Recent developments in superhydrophobic surfaces and their relevance to marine fouling: A review

Biofouling

Volumn 22, Issue 5, 2006, Pages 339-360

  Genzer, Jan ^a   Efimenko, Kirill ^a  

^a North Carolina State University   (United States)

Author keywords

Amphiphilic surfaces; Marine fouling; Responsive "smart" surfaces; Superhydrophobic surfaces; Wettability

Indexed keywords

FOULING; HYDROPHOBICITY; MARINE ENGINEERING; SOLVENTS; SURFACE STRUCTURE;

BIOFOULING; CHEMICAL COMPOSITION; ELECTRIC FIELD; HYDROPHOBICITY; LIGHT EFFECT; MARINE POLLUTION; SOLVENT; SUBSTRATE; SURFACE; TEMPERATURE EFFECT; TEXTURE; WETTABILITY;

ANIMAL; BIOFILM; BIOLOGY; GROWTH, DEVELOPMENT AND AGING; HYDROPHOBICITY; REVIEW; SURFACE PROPERTY; WETTABILITY;

ANIMALS; BIOFILMS; HYDROPHOBICITY; MARINE BIOLOGY; SURFACE PROPERTIES; WETTABILITY;

EID: 33751264386     PISSN: 08927014     EISSN: 10292454     Source Type: Journal    
DOI: 10.1080/08927010600980223     Document Type: Review

References (133)

