooks, W.; McMurray, T. J.; Choppin, G. R.; Woulfe, S. R. Inorg. Chem. 2001, 40, 2170-2176. A detailed account of our analysis can be found in the Supporting Information.
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(2001)
Inorg. Chem
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Caravan, P.1
Comuzzi, C.2
Crooks, W.3
McMurray, T.J.4
Choppin, G.R.5
Woulfe, S.R.6
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31
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2942678732
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Hong, S. H.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2004, 126, 7414-7415.
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(2004)
J. Am. Chem. Soc
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Hong, S.H.1
Day, M.W.2
Grubbs, R.H.3
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32
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4444244930
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Schuehler, D. E.; Williams, J. E.; Sponsler, M. B. Macromolecules 2004, 37, 6255-6257.
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(2004)
Macromolecules
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Schuehler, D.E.1
Williams, J.E.2
Sponsler, M.B.3
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33
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34249026714
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A trace amount of polymerization that was observed within minutes was prevented by addition of EVE before the acetylene reaction. This apparently removed traces of 3 or other active impurities
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A trace amount of polymerization that was observed within minutes was prevented by addition of EVE before the acetylene reaction. This apparently removed traces of 3 or other active impurities.
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34
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34249049248
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Grubbs and co-workers have been generally careful in this respect. 7,15a
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7,15a
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