C2-symmetric fluorous diamino-dialkoxide complexes of early transition metals

Organometallics

Volumn 23, Issue 23, 2004, Pages 5450-5458

  Lavanant, Laurent ^a   Chou, Tsung Yi ^b   Chi, Yun ^b   Lehmann, Christian W ^d   Toupet, Loic ^c   Carpentier, Jean Fraņois ^a  

^a UMR 6509 Organometalliques et Catalyse Chimie et Electrochimie Moleculaires   (France)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^c NATIONAL TSING HUA UNIVERSITY   (Taiwan)

^d UNIVERSITÉ DE RENNES 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMPLEXATION; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; RING OPENING POLYMERIZATION; SINGLE CRYSTALS; SOLUTIONS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION ANALYSIS;

ELECTROPOSITIVE METALS; LIGANDS; ROOM TEMPERATURE (RT); STEREOISOMERS;

TRANSITION METALS;

EID: 9244222737     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0494364     Document Type: Article

References (73)

1. For reviews on post-metallocene complexes of groups 3-5 and the lanthanides related to polymerization, see: (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428. (b) Gibson, V. C.; Spitzmesser, S. K. Chem. Reu. 2003, 103, 283. (c) Gromada, J.; Mortreux, A.; Carpentier, J.-F. Coord. Chem. Rev. 2004, 248, 397. Corradini, P.; Guerra, G.; Cavallo, L. Ace. Chem. Res. 2004, 37, 231.
2. For reviews on post-metallocene complexes of groups 3-5 and the lanthanides related to polymerization, see: (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428. (b) Gibson, V. C.; Spitzmesser, S. K. Chem. Reu. 2003, 103, 283. (c) Gromada, J.; Mortreux, A.; Carpentier, J.-F. Coord. Chem. Rev. 2004, 248, 397. Corradini, P.; Guerra, G.; Cavallo, L. Ace. Chem. Res. 2004, 37, 231.
3. For reviews on post-metallocene complexes of groups 3-5 and the lanthanides related to polymerization, see: (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428. (b) Gibson, V. C.; Spitzmesser, S. K. Chem. Reu. 2003, 103, 283. (c) Gromada, J.; Mortreux, A.; Carpentier, J.-F. Coord. Chem. Rev. 2004, 248, 397. Corradini, P.; Guerra, G.; Cavallo, L. Ace. Chem. Res. 2004, 37, 231.
4. For reviews on post-metallocene complexes of groups 3-5 and the lanthanides related to polymerization, see: (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428. (b) Gibson, V. C.; Spitzmesser, S. K. Chem. Reu. 2003, 103, 283. (c) Gromada, J.; Mortreux, A.; Carpentier, J.-F. Coord. Chem. Rev. 2004, 248, 397. Corradini, P.; Guerra, G.; Cavallo, L. Ace. Chem. Res. 2004, 37, 231.
5. (a) Bradley, D. C.; Mehrotra, R. M.; Rothwell, I. P.; Singh, A. Alkoxo and Aryloxo Derivatives of Metals; Academic Press: London, 2001.
6. (b) Mehrotra, R. M.; Singh, A. Prog. Inorg. Chem. 1997, 46, 239.
7. (c) Hubert-Pfalzgraf, L. G. Coord. Chem. Rev. 1998, 178-180, 967.
8. For reviews on alkoxo and aryloxo chemistry of lanthanides, see: (a) Caulton, K. G.; Hubert-Pfalzgraf, L. G. Chem. Rev. 1990, 90, 969. (b) Mehrotra, R. C.; Singh, A.; Triptathi, U. M. Chem. Rev. 1991, 91, 1287.
