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note
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In the case of bis(2-diphenylphosphinophenyl)ether (DPEphos) and 9,9-dimethyl-4,5-bis(diphenylphosphino)thioxanthene we observed decomposition of the carbene moiety. Formation of impurities, which could not be separated from the product, was observed when using 2,3′-bis((diphenylphosphino)methyl)-1,1′-biphenyl (2,3′-BISBI), and no reaction occurred with 1,1′-bis(di-tert-butylphosphino)ferrocene because of steric bulk of the ligand.
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27
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0003668202
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The DIRDIF 97 Program System
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University of Nijmegen, The Netherlands
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28
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