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There has been a recent review of C-H activation in NHC complexes: Crudden, C. M.; Allen, D. P. Coord. Chem. Rev. 2004, 248, 2247.
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For other examples, see: (a) Corberán, R.; Sanaú, M.; Peris, E. Organometallics 2006, 25, 4002.
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(d) Cariou, R.; Fischmeister, C.; Toupet, L.; Dixneuf, P. H. Organometallics 2006, 25, 2126.
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(e) Burling, S.; Mahon, M. F.; Powell, R. E.; Whittlesey, M. K.; Williams, J. M. J. J. Am. Chem. Soc. 2006, 128, 13702.
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(g) Scott, N. M.; Pons, V.; Stevens, E. D.; Heinekey, D. M.; Nolan, S. P. Angew. Chem., Int. Ed. 2005, 44, 2512.
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(n) Trnka, T. M.; Morgan, J. P.; Sanford, M. S.; Wilhelm, T. E.; Scholl, M.; Choi, T.-L.; Deng, S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 2546.
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(u) Hitchcock, P. B.; Lappert, M. F.; Pye, P. L. J. Chem. Soc., Chem. Commun. 1977, 196.
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Hitchcock, P.B.1
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94
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33645458949
-
-
Competitive intramolecular C-H activation and catalytic, intermolecular H/D exchange has very recently been described: Corberán, R.; Sanaú, M.; Peris, E. J. Am. Chem. Soc. 2006, 128, 3974.
-
Competitive intramolecular C-H activation and catalytic, intermolecular H/D exchange has very recently been described: Corberán, R.; Sanaú, M.; Peris, E. J. Am. Chem. Soc. 2006, 128, 3974.
-
-
-
-
95
-
-
33847293492
-
-
Typically, heating at 70 °C in toluene for 16-20 h was sufficient to consume Ru(PPh3)3(CO)H2, although the reaction with IMe4 required 3 days at 80 °C to give complete conversion into a mixture of 4, Ru(IMe4)2(PPh 3, CO)H2, and Ru(IMe4)3(CO)H 2
-
2.
-
-
-
-
96
-
-
33847308369
-
-
3 ligands with a cis disposition. Complete isomerization to the major isomer occurs upon standing for 16 h at room temperature.
-
3 ligands with a cis disposition. Complete isomerization to the major isomer occurs upon standing for 16 h at room temperature.
-
-
-
-
97
-
-
29044436491
-
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Burling, S.; Kociok-Köhn, G.; Mahon, M. F.; Whittlesey, M. K.; Williams, J. M. J. Organometallics 2005, 24, 5868.
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Burling, S.1
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Whittlesey, M.K.4
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-
98
-
-
33847291076
-
-
mesityl bonds in 1 was also investigated. See the Supporting Information for full details.
-
mesityl bonds in 1 was also investigated. See the Supporting Information for full details.
-
-
-
-
100
-
-
0000787564
-
-
Adkins, H.; Elofson, R. M.; Rossow, A. G.; Robinson, C. C. J. Am. Chem. Soc. 1949, 71, 3622.
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Adkins, H.1
Elofson, R.M.2
Rossow, A.G.3
Robinson, C.C.4
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101
-
-
33847337155
-
-
2: Herrmann, W. A.; Weskamp, T.; Böhm, V. P. W. Adv. Organomet. Chem. 2002, 48, 1.
-
2: Herrmann, W. A.; Weskamp, T.; Böhm, V. P. W. Adv. Organomet. Chem. 2002, 48, 1.
-
-
-
-
102
-
-
33847325501
-
-
See the Supporting Information for tables of conversion data
-
See the Supporting Information for tables of conversion data.
-
-
-
-
103
-
-
33847328124
-
-
No difference in reactivity was seen between 9 and the dihydride precursor 8.
-
No difference in reactivity was seen between 9 and the dihydride precursor 8.
-
-
-
-
104
-
-
33847248178
-
-
3 added to promote the initial C-H activation. No reduction in conversion through to product alkanes was found when catalysis was performed with alkene excluded.
-
3 added to promote the initial C-H activation. No reduction in conversion through to product alkanes was found when catalysis was performed with alkene excluded.
-
-
-
-
105
-
-
33847263245
-
-
This is clear from the 2-week reaction time that is typically needed for the synthesis of 1
-
This is clear from the 2-week reaction time that is typically needed for the synthesis of 1.
-
-
-
-
106
-
-
33847311984
-
-
No exchange was observed without warming
-
No exchange was observed without warming.
-
-
-
-
107
-
-
33847256140
-
-
We have identified this compound, in the THF solution used for the reaction, via 29Si-1H correlation NMR
-
1H correlation NMR.
-
-
-
-
108
-
-
33847295932
-
-
Our results cannot establish whether phosphine loss occurs only from one position within the coordination sphere
-
Our results cannot establish whether phosphine loss occurs only from one position within the coordination sphere.
-
-
-
-
110
-
-
65649098906
-
-
Herrmann, W. A.; Kocher, C.; Goossen, L. J.; Artus, G. R. J. Chem. Eur. J. 1996, 2, 1627.
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Herrmann, W.A.1
Kocher, C.2
Goossen, L.J.3
Artus, G.R.J.4
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111
-
-
0033579627
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Arduengo, A. J.; Krafczyk, R.; Schmutzler, R.; Craig, H. A.; Goerlich, J. R.; Marshall, W. J.; Unverzagt, M. Tetrahedron 1999, 55, 14523.
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Arduengo, A.J.1
Krafczyk, R.2
Schmutzler, R.3
Craig, H.A.4
Goerlich, J.R.5
Marshall, W.J.6
Unverzagt, M.7
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112
-
-
0037011774
-
-
2 is reported in: Niehues, M.; Kehr, G.; Erker, G.; Wibbeling, B.; Fröhlich, R.; Blacque, O.; Berke, H. J. Organomet. Chem. 2002, 663, 192.
-
2 is reported in: Niehues, M.; Kehr, G.; Erker, G.; Wibbeling, B.; Fröhlich, R.; Blacque, O.; Berke, H. J. Organomet. Chem. 2002, 663, 192.
-
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113
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0003038887
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Ahmad, N.; Levison, J. J.; Robinson, S. D.; Uttley, M. F. Inorg. Synth. 1974, 15, 48.
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Ahmad, N.1
Levison, J.J.2
Robinson, S.D.3
Uttley, M.F.4
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