C3-Symmetric Chiral Amidate Complexes: Effects of Ligand Binding on Cavity Structure

Inorganic Chemistry

Volumn 36, Issue 15, 1997, Pages 3210-3211

  Hammes, Brian S ^a   Ramos Maldonado, Dorisa ^a   Yap, Glenn P A ^b   Liable Sands, Louise ^b   Rheingold, Arnold L ^b   Young Jr , Victor G ^c   Borovik, A S ^a,d  

^a KANSAS STATE UNIVERSITY   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

^c University of Minnesota ^*  (United States)

^d UNIVERSITY OF KANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001039453     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970124l     Document Type: Article

References (29)

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16. Synthesis details and characterization data for all new compounds are given in Supporting Information.
17. 2) = 1.0047.
18. 2⋯ Ph interactions per molecule in the crystal lattice.
19. - with additional ligands yields a mixture of products that could not be readily separated.
20. Magnetic moment and EPR data are consistent with the complex having a S = 3/2 ground state.
21. (a) Enemark, J. H.; Feltham, R. D. Coord. Chem. Rev. 1974, 13, 339.
22. (b) Feltham, R. D.; Enemark, J. H. Top. Stereochem. 1981, 12, 155.
23. (c) Chiou, Y.-M.; Que, L., Jr. Inorg. Chem. 1995, 34, 3270.
24. 3-.
25. 2) =1.109.
26. -.
27. -, 2.048(3), 115.6(1), 77.8(1). Not significant at P < 0.05 using an analysis of variance test.
28. s-mbz(NO)r are 3.938 and 4.348 Å.
29. s-mbz(NO)].