Oligomerization and hydroamination of terminal alkynes promoted by the cationic organoactinide compound [(Et2N)3U][BPh4]

Chemistry - A European Journal

Volumn 8, Issue 23, 2002, Pages 5384-5396

  Wang, Jiaxi ^a   Dash, Aswini Kumar ^a   Kapon, Moshe ^a   Berthet, Jean Claude ^b   Ephritikhine, Michel ^b   Eisen, Moris S ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

^b CEA SACLAY   (France)

Author keywords

Alkynes; Dimerization; Homogeneous catalysis; Hydroamination; Uranium

Indexed keywords

CATALYSTS; CHEMICAL BONDS; DIMERS; ISOMERIZATION; ISOMERS; X RAY DIFFRACTION;

HYDROAMINATION;

AMINES;

ACTINIDE; ALKYNE DERIVATIVE; AMINE; DEUTERIUM; DIMER; IMINE; LIGAND; METAL; URANIUM;

AMINATION; ARTICLE; CATALYST; CIS ISOMER; COMPLEX FORMATION; HYDROGEN BOND; ISOMERISM; MOLECULAR STABILITY; OLIGOMERIZATION; PROTON TRANSPORT; REACTION ANALYSIS; STEREOSPECIFICITY; THERMODYNAMICS; X RAY DIFFRACTION;

EID: 0037011064     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20021202)8:23<5384::AID-CHEM5384>3.0.CO;2-X     Document Type: Article

References (108)

