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Volumn 691, Issue 26, 2006, Pages 5567-5575

Ligand substitution in the tetrahedrane clusters RCCo2Mo(η5-indenyl)(CO)8 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Influence of the carbyne and indenyl ligands on the stability of the substitution products and X-ray diffraction structures of HCCo2Mo(η5-indenyl)(CO)6(μ-bpcd) and

Author keywords

Chlorine atom abstraction; Ligand substitution; Mixed metal clusters; Tetrahedrane clusters

Indexed keywords

CHLORINATION; DECOMPOSITION; MOLECULAR STRUCTURE; SUBSTITUTION REACTIONS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 33751415021     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.08.095     Document Type: Article
Times cited : (4)

References (54)
  • 8
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    • W.H. Watson, K. Ejsmont, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 36 (in press).
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    • 33751417421 scopus 로고    scopus 로고
    • saint Version 6.02, Bruker Analytical X-ray Systems, Inc. Copyright 1997-1999.
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    • shelxtl Version 5.1, Bruker Analytical X-ray Systems, Inc. Copyright 1998.
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    • A.L. Spek, platon - A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 2001.
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    • 0001157784 scopus 로고
    • For structural data on related tetrahedrane clusters, see:
    • For structural data on related tetrahedrane clusters, see:. Beurich H., Blumhofer R., and Vahrenkamp H. Chem. Ber. 115 (1982) 2409
    • (1982) Chem. Ber. , vol.115 , pp. 2409
    • Beurich, H.1    Blumhofer, R.2    Vahrenkamp, H.3
  • 43
    • 33751402173 scopus 로고    scopus 로고
    • note
    • Our crude X-ray structure for cluster 4 was of poor quality due to numerous attached crystallites, whose scattering coincided with that of the main crystal. This complication was further exacerbated by the presence of a disorder solvent molecule (hexane) between the two independent molecules of 4 in the unit cell. Since the preliminary R value of 0.09 was not likely to change for the better, we terminated the refinement for 4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.