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Volumn 128, Issue 25, 2006, Pages 8152-8153

Rh(I)-catalyzed silylation of aryl and alkenyl cyanides involving the cleavage of C-C and Si-Si bonds

Author keywords

[No Author keywords available]

Indexed keywords

2 NAPHTHONITRILE; CYANIDE; HEXAMETHYLDISILANE; NAPHTHALENE DERIVATIVE; RHODIUM; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 33745676767     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja062745w     Document Type: Article
Times cited : (159)

References (34)
  • 27
    • 0034245862 scopus 로고    scopus 로고
    • For reviews on Si-Si bond activation, see: (a) Suginome, M.; Ito, Y. Chem. Rev. 2000, 100, 3221.
    • (2000) Chem. Rev. , vol.100 , pp. 3221
    • Suginome, M.1    Ito, Y.2
  • 29
    • 33745640102 scopus 로고    scopus 로고
    • note
    • Two mechanisms may be possible for this step: (1) via σ-bond metathesis and (2) via oxidative addition of disilane, followed by reductive elimination of alkyl(aryl)silane.
  • 32
    • 33745665134 scopus 로고    scopus 로고
    • note
    • 8. Resonances observed were in agreement with those of an authentic sample (-12.73 ppm).
  • 34
    • 0034536964 scopus 로고    scopus 로고
    • (b) Gooßen, L. J.; Ferwanah, A.-R. Synlett 2000, 1801. These reactions require bases, such as KF, for the activation of a Si-Si bond.
    • (2000) Synlett , pp. 1801
    • Gooßen, L.J.1    Ferwanah, A.-R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.