Pyrrolidine and piperidine formation via copper(II) carboxylate-promoted intramolecular carboamination of unactivated olefins: Diastereoselectivity and mechanism

Journal of Organic Chemistry

Volumn 72, Issue 10, 2007, Pages 3896-3905

  Sherman, Eric S ^a   Fuller, Peter H ^a   Kasi, Dhanalakshmi ^a   Chemler, Sherry R ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHEMICAL BONDS; COPPER COMPOUNDS; CYCLIZATION; OLEFINS; STEREOSELECTIVITY; SYNTHESIS (CHEMICAL);

COPPER CARBOXYLATE; INTRAMOLECULAR ADDITION; INTRAMOLECULAR CARBOAMINATION; OXIDATIVE CYCLIZATION;

AMINES;

ALKENE; ANILINE DERIVATIVE; CARBON; CARBOXYLIC ACID DERIVATIVE; COPPER; NITROGEN; PIPERIDINE; PROLINE DERIVATIVE; REAGENT; SULFONAMIDE;

AMINATION; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CYCLIZATION; HEATING; METHODOLOGY; OXIDATION; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION;

ALKENES; AMINATION; CARBOXYLIC ACIDS; COPPER; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; FREE RADICALS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NITROGEN; OXIDATION-REDUCTION; PIPERIDINES; PYRROLIDINES; SOLVENTS; STEREOISOMERISM; SULFONAMIDES; TEMPERATURE; WATER;

EID: 34248572954     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo070321u     Document Type: Article

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