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12. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
13. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
14. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
15. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
16. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
17. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
18. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
19. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: a) P. W. Roesky, U. Denninger, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4486; b) P. W. Roesky, C. L. Stern, T. J. Marks, Organometallics 1997, 16, 4705; c) C. M. Haar C. L. Stern, T. J. Marks, Organometallics 1996, 15, 1765; d) G. A. Molander, J. Winterfeld, J. Organomet. Chem. 1996, 524, 275; e) M. A. Giardello, V. P. Conticello, L. Brard, M. R. Gagnè, T. J. Marks, J. Am. Chem. Soc. 1994, 116, 10241; f) G. A. Molander, J. O. Hoberg, J. Am. Chem. Soc. 1992, 114, 3123; g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8111; h) W. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1983, 105, 1401.
20. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
21. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
22. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
23. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
24. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
25. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
26. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
27. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
28. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
29. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
30. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
31. For examples of catalytic activity of organolanthanides in dimerization, oligomerization, or polymerization, see: a) L. S. Boff, B. M. Novak, Macromolecules 1997, 30, 3494; b) W. J. Evans, P. M. DeCoster, J. Greaves, Macromolecules 1995, 28, 7929; c) H. J. Heeres, A. Heeres, J. H. Teuben, Organometallics 1990, 9, 1508; d) J. P. Mitchell, S. Hajela, S. K. Brookhart, K. I. Hardcastle, L. M. Henling, J. E. Bercaw, J. Am. Chem. Soc. 1996, 118, 1045; e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909; f) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747; g) C. J. Schaverien, Organometallics 1994, 13, 69; h) H. J. Heeres, J. H. Teuben, Organometallics 1991, 10, 1980; i) H. J. Heeres, J. Renkema, M. Booij, A. Meetsma, J. H. Teuben, Organometallics 1988, 7, 2495, and references therein; j) G. Jeske, L. E. Schock, P. N. Swepson, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091; k) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51; l) W. J. Evans, R. A. Keyer, J. W. Ziller, Organometallics, 1993, 12, 2618.
32. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
33. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
34. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
35. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
36. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
37. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
38. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
39. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
40. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
41. For examples of catalytic activity of organolanthanides in hydroamination, see: a) V. M. Arredondo, F. E. McDonald, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 4871; b) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 9295; c) Y. Li, T. J. Marks, Organometallics 1996, 15, 3770; d) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 707; e) Y. Li, P.-F. Fu, T. J. Marks, Organometallics 1994, 13, 439; f) see ref.[3e]; g) see ref. [3b]; h) S. Tian, V. M. Arredondo, C. L. Stern, T. J. Marks, Organometallics 1999, 18, 2568, and references therein: i) G. A. Molander, E. D. Dowdy, J. Org. Chem. 1999, 64, 6515, and references therein; f) Y. Li, T. J. Marks, J. Am. Chem. Soc. 1998, 120, 1757.
42. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
43. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
44. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
45. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
46. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
47. For examples of catalytic activity of organolanthanides in hydrosilylation see: a) P.-F. Fu, L. Brard, Y. Li, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 7157; b) G. A. Molander, P. J. Nichols, J. Am. Chem. Soc. 1995, 117, 4415; c) G. A. Molander, M. Julius, J. Org. Chem. 1992, 57, 6347; d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. 1991, 40; e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. J. Negishi, J. Am. Chem. Soc. 1991, 113, 8664; f) G. A. Molander, E. D. Dowdy, B. C. Noll, Organometallics 1998, 17, 3754.
48. For examples of catalytic activity of organolanthanides in hydrophosphination, see: M. A. Giardello, W. A. King, S. P. Nolan, M. Porchia, C. Sishta, T. J. Marks, in Energetics of Organometallic Species (Ed.: J. A. Martinho Simoes) Kluwer, Dordrecht (The Netherlands), 1992, pp 35-54.
49. For examples of catalytic activity of organolanthanides in hydroboration, see: a) R. Anwander, in Applied Homogeneous Catalysis with Organometallic Compounds, Vol. 2 (Eds.: B. Cornils, W. Hermann), VCH, Weinheim (Germany), 1997, pp. 866-892; b) E. A. Bijpost, R. Duchateau, J. H. Teuben, J. Mol. Catal. 1995, 95, 121; c) K. N. Harrison, T. J. Marks, J. Am. Chem. Soc. 1992, 114, 9220.
50. For examples of catalytic activity of organolanthanides in hydroboration, see: a) R. Anwander, in Applied Homogeneous Catalysis with Organometallic Compounds, Vol. 2 (Eds.: B. Cornils, W. Hermann), VCH, Weinheim (Germany), 1997, pp. 866-892; b) E. A. Bijpost, R. Duchateau, J. H. Teuben, J. Mol. Catal. 1995, 95, 121; c) K. N. Harrison, T. J. Marks, J. Am. Chem. Soc. 1992, 114, 9220.
