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33745640102
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note
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Two mechanisms may be possible for this step: (1) via σ-bond metathesis and (2) via oxidative addition of disilane, followed by reductive elimination of alkyl(aryl)silane.
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32
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33745665134
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note
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8. Resonances observed were in agreement with those of an authentic sample (-12.73 ppm).
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33
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0034619189
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For recent examples of the catalytic synthesis of arylsilanes from aryl halides and hexamethyldisilane, see: (a) Shirakawa, E.; Kurahashi, T.; Yoshida, H.; Hiyama, T. Chem. Commun. 2000, 1895.
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(b) Gooßen, L. J.; Ferwanah, A.-R. Synlett 2000, 1801. These reactions require bases, such as KF, for the activation of a Si-Si bond.
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Synlett
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Gooßen, L.J.1
Ferwanah, A.-R.2
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