Origin of the π-facial stereoselectivity in the addition of nucleophilic reagents to chiral aliphatic ketones as evidenced by high-level ab initio molecular-orbital calculations

Chemistry - An Asian Journal

Volumn 1, Issue 6, 2006, Pages 852-859

  Takahashi, Osamu ^a   Yamasaki, Katsuyoshi ^a   Kohno, Yuji ^b   Ueda, Kazuyoshi ^b   Suezawa, Hiroko ^c   Nishio, Motohiro ^d  

^a HIROSHIMA UNIVERSITY   (Japan)

^b YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^c Japan Ministry of Education Culture Sports Science and Technology   (Japan)

^d CHPI Institute   (Japan)

Author keywords

Conformation analysis; Hydrogen bonds; Nucleophilic addition; Pi facia stereoselectivity; Transition states

Indexed keywords

EID: 33845920935     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600204     Document Type: Article

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