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There are two dimethyldihydride Ir(V) isomers - one cis dihydride, one trans - the cis isomer is lower in energy.
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This ligand has been previously considered theoretically. (a) R.R. Sauers, Tetrahedron 53 (1997) 2357.
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78649745802
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One such modified Cp ligand system (with the phosphine connected to the Cp ring by a substituted ethyl linkage) has been reported by Mobley and Bergman. T.A. Mobley, R.G. Bergman, J. Am. Chem. Soc. 120 (1998) 3253.
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Stable Ir(V) intermediate analogues are also formed from the reaction of cycloalkanes with the hydride analogue starting material by carbon-carbon bond activation forming metallocycloalkanes.
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0038650170
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-1 (ΔE, BS1) less stable than the Ir(III) reactant and methane.
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-
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