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The yield of anhydrides based on integration with respect to the product dfmp methyl resonance varies from 70 to 90, A spectroscopic reference sample of CH3C(O)OTf was prepared by the addition of acetic anhydride to triflic acid, a) Germain, A, Commeyras, A, Casadevall, A. Bull. Soc. Chim. Fr. 1973, 2527
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33846391795
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+ is also a viable intermediate.
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+ is also a viable intermediate.
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CH = 155 Hz): McGarrity, J. F.; Cox, D. P. J. Am. Chem. Soc. 1983, 105, 3961.
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33846390211
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Free dfmp in FSO3H is stable for several hours at ambient temperatures, but when heated to 80°C converts to a new species, 31P NMR: δ 52.2 (p, 2JPF, 88 Hz, 1H NMR: δ 1.65 (d, 2JPH, 16 Hz, which we tentatively assign as the phosphine oxide (C2F5) 2P(Me)O
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2P(Me)(O).
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54
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33846385526
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A reviewer has suggested that dimerization of intermediate Pt(0) species with Pt(II) centers could facilitate cis/trans isomerization via an associative process and also might account for the non-first-order kinetic behavior observed.
-
A reviewer has suggested that dimerization of intermediate Pt(0) species with Pt(II) centers could facilitate cis/trans isomerization via an associative process and also might account for the non-first-order kinetic behavior observed.
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55
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33846340973
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2O in this redox process is very difficult to discern in neat acid media.
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2O in this redox process is very difficult to discern in neat acid media.
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