A modular approach toward regulating the secondary coordination sphere of metal ions: Differential dioxygen activation assisted by intramolecular hydrogen bonds

Journal of the American Chemical Society

Volumn 128, Issue 48, 2006, Pages 15476-15489

  Lucas, Robie L ^a   Zart, Matthew K ^a   Murkerjee, Jhumpa ^a,c   Sorrell, Thomas N ^b   Powell, Douglas R ^a   Borovik, A S ^a,c  

^a UNIVERSITY OF KANSAS   (United States)

^b University of North Carolina at Chapel Hill   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; COORDINATION REACTIONS; HYDROGEN BONDS; METAL ANALYSIS; MOLECULAR STRUCTURE; UREA;

DIOXYGEN ACTIVATION; INTRAMOLECULAR HYDROGEN BONDS; LIGANDS; METAL IONS; NUCLEOPHILICITY;

IONS;

[(N' TERT BUTYLUREAYL) N ETHYL] BIS(N'' CYCLOPENTYLCARBAMOYLMETHYL)AMINE; [(N' TERT BUTYLUREAYL) N ETHYL] BIS(N'' ISOPROPYLCARBAMOYLMETHYL)AMINE; AMIDE; BIS(N ISOPROPYLCARBAMOYLMETHYL)AMINE; BIS[(N TERT BUTYLUREAYL) N ETHYL] (N'' CYCLOPENTYLCARBAMOYLMETHYL)AMINE; BIS[(N' TERT BUTYLUREAYL) N ETHYL] (N'' ISOPROPYLCARBAMOYLMETHYL)AMINE; COBALT COMPLEX; ETHYLAMINE; HYDROGEN; LIGAND; METAL ION; OXYGEN; TRIS[(N' TERT BUTYLUREAYL) N ETHYL]AMINE; TRIS[(N' TERT BUTYLUREAYLATO) N ETHYL]AMINATOCOBALT; UREA; UREA DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; ELECTRON SPIN RESONANCE; HYDROGEN BOND; ISOTOPE LABELING; REACTION ANALYSIS; SIGNAL DETECTION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

AMIDES; CATIONS; COBALT; HYDROGEN BONDING; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXYGEN; UREA;

EID: 33845343296     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja063935+     Document Type: Article

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97. - (0.29 mmol) in 3 mL of DMA was treated with excess dioxygen for 15 min, after which the reaction mixture was placed under reduced pressure for 5 min. The resulting heterogeneous mixture was filtered under argon, and the isolated solid was washed with diethyl ether and dried in vacuo to afford a tan powder.
98. 2) = 1.075. See Supporting Information for details.
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