51. For examples of catalytic activity of organolanthanides in hydroboration, see: a) R. Anwander, in Applied Homogeneous Catalysis with Organometallic Compounds, Vol. 2 (Eds.: B. Cornils, W. Hermann), VCH, Weinheim (Germany), 1997, pp. 866-892; b) E. A. Bijpost, R. Duchateau, J. H. Teuben, J. Mol. Catal. 1995, 95, 121; c) K. N. Harrison, T. J. Marks, J. Am. Chem. Soc. 1992, 114, 9220.
52. For examples of catalytic activity of organolanthanides in ring-opening Ziegler polymerizations, see: a) L. Jia, X. Yang, A. M. Seyam, I. D. L. Albert, P.-F. Fu, S. Yang, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 7900; b) X. Yang, A. M. Seyam, P.-F. Fu, T. J. Marks, Macromolecules 1994, 27, 4625.
53. For examples of catalytic activity of organolanthanides in ring-opening Ziegler polymerizations, see: a) L. Jia, X. Yang, A. M. Seyam, I. D. L. Albert, P.-F. Fu, S. Yang, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 7900; b) X. Yang, A. M. Seyam, P.-F. Fu, T. J. Marks, Macromolecules 1994, 27, 4625.
54. For examples of catalytic activity of organoactinides in C-H activation processes, see: a) G. M. Smith, J. D. Carpenter, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 6805: b) J. W. Bruno, G. M. Smith, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 40; c) C. M. Fendrick, L. D. Schertz, V. W. Day, T. J. Marks, Organometallics 1988, 7, 1828.
55. For examples of catalytic activity of organoactinides in C-H activation processes, see: a) G. M. Smith, J. D. Carpenter, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 6805: b) J. W. Bruno, G. M. Smith, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 40; c) C. M. Fendrick, L. D. Schertz, V. W. Day, T. J. Marks, Organometallics 1988, 7, 1828.
56. For examples of catalytic activity of organoactinides in C-H activation processes, see: a) G. M. Smith, J. D. Carpenter, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 6805: b) J. W. Bruno, G. M. Smith, T. J. Marks, J. Am. Chem. Soc. 1986, 108, 40; c) C. M. Fendrick, L. D. Schertz, V. W. Day, T. J. Marks, Organometallics 1988, 7, 1828.
57. For examples of catalytic activity of organoactinides in hydrogenation, see: Z. Lin, T. J. Marks, J. Am. Chem. Soc, 1990, 112, 5515, and references therein.
58. For examples of catalytic activity of organoactinides in hydroamination, see: a) T. Straub, A. Haskel, T. G. Neyroud, M. Kapon, M. Botoshansky, M. S. Eisen, Organometallics 2001, 20, 5017; b) A. Haskel, T. Straub, M. S. Eisen, Organometallics 1996, 15, 3773; c) T. Straub, W. Frank, G. J. Reiss, M. S. Eisen, J. Chem. Soc. Dalton Trans. 1996, 2541.
59. For examples of catalytic activity of organoactinides in hydroamination, see: a) T. Straub, A. Haskel, T. G. Neyroud, M. Kapon, M. Botoshansky, M. S. Eisen, Organometallics 2001, 20, 5017; b) A. Haskel, T. Straub, M. S. Eisen, Organometallics 1996, 15, 3773; c) T. Straub, W. Frank, G. J. Reiss, M. S. Eisen, J. Chem. Soc. Dalton Trans. 1996, 2541.
60. For examples of catalytic activity of organoactinides in hydroamination, see: a) T. Straub, A. Haskel, T. G. Neyroud, M. Kapon, M. Botoshansky, M. S. Eisen, Organometallics 2001, 20, 5017; b) A. Haskel, T. Straub, M. S. Eisen, Organometallics 1996, 15, 3773; c) T. Straub, W. Frank, G. J. Reiss, M. S. Eisen, J. Chem. Soc. Dalton Trans. 1996, 2541.
61. For examples of catalytic activity of organoactinides in hydrosilylation, see: a) A. K. Dash, J. Q. Wang, M. S. Eisen, Organometallics 1999, 18, 4724; b) A. K. Dash, I. Gourevich, J. Q. Wang, J. Wang, M. Kapon, M. S. Eisen, Organometallics 2001, 20, 5084; c) M. S. Eisen, Proceedings of the XVIIIth International Conference on Organometallic Chemistry, Munich, Germany, 1998, p. B11; d) J. Q. Wang, M. S. Eisen, Proceedings of the 11th International Symposium on Homogeneous Catalysis, St. Andrews (Scotland), 1998, p. 82.
62. For examples of catalytic activity of organoactinides in hydrosilylation, see: a) A. K. Dash, J. Q. Wang, M. S. Eisen, Organometallics 1999, 18, 4724; b) A. K. Dash, I. Gourevich, J. Q. Wang, J. Wang, M. Kapon, M. S. Eisen, Organometallics 2001, 20, 5084; c) M. S. Eisen, Proceedings of the XVIIIth International Conference on Organometallic Chemistry, Munich, Germany, 1998, p. B11; d) J. Q. Wang, M. S. Eisen, Proceedings of the 11th International Symposium on Homogeneous Catalysis, St. Andrews (Scotland), 1998, p. 82.
63. For examples of catalytic activity of organoactinides in hydrosilylation, see: a) A. K. Dash, J. Q. Wang, M. S. Eisen, Organometallics 1999, 18, 4724; b) A. K. Dash, I. Gourevich, J. Q. Wang, J. Wang, M. Kapon, M. S. Eisen, Organometallics 2001, 20, 5084; c) M. S. Eisen, Proceedings of the XVIIIth International Conference on Organometallic Chemistry, Munich, Germany, 1998, p. B11; d) J. Q. Wang, M. S. Eisen, Proceedings of the 11th International Symposium on Homogeneous Catalysis, St. Andrews (Scotland), 1998, p. 82.
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89. For selected hydroamination reactions promoted by transition complexes, see: a) M. Beller, H. Trauthwein. M. Eichberger, C. Breindl, J. Herwig, T. E. Müller, O. R. Thiel, Chem. Eur. J. 1999, 5, 1306; b) T. E. Müller, A.-K. Pleier, J. Chem. Soc. Dalton Trans. 1999, 583; c) T. E. Müller, M. Grosche, E. Herdtweck, A.-K. Pleier, E. Walter, Y.-K. Yan, Organometallics 2000, 19, 170; d) H. M. Senn, P. E. Blöchl, A. Togni, J. Am. Chem. Soc. 2000. 122, 4098; e) C. Cao, J. T. Ciszewski, A. L. Odom, Organometallics 2001, 20, 5011; f) Y. Shi, J. T. Ciszewski, A. L. Odom, Organometallics 2001, 20, 3967.
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