9. For reviews on alkoxo and aryloxo chemistry of lanthanides, see: (a) Caulton, K. G.; Hubert-Pfalzgraf, L. G. Chem. Rev. 1990, 90, 969. (b) Mehrotra, R. C.; Singh, A.; Triptathi, U. M. Chem. Rev. 1991, 91, 1287.
10. Hubert-Pfalzgraf, L. G. New J. Chem. 1995, 19, 727. Anwander, R. Top. Curr. Chem. 1996, 279, 149. Piers, W. E.; Emslie, D. J. H. Coord. Chem. Rev. 2002, 233-234, 131. (e) Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Chem. Rev. 2002, 102, 1851.
11. Hubert-Pfalzgraf, L. G. New J. Chem. 1995, 19, 727. Anwander, R. Top. Curr. Chem. 1996, 279, 149. Piers, W. E.; Emslie, D. J. H. Coord. Chem. Rev. 2002, 233-234, 131. (e) Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Chem. Rev. 2002, 102, 1851.
12. Hubert-Pfalzgraf, L. G. New J. Chem. 1995, 19, 727. Anwander, R. Top. Curr. Chem. 1996, 279, 149. Piers, W. E.; Emslie, D. J. H. Coord. Chem. Rev. 2002, 233-234, 131. (e) Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Chem. Rev. 2002, 102, 1851.
13. Hubert-Pfalzgraf, L. G. New J. Chem. 1995, 19, 727. Anwander, R. Top. Curr. Chem. 1996, 279, 149. Piers, W. E.; Emslie, D. J. H. Coord. Chem. Rev. 2002, 233-234, 131. (e) Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Chem. Rev. 2002, 102, 1851.
14. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
15. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
16. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
17. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
18. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
19. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
20. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
21. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
22. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
23. For examples in group 4 chemistry see: (a) Balsells, J.; Carroll, P. J.; Walsh, P. J. Inorg. Chem. 2001, 40, 5568-5574. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706. (d) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 14, 3017. (e) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662. (f) Reimer, V.; Spanio, T. P.; Okuda, J.; Ebeling, H.; Tuchbreiter, A.; Mülhaupt, R. Inorg. Chim. Acta 2003, 345, 221. (g) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Am. Chem. Soc. 2003, 125, 4964 . (h) Capacchione, C.; Proto, A.; Ebeling, H.; Mülhaupt, R.; Manivannan, R.; Möller, K.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chem. 2004, 213, 137. (i) Pokken, S.; Spaniol, T. P.; Okuda, J. Organometallics 1907, 16, 4240. (j) Fokken, S.; Reichwald, F.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2002, 663, 158.
24. For examples in group 3 and lanthanide chemistry see: (a) Schaverien, C. J.; Meijboom, N.; Orpen, A. G. J. Chem. Soc., Chem. Commun. 1992, 124.
25. (b) Skinner, M. E. G.; Tyrell, B. R.; Ward, B. D.; Mountford, P. J. Organomet. Chem. 2002, 647, 145.
26. (c) Arnold, P. L.; Natrajan, L. S.; Hall, J. J.; Bird, S. J.; Wilson, C. J. Organomet. Chem. 2002, 647, 205. (d)
27. (d) Cai, C.-X.; Toupet, L.; Carpentier, J.-F. J. Organomet. Chem. 2003, 653, 131.
28. (e) Cai, C.-X.; Amgoune, A.; Lehmann, C. W.; Carpentier, J.-F. Chem. Commun. 2004, 330. (f)
