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19F NMR quartets was observed upon warming, but the diasteromeric ratio changed to about 1:2 at 338 K. The phenomenon is reversible upon cooling.
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19F NMR quartets was observed upon warming, but the diasteromeric ratio changed to about 1:2 at 338 K. The phenomenon is reversible upon cooling.
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Complex 5 is stable overnight at 220 K and decomposes within 6 h at 270 K, and more rapidly at room temperature.
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Complex 5 is stable overnight at 220 K and decomposes within 6 h at 270 K, and more rapidly at room temperature.
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A similar DFT study was also performed on the neutral complexes H and 3, and gave results consistent with spectroscopic observations.
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A similar DFT study was also performed on the neutral complexes H and 3, and gave results consistent with spectroscopic observations.
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Catalytic combinations based on MAO activator were not explored because of the possible transfer of (OZZOR)2- ligands between group 4 metal and aluminum centers; see reference [10b
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n=2.6. See reference [11].
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