Binding two C2 units to an electron-rich transition-metal center: The interplay of alkyne(alkynyl), bisalkynyl(hydrido), alkynyl(vinylidene), alkynyl(allene), alkynyl(olefin), and alkynyl(enyne) rhodium complexes

Organometallics

Volumn 23, Issue 24, 2004, Pages 5713-5728

  Schafer, Martin ^a   Wolf, Justin ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; DERIVATIVES; INFRARED SPECTROSCOPY; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; PHOTOLYSIS; RHODIUM COMPOUNDS; TRANSITION METALS;

CHELATE COMPOUNDS; GRIGNARD REAGENTS; HEXANE; HYDRIDOMETAL DERIVATIVES;

ORGANOMETALLICS;

EID: 10044256639     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049389f     Document Type: Article

References (47)

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43. For recent theoretical work on the acetylene to vinylidene isomerization see inter alia: (a) Wakatsuki, Y.; Koga, N.; Yamazaki, H.; Morokuma, K. J. Am. Chem. Soc. 1994, 116, 8105-8111. (b) Stegmann, R.; Frenking, G. Organometallics 1998, 17, 2089-2095. (c) Oliván, M.; Clot, E.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 3091-3100. (d) Peréz-Carreno, E.; Paoli, P.; Ienco, A.; Mealli, C. Eur. J. Inorg. Chem. 1999, 1315-1324. (e) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Peréz-Carreno, E.; García-Granda, S. Organometallics 1999, 18, 2821-2832. (f) García-Yebra, C.; López-Mardomingo, C.; Fajardo, M.; Antinolo, A.; Otero, A.; Rodríguez, A.; Vallat, A.; Lucas, D.; Mugnier, Y.; Carbó, J. J.; Lledós, A.; Bo, C, Organometallics 2000, 19, 1749-1765. (g) De Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2002, 27, 2715-2723.
44. For recent theoretical work on the acetylene to vinylidene isomerization see inter alia: (a) Wakatsuki, Y.; Koga, N.; Yamazaki, H.; Morokuma, K. J. Am. Chem. Soc. 1994, 116, 8105-8111. (b) Stegmann, R.; Frenking, G. Organometallics 1998, 17, 2089-2095. (c) Oliván, M.; Clot, E.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 3091-3100. (d) Peréz-Carreno, E.; Paoli, P.; Ienco, A.; Mealli, C. Eur. J. Inorg. Chem. 1999, 1315-1324. (e) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Peréz-Carreno, E.; García-Granda, S. Organometallics 1999, 18, 2821-2832. (f) García-Yebra, C.; López-Mardomingo, C.; Fajardo, M.; Antinolo, A.; Otero, A.; Rodríguez, A.; Vallat, A.; Lucas, D.; Mugnier, Y.; Carbó, J. J.; Lledós, A.; Bo, C, Organometallics 2000, 19, 1749-1765. (g) De Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2002, 27, 2715-2723.
45. For recent theoretical work on the acetylene to vinylidene isomerization see inter alia: (a) Wakatsuki, Y.; Koga, N.; Yamazaki, H.; Morokuma, K. J. Am. Chem. Soc. 1994, 116, 8105-8111. (b) Stegmann, R.; Frenking, G. Organometallics 1998, 17, 2089-2095. (c) Oliván, M.; Clot, E.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 3091-3100. (d) Peréz-Carreno, E.; Paoli, P.; Ienco, A.; Mealli, C. Eur. J. Inorg. Chem. 1999, 1315-1324. (e) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Peréz-Carreno, E.; García-Granda, S. Organometallics 1999, 18, 2821-2832. (f) García-Yebra, C.; López-Mardomingo, C.; Fajardo, M.; Antinolo, A.; Otero, A.; Rodríguez, A.; Vallat, A.; Lucas, D.; Mugnier, Y.; Carbó, J. J.; Lledós, A.; Bo, C, Organometallics 2000, 19, 1749-1765. (g) De Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2002, 27, 2715-2723.
46. For recent theoretical work on the acetylene to vinylidene isomerization see inter alia: (a) Wakatsuki, Y.; Koga, N.; Yamazaki, H.; Morokuma, K. J. Am. Chem. Soc. 1994, 116, 8105-8111. (b) Stegmann, R.; Frenking, G. Organometallics 1998, 17, 2089-2095. (c) Oliván, M.; Clot, E.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 3091-3100. (d) Peréz-Carreno, E.; Paoli, P.; Ienco, A.; Mealli, C. Eur. J. Inorg. Chem. 1999, 1315-1324. (e) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Peréz-Carreno, E.; García-Granda, S. Organometallics 1999, 18, 2821-2832. (f) García-Yebra, C.; López-Mardomingo, C.; Fajardo, M.; Antinolo, A.; Otero, A.; Rodríguez, A.; Vallat, A.; Lucas, D.; Mugnier, Y.; Carbó, J. J.; Lledós, A.; Bo, C, Organometallics 2000, 19, 1749-1765. (g) De Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2002, 27, 2715-2723.
47. For recent theoretical work on the acetylene to vinylidene isomerization see inter alia: (a) Wakatsuki, Y.; Koga, N.; Yamazaki, H.; Morokuma, K. J. Am. Chem. Soc. 1994, 116, 8105-8111. (b) Stegmann, R.; Frenking, G. Organometallics 1998, 17, 2089-2095. (c) Oliván, M.; Clot, E.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 3091-3100. (d) Peréz-Carreno, E.; Paoli, P.; Ienco, A.; Mealli, C. Eur. J. Inorg. Chem. 1999, 1315-1324. (e) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Peréz-Carreno, E.; García-Granda, S. Organometallics 1999, 18, 2821-2832. (f) García-Yebra, C.; López-Mardomingo, C.; Fajardo, M.; Antinolo, A.; Otero, A.; Rodríguez, A.; Vallat, A.; Lucas, D.; Mugnier, Y.; Carbó, J. J.; Lledós, A.; Bo, C, Organometallics 2000, 19, 1749-1765. (g) De Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2002, 27, 2715-2723.