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33645201157
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note
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In the presence of 30 % thiol catalyst the yield decreased (28 %) and thiyl radical addition to vinyl pivalate was observed as a side reaction.
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-
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30
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33645199413
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note
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The regioisomeric hydroamination product, the cyclic N,O acetal, was formed in 5 % yield.
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31
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20444382213
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For recent reports on transition-metal-free transfer hydrogenation see: J. W. Yang, M. T. Hechavarria Fonseca, B. List, Angew. Chem. 2004, 116, 6829;
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