Ethylenebis(salicylideneiminato)zirconium dichloride: Crystal structure and use as a heterogeneous catalyst in the polymerization of ethylene

Macromolecules

Volumn 30, Issue 2, 1997, Pages 171-175

  Repo, Timo ^a   Klinga, Martti ^a   Pietikäinen, Pekka ^a   Leskelä, Markku ^a   Uusitalo, Anne Marja ^b   Pakkanen, Tuula ^b   Hakala, Kimmo ^c   Aaltonen, Päivi ^c   Löfgren, Barbro ^c  

^a UNIVERSITY OF HELSINKI   (Finland)

^b UNIVERSITY OF EASTERN FINLAND   (Finland)

^c AALTO UNIVERSITY   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CATALYSTS; COMPOSITION EFFECTS; CRYSTAL STRUCTURE; DEPOSITION; HEATING; IONS; MOLECULES; POLYMERIZATION; PRESSURE EFFECTS; SILICA; TOLUENE;

LIGANDS; TETRAHYDROFURAN (THF);

ZIRCONIUM COMPOUNDS;

EID: 0030821086     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma960512r     Document Type: Article

References (50)

1. Calligaris, M.; Randaccio, L. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Vol. 2, p 715.
2. (a) Srinivasan, K.; Perrier, S.; Kochi, J. K. J. Am. Chem. Soc. 1986, 108, 2309.
3. (b) Jorgensen, A. K. Chem. Rev. 1989, 89, 431.
4. (c) Xheng, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296.
5. (d) Jacobsen, E. N.; Zhang, W.; Muci, A. R.; Ecker, J. R.; Deng, L. J. Am. Chem. Soc. 1991, 113, 7063.
6. (e) Mukaiyama, T.; Yamada, T.; Nagata, T.; Imagawa, K. Chem. Lett. 1991, 327.
7. (f) Deng, L.; Jacobsen, E. N. J. Org. Chem. 1992, 57, 4320.
8. (g) De, B. B.; Lohray, B. B.; Dhal, P. K. Tetrahedron Lett. 1993, 34, 2371.
9. Rihter, B.; SriHari, S.; Hubter, S; Masnovi, J. J. Am. Chem. Soc. 1993, 115, 3918.
10. (a) Sasaki, C.; Nakajima, K.; Kojima, M.; Fujita, J. Bull. Chem. Soc. Jpn. 1991, 64, 1318.
11. (b) Bolm C.; Bienewald, F. Angew. Chem., Int. Ed. Engl. 1995, 34, 2640.
12. (a) Nitta, H.; Yu, D.; Kudo, M.; Mori, A.; Inoue, S. J. Am. Chem. Soc. 1992, 114, 7969.
13. (b) Hayashi, M.; Miyamoto, Y.; Inoue, T.; Oguni, N. J. Org. Chem. 1993, 58, 1515.
14. Hollis, T. K.; Oldenkirk, W.; Robinson, N. P.; Whelan, J.; Bosnich, B. Tetrahedron, 1993, 49, 5415.
15. (a) Gupta, S. R.; Tandon, J. P. Z. Naturforsch. b 1970, 25, 1231.
16. (b) Gilli, G.; Cruickshank, D. W. J.; Beddoes, R. L.; Mills, O. S. Acta Crystallogr. 1972, B28, 1889.
17. (c) Pasquali, M.; Marchetti, F.; Landi, A.; Floriani, C. J. Chem. Soc., Dalton Trans. 1978, 545.
18. (d) Dell'Amico, G.; Marchetti, F.; Floriani, C. J. Chem. Soc. Dalton Trans. 1982, 2197.
19. (e) Solari, E.; Corazza, F.; Floriani, C.; Chiesi-Villa, A.; Guasti, C. J. Chem. Soc. Dalton Trans. 1990, 1345.
20. (f) Repo, T.; Klinga, M.; Leskelä, M.; Pietikäinen, P.; Brunow, G. Acta Crystallogr. 1996, C52, 2742.
21. (a) Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Chem. Soc., Dalton Trans. 1992, 367.
22. (b) Carroll, K. M.; Schwartz, J.; Ho, D. M. Inorg. Chem. 1994, 33, 2707.
23. (a) Bradley, D. C.; Hursthouse, M. R.; Rendall,. I. F. J. Chem. Soc., Chem. Comm. 1970, 368.
24. (b) Archer, R. D.; Day, R. O.; Illingsworth, M. L. Inorg. Chem. 1979, 18, 2908.
25. (c) Fay, R. C. In Comprehensive Coordination Chemistry, Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Vol. 3, p 434.
26. (d) Illingsworth, M. L.; Cleary, B. P.; Jensen, A. J.; Schwartz, L. J.; Rheingold, A. L. Inorg. Chim. Acta 1993, 207, 147.
27. (e) Leung, W.-H.; Chan, E. Y. Y.; Chow, E. K. F.; Williams, I. D.; Peng, S. M. J. Chem. Soc., Dalton Trans. 1996, 1229.
28. Corazza, F.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Chem. Soc., Dalton Trans. 1990, 1335.
29. (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem. Int. Ed. Engl. 1995, 34, 1143 and references therein.
30. (b) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255 and references therein.
31. Tjaden, E. B.; Swenson, D. C.; Jordan, R. F.; Petersen, J. L. Organometallics 1995, 14, 371.
32. Tjaden, E. B.; Jordan, R. F. Macromol. Symp. 1995, 89, 231.
33. TEXSAN: Single Crystal Structure Analysis Software, Molecular Structure Corp., The Woodlands, TX, 1993.
34. Sheldrick, G. M. SHELXTL, Release 4.1, Siemens Analytical X-ray Instruments Inc., Madison, WI, 1990.
35. Sheldrick, G. M. SHELXL-93, University of Göttingen, Germany.
36. 2 = 0.1072, S = 1.026, prismatic, pale yellow crystal, 0.40 × 0.30 × 0.20 mm.
37. Calligaris, M.; Nardin, G.; Randaccio, L. Coord. Chem. Rev. 1972, 7, 385.
38. 6). Proton signals of THF [δ 1.79 (m, 4H), 3.65 (m, 4H)] are missing.
39. (a) Aaltonen, P.; Seppälä, J.; Matilainen, L.; Leskelä, M. Macromolecules 1994, 27, 3136.
40. (b) Matilainen, L.; Klinga, M.; Leskelä, M. J. Chem. Soc., Dalton Trans. 1996, 219.
41. (c) Van der Linden, A.; Schaverien, C. J.; Meijboom, N.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
42. Kaminsky, W.; Bark, A.; Steiger, R. J. Mol. Cat. 1992, 74, 109
43. Kaminsky, W.; Renner F. Makromol. Chem., Rapid Commun. 1993, 14, 239.
44. Janiak, C.; Rieger B. Angew. Makromol. Chem. 1994, 215, 47.
45. Tait, P. J. T.; Monteiro, M. G. K. MetCon'95, Houston, TX, May 17-19, 1995.
46. Sacchi, M. C.; Zucchi, D.; Tritto, I.; Locatelli, P. Makromol. Rapid Commun. 1995, 16, 581
47. Tritto, I.; Li, S. X.; Sacchi, M. C.; Locatelli, P.; Zannoni, G. Macromolecules 1995, 28, 5358.
48. (a) Stehling, U.; Diebold, J.; Kristen, R.; Röll, W.; Brintzinger, H.-H.; Jüngling, S.; Mülhaupt, R; Langhauser, F. Organometallics 1994, 13, 964.
49. (b) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954.
50. (c) Chien, J. C. W.; Sugimoto, R. J. Polym. Sci. A 1991, 29, 459.