Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination

Organometallics

Volumn 22, Issue 24, 2003, Pages 4836-4838

  Stubbert, Bryan D ^a   Stern, Charlotte L ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIZATION; INTRAMOLECULAR HYDROAMINATION;

ACTINIDES; AMINATION; CATALYSIS; CATALYSTS; HYDROGEN BONDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

ORGANOMETALLICS;

EID: 0345016345     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034093f     Document Type: Article

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48. An alternative cycle proceeding through an An=NR species (see ref 18) as a catalytically inactive species or as the active catalyst species cannot be rigorously ruled out at this time. Imide formation as a reversible, turnover-limiting step seems unlikely given the observed independence of overall rate on [substrate].