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Volumn 126, Issue 6, 2004, Pages 1622-1623

Palladium-Catalyzed Intramolecular Asymmetric Hydroamination of Alkynes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; AMINE; HETEROCYCLIC NITRO COMPOUND; PALLADIUM;

EID: 1242291816     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039774g     Document Type: Article
Times cited : (219)

References (33)
  • 27
    • 85039573654 scopus 로고    scopus 로고
    • note
    • The reaction shown in eq 1 is a formal 1,3-addition of N-H to a triple bond involving the shift of one proton similar to known allylic amination reactions.
  • 28
    • 85039576984 scopus 로고    scopus 로고
    • note
    • The starting material 1d was recovered in ca. 40% yield.
  • 30
    • 85039576540 scopus 로고    scopus 로고
    • note
    • Efforts to determine the ee of 2e were undertaken using GC with different chiral columns. However, no satisfactory separation of enantiomers could be obtained.
  • 31
    • 85039568554 scopus 로고    scopus 로고
    • note
    • The synthesis of seven-membered rings was not achieved under these conditions.
  • 33
    • 85039562853 scopus 로고    scopus 로고
    • note
    • 8 was used because the determination of the ee of the product from the corresponding Nf-protected compound proved difficult.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.