Coordination of alkenes and alkynes to a cationic d0 zirconocene alkoxide complex

Journal of the American Chemical Society

Volumn 125, Issue 11, 2003, Pages 3222-3223

  Stoebenau III, Edward J ^a   Jordan, Richard F ^a  

^a UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; CATION; METAL COMPLEX; ZIRCONIUM DERIVATIVE; ZIRCONOCENE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHELATION; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DISSOCIATION; EQUILIBRIUM CONSTANT; METAL BINDING; OLIGOMERIZATION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0037454327     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029963j     Document Type: Article

References (26)

1. (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
2. (b) Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253.
3. Horton, A. D. Chem. Commun. 1992. 185.
4. (a) Humphries, M. J.; Douthwaite, R. E.; Green, M. L. H. J. Chem. Soc., Dalton Trans. 2000, 2952.
5. (b) Witte, P. T.; Meetsma, A.; Hessen, B.; Budzelaar, P. H. M. J. Am. Chem. Soc. 1997, 119, 10561.
6. (c) Kress, J.; Osborn, J. A. Angew. Chem., Int. Ed. Engl. 1992, 31, 1585.
7. Curtis, M. A.; Finn, M. G.; Grimes, R. N. J. Organomet. Chem. 1998, 550, 469.
8. (a) Carpentier, J.-F.; Wu, Z.; Lee, C. W.; Strömberg, S.; Christopher, J. N.; Jordan, R. F. J. Am. Chem. Soc. 2000, 122, 7750.
9. (b) Wu, Z.; Jordan, R. F.; Petersen, J. L. J. Am. Chem. Soc. 1995, 117, 5867.
10. (c) Carpentier, J.-F.; Maryin, V. P.; Luci, J.; Jordan, R. F. J. Am. Chem. Soc. 2001, 123, 898.
11. (d) Galakhov, M. V.; Heinz, G.; Royo, P. Chem. Commun. 1998, 17.
12. (e) Brandow, C. G.; Mendiratta, A.; Bercaw, J. E. Organometallics 2001, 20, 4253.
13. (f) Casey, C. P.; Carpenetti, D. W., II; Sakurai, H. Organometallics 2001, 20, 4262 and references therein.
14. (g) Casey, C. P.; Klein, J. F.; Fagan, M. A. J. Am. Chem. Soc. 2000, 122, 4320 and references therein.
15. Temme, B.; Erker, G.; Fröhlich, R.; Grehl, M. Angew. Chem., Int. Ed. Engl. 1994, 33, 1480.
16. The existence of an yttrium-propylene adduct has been deduced from NMR line broadening effects. Casey, C. P.; Lee, T.-Y.; Tunge, J. A.; Carpenetti, D. W., II. J. Am. Chem. Soc. 2001, 123, 10762.
17. Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F.; Rogers, R. D. Organometallics 1998, 17, 382.
18. (a) Horton, A. D.; Orpen, A. G. Organometallics 1991, 10, 3910.
19. (b) Goodman, J. T.; Schrock, R. R. Organometallics 2001, 20, 5205.
20. + cation is very unlikely in RCl solution.
21. 4] have been crystallographically characterized. Wu, F.; Jordan, R. F., unpublished results.
22. 2]) ≈ 5.5 eu.
23. + species, see: (a) Schaper, F.; Geyer, A.; Brintzinger, H. H. Organometallics 2002, 21, 473. (b) Collins, S.; Koene, B. E.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2092.
24. + species, see: (a) Schaper, F.; Geyer, A.; Brintzinger, H. H. Organometallics 2002, 21, 473. (b) Collins, S.; Koene, B. E.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2092.
25. For other examples of cationic Zr(IV) CO complexes, see: Guo, Z.; Swenson, D. C.; Guram, A. S.; Jordan, R. F. Organometallics 1994, 13, 766 and references therein.
26. von Schenck, H.; Strömberg, S.; Zetterberg, K.; Ludwig, M.; Åkermark, B.; Svensson, M. Organometallics 2001, 20, 2813.