29. Ma, H.; Spaniol, T. P.; Okuda, J. Dalton Trans. 2003, 4770.
30. Examples of groups 3-4 and lanthanide complexes bearing fluorinated alkoxide ligands: (a) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 12, 1907. (b) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 13, 7. Samuels, J. A.; Lobkovsky, E. B.; Streib, W. E.; Folting, K.; Huffman, J. C.; Zwanziger, J. W.; Caulton, K. G. J. Am. Chem. Soc. 1993, 115, 5093. (d) Tsukuhara, T.; Swenson, D, C.; Jordan, R. F. Organometallics 1997, 16, 3303.
31. Examples of groups 3-4 and lanthanide complexes bearing fluorinated alkoxide ligands: (a) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 12, 1907. (b) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 13, 7. Samuels, J. A.; Lobkovsky, E. B.; Streib, W. E.; Folting, K.; Huffman, J. C.; Zwanziger, J. W.; Caulton, K. G. J. Am. Chem. Soc. 1993, 115, 5093. (d) Tsukuhara, T.; Swenson, D, C.; Jordan, R. F. Organometallics 1997, 16, 3303.
32. Examples of groups 3-4 and lanthanide complexes bearing fluorinated alkoxide ligands: (a) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 12, 1907. (b) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 13, 7. Samuels, J. A.; Lobkovsky, E. B.; Streib, W. E.; Folting, K.; Huffman, J. C.; Zwanziger, J. W.; Caulton, K. G. J. Am. Chem. Soc. 1993, 115, 5093. (d) Tsukuhara, T.; Swenson, D, C.; Jordan, R. F. Organometallics 1997, 16, 3303.
33. Examples of groups 3-4 and lanthanide complexes bearing fluorinated alkoxide ligands: (a) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 12, 1907. (b) Bradley, D. C.; Chudszynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1994, 13, 7. Samuels, J. A.; Lobkovsky, E. B.; Streib, W. E.; Folting, K.; Huffman, J. C.; Zwanziger, J. W.; Caulton, K. G. J. Am. Chem. Soc. 1993, 115, 5093. (d) Tsukuhara, T.; Swenson, D, C.; Jordan, R. F. Organometallics 1997, 16, 3303.
34. Carpentier, J.-F.; Martin, A.; Swenson, D. C.; Jordan, R. F. Organometallics 2003, 22, 4999.
35. Hinshaw, C. J.; Peng, G.; Singh, R.; Spence, J. T.; Enemark, J. H.; Brück, M.; Kristofzski, J.; Merbs, S. L.; Ortega, R. B.; Wexler, P. A, Inorg. Chem. 1889, 28, 4483.
36. Chang, I.-S.; Willis, C. J. Can. J. Chem. 1977, 55, 2465.
37. 2 by alcohol nucleophiles see also: (c) Petrov, V A. Synthesis 2002, 2225.
38. 2 by alcohol nucleophiles see also: (c) Petrov, V A. Synthesis 2002, 2225.
39. 2 by alcohol nucleophiles see also: (c) Petrov, V A. Synthesis 2002, 2225.
40. 2 by alcohol nucleophiles see also: (c) Petrov, V A. Synthesis 2002, 2225.
41. Purcell, K. F.; Kotz, J. C. In Inorganic Chemistry; Saunders Co.: Philadelphia, 1977; pp 368-648.
42. (a) Gothelf, K. V.; Joergensen, K. Journal J. Org. Chem. 1994, 59, 9, 5687.
43. (b) Seebach, D.; Beck, A. K.; Imwinkelried, R.; Roggo, S.; Wonnacott, A. Helv. Chim. Acta 1987, 70, 954.
44. Seebach, D.; Lyapkalo, I. M.; Dahinden, R. Helv. Chim. Acta 1999, 82, 1829.
45. Benito, J. M.; Arevalo, S.; de Jesus, E.; de la Mata, F. J.; Flores, J. C.; Gomez, R. J. Organomet. Chem. 2000, 610, 42.
