Synthesis and structure of a trigonal monopyramidal Fe(II) complex and its paramagnetic carbon monoxide derivative

Journal of the American Chemical Society

Volumn 118, Issue 25, 1996, Pages 6084-6085

  Ray, Manabendra ^a   Golombek, Adina P ^b   Hendrich, Michael P ^b   Young Jr , Victor G ^c   Borovik, A S ^a  

^a KANSAS STATE UNIVERSITY   (United States)

^b CARNEGIE MELLON UNIVERSITY   (United States)

^c University of Minnesota ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; IRON COMPLEX;

ARTICLE; COMPLEX FORMATION; CRYSTALLOGRAPHY; DRUG STRUCTURE;

EID: 0030018857     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960036k     Document Type: Article

References (42)

1. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
2. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
3. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
4. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
5. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
6. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
7. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
8. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
9. Structurally characterized trigonal monopyramidal metal complexes with tripodal ligands: (a) Ni(0), Mealli, C.; Sacconi, L. J. Chem. Soc., Chem. Commun. 1973, 886. (b) Co(I), Sacconi, L.; Orlandini, A.; Midollini, S. Inorg. Chem. 1974, 13, 2850. (c) Cu(I), Karlin, K. D.; Dahlstrom, P. L.; Stanford, M. L.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1979, 465. Karlin, K. D.; Dahlstrom, P. L.; Hyde, J. R.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1980, 906. Chuang, C.; Lim, K.; Chen, K.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2563. (d) Ag(I), de Mendoza, J.; Mesa, E.; Robdrigues-Ubis, J.-C; Vázques, P.; Vögtle, F.; Windscheif, P,- M.; Rissanen, K.; Lehn, J.-M.; Lilienbaum, D.; Ziessel, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 1331. (e) V(III),Cummins, C.C; Lee, J.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1501. (f) Al(III), Pinkas, J.; Wang, T.; Jacobson, R. A.; Verkade, J. G. Inorg. Chem. 1994, 33, 4202. (g) Ni(II), Ray M.; Yap, G. P. A.; Rheingold, A. L.; Borovik, A. S. J. Chem. Soc., Chem. Commun. 1995, 1777.
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13. 1a,b,c-g (a) Plass, W.; Verkade, J. G. J. Am. Chem. Soc. 1992, 114, 2275. (b) Cummins, C. C.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1993, 32, 757. (c) Shih, K.-Y.; Schrock, R. R.; Kempe, R. J. Am. Chem. Soc. 1994, 116, 8804. (d) Cummins, C. C.; Schrock, R. R.; Davis, W. D. Inorg. Chem. 1994, 33, 1448. (e) Trofimenko, S. Chem. Rev. 1993, 93, 943 and references therein. (f) Memmler, H.; Walsh, K.; Gade, L.; Lauher, J. W. Inorg. Chem. 1995, 34, 4062 and references therein, (g) Kitajima, N.; Tolman, W. B. In Progress in Inorganic Chemistry; Karlin, K. D., Ed.; Wiley: New York, 1995; p 419.
14. 1a,b,c-g (a) Plass, W.; Verkade, J. G. J. Am. Chem. Soc. 1992, 114, 2275. (b) Cummins, C. C.; Schrock, R. R.; Davis, W. D. Angew. Chem., Int. Ed. Engl. 1993, 32, 757. (c) Shih, K.-Y.; Schrock, R. R.; Kempe, R. J. Am. Chem. Soc. 1994, 116, 8804. (d) Cummins, C. C.; Schrock, R. R.; Davis, W. D. Inorg. Chem. 1994, 33, 1448. (e) Trofimenko, S. Chem. Rev. 1993, 93, 943 and references therein. (f) Memmler, H.; Walsh, K.; Gade, L.; Lauher, J. W. Inorg. Chem. 1995, 34, 4062 and references therein, (g) Kitajima, N.; Tolman, W. B. In Progress in Inorganic Chemistry; Karlin, K. D., Ed.; Wiley: New York, 1995; p 419.
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25. -, unpublished results.
26. -.
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39. - in DMF at various partial pressures of CO.
40. Y2 orbitals.
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42. Note Added in Proof: Another 5 = 1 Fe-CO complex has been isolated recently by S. A. Koch (submitted for publication).