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Volumn 238-239, Issue , 2003, Pages 315-331

De Novo design in organometallic chemistry: Stabilizing iridium(V)

Author keywords

Carbon hydrogen bond activation; Density functional theory; Ir(V) intermediates; Iridium complexes; Organometallic reaction mechanisms; Oxidative addition

Indexed keywords

ALKANE DERIVATIVE; IRIDIUM COMPLEX; LIGAND; ORGANOMETALLIC COMPOUND; PHOSPHINE DERIVATIVE; SILANE DERIVATIVE; TIN DERIVATIVE;

EID: 0037656134     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0010-8545(02)00329-6     Document Type: Review
Times cited : (39)

References (119)
  • 65
  • 68
    • 4244064972 scopus 로고
    • (b) A. Höllwarth, M. Böhme, S. Dapprich, A.W. Ehlers, A. Gobbi, V. Jonas, K.F. Köhler, R. Stegmann, A. Veldkamp, G. Frenking, Chem. Phys. Lett. 208 (1993) 237; 224 (1994) 603.
    • (1994) Chem. Phys. Lett. , vol.224 , pp. 603
  • 78
    • 0037635655 scopus 로고    scopus 로고
    • note
    • There are two dimethyldihydride Ir(V) isomers - one cis dihydride, one trans - the cis isomer is lower in energy.
  • 102
    • 0037973855 scopus 로고    scopus 로고
    • note
    • -1), and it did not improve the results either.
  • 103
    • 0031575641 scopus 로고    scopus 로고
    • This ligand has been previously considered theoretically. (a) R.R. Sauers, Tetrahedron 53 (1997) 2357.
    • (1997) Tetrahedron , vol.53 , pp. 2357
    • Sauers, R.R.1
  • 106
    • 78649745802 scopus 로고    scopus 로고
    • One such modified Cp ligand system (with the phosphine connected to the Cp ring by a substituted ethyl linkage) has been reported by Mobley and Bergman. T.A. Mobley, R.G. Bergman, J. Am. Chem. Soc. 120 (1998) 3253.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 3253
    • Mobley, T.A.1    Bergman, R.G.2
  • 107
    • 0037635620 scopus 로고    scopus 로고
    • note
    • Stable Ir(V) intermediate analogues are also formed from the reaction of cycloalkanes with the hydride analogue starting material by carbon-carbon bond activation forming metallocycloalkanes.
  • 115
    • 0038650170 scopus 로고    scopus 로고
    • note
    • -1 (ΔE, BS1) less stable than the Ir(III) reactant and methane.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.