46. (a) Howard, W. A.; Trnka, T. M.; Parkin, G. Inorg. Chem. 1995, 34, 5900.
47. (b) Stephan, D. W. Organometallics 1990, 9, 2718.
48. 3+, 0.90 Å. Shannon, R. D. Acta Crystallogr., Sect. A 1978, A32, 751.
49. (a) Bickley, D. G.; Serpone, N. Inorg. Chem. 1979, 18, 2200.
50. (b) Harrod, J. F.; Taylor, K. J. Chem. Soc., Chem. Commun. 1971, 696.
51. (c) Denekamp, C. I. F.; Evans, D. F.; Slawin, A. M. Z.; Williams, D. J.; Wong, C. Y.; Woollins, J. D. J. Chem. Soc., Dalton. Trans. 1992, 2375.
52. (d) Gau, H.; Fay, R. C. Inorg. Chem. 1990, 29, 4974.
53. (e) Nieto, J. L.; Galindo, F.; Gutiérrez, A. M. Polyhedron 1985, 4, 1611.
54. (f) Willem, R.; Gielen, M.; Pepermans, H.; Brocas, J.; Fastenakel, D.; Finocchiaro, F. J. Am. Chem. Soc. 1985, 107, 1146.
55. (g) Willem, R.; Gielen, M.; Pepermans, H.; Hallenga, K.; Recca, A.; Finocchiaro, P. J. Am. Chem. Soc. 1985, 107, 1153.
56. (h) Bei, X.; Swenson, D. C.; Jordan, R. F. Organometallics 1997, 16, 3282.
57. (i) Holm, R. H. In Dynamic Nuclear Magnetic Resonance Spectroscopy; Jackman, L. M., Cotton, F. A., Eds.; Academic Press: New York, 1975; Chapter 9.
58. 4h
59. c = 350 K. See: (b) Alexander, S. J. Chem. Phys. 1962, 37, 971. (c) Kurland, R. J.; Rubin, M. B.; Wise, W. B. J. Chem. Phys. 1964, 40, 2426. (d) Kost, D.; Zeichner, A. Tetrahedron Lett. 1974, 4533.
60. c = 350 K. See: (b) Alexander, S. J. Chem. Phys. 1962, 37, 971. (c) Kurland, R. J.; Rubin, M. B.; Wise, W. B. J. Chem. Phys. 1964, 40, 2426. (d) Kost, D.; Zeichner, A. Tetrahedron Lett. 1974, 4533.
61. c = 350 K. See: (b) Alexander, S. J. Chem. Phys. 1962, 37, 971. (c) Kurland, R. J.; Rubin, M. B.; Wise, W. B. J. Chem. Phys. 1964, 40, 2426. (d) Kost, D.; Zeichner, A. Tetrahedron Lett. 1974, 4533.
62. c = 350 K. See: (b) Alexander, S. J. Chem. Phys. 1962, 37, 971. (c) Kurland, R. J.; Rubin, M. B.; Wise, W. B. J. Chem. Phys. 1964, 40, 2426. (d) Kost, D.; Zeichner, A. Tetrahedron Lett. 1974, 4533.
63. Lara-Sanchez, A.; Rodriguez, A.; Hughes, D. L.; Schormann, M.; Bochmann, M. J. Organomet. Chem. 2002, 663, 63.
64. Hayes, P. G.; Welch, G. C.; Emslie, D. J.; Noack, C. N.; Piers, W. E.; Parvez, M. Organometallics 2003, 22, 1577.
65. Memmler, H.; Walsh, K.; Gade, L. H.; Lauher, J. W. Inorg. Chem. 1995, 34, 4062.
66. Song, X.; Thornton-Pett, M.; Bochmann, M. Organometallics 1998, 17, 1004.
67. Bradley, D. C.; Chudzynska, H.; Hursthouse, M. B.; Motevalli, M. Polyhedron 1993, 12, 1907.
68. Zucchini, U.; Albizzati, E.; Giannini, U. J. Organomet. Chem. 1971, 26, 357.
69. (a) Lappert, M. F.; Pearce, R. J. Chem. Soc., Chem. Commun. 1973, 126.
70. (b) Hultzsch, K. C.; Voth, P.; Beckerle, K.; Spaniol, T. P.; Okuda, J. Organometallics 2000, 19, 228.
71. Anwander, R.; Runte, O.; Eppinger, J.; Gerstberger, G.; Herdtweek, E.; Spiegier, M. J. Chem. Soc., Dalton Trans. 1998, 847.
72. (a) Sheldrick, G. M. SHELXS-97, Program for the Determination of Crystal Structures; University of Goettingen: Germany, 1997,
73. (b) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures; University of Goettingen: Germany, 1997.