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Volumn 25, Issue 26, 2006, Pages 6108-6114

Adduct studies and reactivity of trans-[(C2F5) 2MeP]2Pt(Me)X (X = O2CCF3, OTF, OSO2F)

Author keywords

[No Author keywords available]

Indexed keywords

ACID SOLVENTS; APROTIC CONDITIONS; TRIFLUOROACETIC ACIDS;

EID: 33846379138     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060847p     Document Type: Article
Times cited : (12)

References (60)
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    • 3Pt is the dominant product. Butikofer, J. L.; Roddick, D. M. Unpublished results.
    • 3Pt is the dominant product. Butikofer, J. L.; Roddick, D. M. Unpublished results.
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    • The yield of anhydrides based on integration with respect to the product dfmp methyl resonance varies from 70 to 90, A spectroscopic reference sample of CH3C(O)OTf was prepared by the addition of acetic anhydride to triflic acid, a) Germain, A, Commeyras, A, Casadevall, A. Bull. Soc. Chim. Fr. 1973, 2527
    • 3C(O)OTf was prepared by the addition of acetic anhydride to triflic acid, (a) Germain, A.; Commeyras, A.; Casadevall, A. Bull. Soc. Chim. Fr. 1973, 2527.
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    • + is also a viable intermediate.
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    • Free dfmp in FSO3H is stable for several hours at ambient temperatures, but when heated to 80°C converts to a new species, 31P NMR: δ 52.2 (p, 2JPF, 88 Hz, 1H NMR: δ 1.65 (d, 2JPH, 16 Hz, which we tentatively assign as the phosphine oxide (C2F5) 2P(Me)O
    • 2P(Me)(O).
  • 54
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    • A reviewer has suggested that dimerization of intermediate Pt(0) species with Pt(II) centers could facilitate cis/trans isomerization via an associative process and also might account for the non-first-order kinetic behavior observed.
    • A reviewer has suggested that dimerization of intermediate Pt(0) species with Pt(II) centers could facilitate cis/trans isomerization via an associative process and also might account for the non-first-order kinetic behavior observed.
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    • 2O in this redox process is very difficult to discern in neat acid media.
    • 2O in this redox process is very difficult to discern in neat acid media.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.