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2-C and -N atoms were not discriminated in the present survey. The C-H bond length and angle were normalized to standard values in the QUEST3D program, unless only coordinates from neutron studies are analyzed.
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72
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85153245345
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note
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6 aromatic ring.
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73
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85153284425
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note
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+ as the counter ion.
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74
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85153274556
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note
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max 2.90 Å: Hydrogen atoms are limited to aromatic CH groups to minimize the chemical inhomogeneity.
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75
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85153250928
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note
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It is difficult in the present search to distinguish the intraligand and interligand CH/π interaction. Occurrence of intraligand interaction is not frequent, but we often note interactions within a ligand in certain ligands such as triphenylphosphane.
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This type of interaction has been known and is often referred to as the edge-to-face (or point-to-face, T-shape) π/π (or arene/ arene, aromatic/aromatic) interaction.
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