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Volumn 23, Issue 1, 2004, Pages 117-126

C-C bond cleavage of acetonitrile by a carbonyl iron complex with a silyl ligand

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ACTIVATION ENERGY; ADDITION REACTIONS; CARBON; CHEMICAL ACTIVATION; CHEMICAL BONDS; NUMERICAL METHODS; PHOTOCHEMICAL REACTIONS; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; X RAY SPECTROSCOPY;

EID: 1642454928     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0208319     Document Type: Article
Times cited : (118)

References (56)
  • 39
    • 1642451463 scopus 로고    scopus 로고
    • note
    • 3 groups being cis to each other as an intermediate.
  • 40
    • 1642533265 scopus 로고    scopus 로고
    • note
    • 3 group, the hydrogen atom of the newly formed Fe-H bond of 26 can also migrate back to the carbene ligand. The activation energy needed for this was the same as that for the 26 to 27 conversion. However, the reaction profile consisting of the hydrogen migration product that leads to the agostic complex 28 was placed at higher energy level than that described in the reaction profile depicted in Figure 9. So we do not describe this path in detail.
  • 46
    • 1642533263 scopus 로고
    • A crystal structure analysis package
    • Molecular Structure Corporation: The Woodlands, TX
    • teXsan, A Crystal Structure Analysis Package; Molecular Structure Corporation: The Woodlands, TX, 1985 and 1992.
    • (1985) TeXsan


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.