1. Absolom DR, Lamberti FV, Policova Z, Zingg W, van Oss CJ, Neumann W. 1983. Surface thermodynamics of bacterial adhesion. Appl Environm Microbiol 46:90-97.
2. Anderson C, Altar M, Callow M, Candries M, Milne A, Townson RL. 2003. The development of foul-release coatings for seagoing vessels. J Mar Design Operations 84:11-23.
3. Autumn K. 2006. Properties, principles and parameters of the gecko adhesive system. In: Smith AM, Callow JA, editors. Biological Adhesives. Berlin, Heidelberg: Springer-Verlag. pp 225-256.
4. Baier RE. 1970. Surface properties influencing biological adhesion. In: Manly RS, editor. Adhesion in biological systems. New York: Academic Press Inc. pp 15-48.
5. Baier RE. 1972. Influence of the initial surface condition of materials on bioadhesion. In: Acker RF, Brown BF, DePalma JR, Iverson WP, editors. Proc 3rd Int Congr Marine Corrosion and Fouling. Evanston, IL: Northwestern University Press. pp 633-639.
6. Bers AV, Wahl M. 2004. The influence of natural surface microtopographies on fouling. Biofouling 20:43-51.
7. Bhat RR, Fischer DA, Genzer J. 2002. Fabricating planar nanoparticle assemblies with number density gradients. Langmuir 18:5640-5643.
8. Bhat RR, Tomlinson MR, Genzer J. 2006a. Orthogonal surface-grafted polymer gradients: a versatile combinatorial platform. J Polymer Sci Polymer Phys Edn 43:3384-3394.
9. Bhat RR, Tomlinson MR, Wu T, Genzer J. 2006b. Surface-grafted polymer gradients: formation, characterization and applications. Adv Polymer Sci 198:51-124.
10. Bico J, Marzolin C, Quéré D. 1999. Pearl drops. Europhys Lett 47:220-226.
11. Bico J, Tordeux C, Quéré D. 2001. Rough wetting. Europhys Lett 55:214-220.
12. Blossey R. 2003. Self-cleaning surface-virtual realities. Nature Mater 2:301-306.
13. Brady RF. 2001. A fracture mechanical analysis of fouling release from nontoxic antifouling coatings. Prog Organic Coat 43: 188-192.
14. Brady RF, Singer IL. 2000. Mechanical factors favoring release from fouling release coatings. Biofouling 15:73-81.
15. Buehrle J, Herminghaus S, Mugele F. 2002. Impact of line tension on the equilibrium shape of liquid droplets on patterned substrates. Langmuir 18:9771-9777.
16. Callies M, Quéré D. 2005. On water repellency. Soft Mater 1:55-61.
17. Callow JA, Callow ME. 2006. The Ulva spore adhesive system. In: Smith AM, Callow JA, editors. Biological adhesives. Berlin Heidelberg: Springer-Verlag. pp 63-78.
18. Callow ME, Callow JA, Ista LK, Coleman SE, Nolasco AC, López GP. 2000. Use of self-assembled monolayers of different wettabilities to study surface selection and primary adhesion processes of green algal (Enteromorpha) zoospores. Appl Environ Microbiol 66:3249-3254.
19. Callow ME, Jennings AR, Brennan AB, Seegert CE, Gibson A, Wilson L, Feinberg A, Baney R, Callow JA. 2002. Microtopographic cue for settlement of zoospores of the green fouling alga Enteromorpha. Biofouling 18: 237-245.
20. Carey DH, Ferguson GS. 1996. A smart surface: entropic control of composition at a polymer/water interface. J Am Chem Soc 118:9780-9781.
21. Carman ML, Estes TG, Feinberg AW, Schumacher JF, Wilkerson W, Wilson LH, Callow ME, Callow JA, Brennan AB. 2006. Engineered antifouling microtopographies - correlating wettability with cell attachment. Biofouling 22:11-21.
22. Cassie ABD, Baxter S. 1944. Wettability of porous surfaces. Trans Faraday Soc 40:546-551.
23. Chaudhury MK, Whitesides GM. 1992. How to make water run uphill. Science 256:1539-1541.
24. Chaudhury MK, Finlay JA, Chung JY, Callow ME, Callow JA. 2005. The influence of elastic modulus and thickness on the soft fouling alga Ulva linza (Enteromorpha linza) from polydimethyl siloxane (PDMS) ideal networks. Biofouling 21: 41-48.
25. Chen W, Fadeev AY, Hsieh MC, Öner D, Youngblood J, McCarthy TJ. 1999. Ultrahydrophobic and ultralyophobic surfaces: some comments and examples. Langmuir 15:3395-3399.
26. Cheng YT, Rodak DE, Wong CA, Hayden CA. 2006. Effects of micro- and nano-structures on the self-cleaning behavior of lotus leaves. Nanotechnology 17:1359-1362.
27. Chiovetti A, Dugdale TM, Wetherbee R. 2006. Diatom adhesives: molecular and mechanical properties. In: Smith AM, Callow JA, editors. Biological adhesives. Berlin Heidelberg: Springer-Verlag. pp 79-103.
28. Crowe JA, Genzer J. 2005. Creating responsive surfaces with tailored wettability switching kinetics and reconstruction reversibility. J Am Chem Soc 127:17610-17611.
29. De Gennes PG, Brochard F, Quéré D. 2003. Capillarity and wetting phenomena: drops, bubbles, pearls, waves. Berlin Heidelberg: Springer-Verlag.
30. Dexter SC. 1979. Influence of substratum critical surface tension on bacterial adhesion - in situ studies. J Colloid Interface Sci 70:346-354.
31. Dexter SC, Sullivan JD Jr, Williams J III, Watson SW. 1975. Influence of substrate wettability on the attachment of marine bacteria to various surfaces. Appl Microbiol 30: 298-308.
32. Discher DE, Janmey P, Wang Y. 2005. Tissue cells feel and respond to the stiffness of their substrate. Science 310: 1139-1143.
33. Efimenko K, Rackaitis M, Manias E, Vaziri A, Mahadevan L, Genzer J. 2005. Nested self-similar wrinkling patterns in skins. Nature Mater 4:293-297.
34. Erbil HY, Demirel AL, Avci Y, Mert O. 2003. Transformation of a simple plastic into a superhydrophobic surface. Science 299:1377-1380.
35. Feng L, Song Y, Zhai J, Liu B, Zu J, Jiang L, Zhu D. 2003. Creation of a superhydrophobic surface from an amphiphilic polymer. Angew Chem Int Ed 42:800-802.
36. Feng L, Zhang Z, Mai Z, Ma Y, Liu B, Jiang L, Zhu D. 2004. A super-hydrophobic and super-oleophobic coating mesh film for the separation of oil and water. Angew Chem Int Ed 43:2012-2014.
37. Feng L, Li S, Li Y, Li H, Zhang L, Zhai J, Song Y, Liu B, Jiang L, Zhu D. 2002. Super-hydrophobic surfaces: from natural to artificial. Adv Mater 14:1857-1860.
38. Fletcher M, Pringle JH. 1985. The effect of surface free energy and medium surface tension on bacterial attachment to solid surfaces. J Colloid Interface Sci 104:5-14.
39. Fu Q, Rama Rao GV, Basame SB, Keller DJ, Artyushkova K, Fulghum JE, López GP. 2004. Reversible control of free energy and topography of nanostructured surfaces. J Am Chem Soc 126:8904-8905.
40. Fürstner R, Barthlott W, Neinhuis C, Walzel P. 2005. Wetting and self-cleaning properties of artificial superhydrophobic surfaces. Langmuir 21:956-961.
41. Galaev IY, Mattiasson B. 1999. 'Smart' polymers and what they could do in biotechnology and medicine. Trends Biotechnol 17:335-340.
42. Gan D, Mueller A, Wooley KL. 2003. Amphiphilic and hydrophobic surface patterns generated from hyperbranched fluoropolymer/linear polymer networks: minimally adhesive coatings via the crosslinking of hyperbranched fluoropolymers. J Polymer Sci: A Polymer Chem 41:3531-3540.
43. Gao L, McCarthy TJ. 2006a. The "Lotus Effect" explained: two reasons why two length scales of topography are important. Langmuir 22:2966-2967.
44. Gao L, McCarthy TJ. 2006b. Two-dimensional fluidics based on differential lyophobicity and gravity. Langmuir 22:4914-4916.
45. Gao L, McCarthy TJ. 2006c. Contact angle hysteresis explained. Langmuir 22:6234-6237.
46. Gao L, McCarthy TJ. 2006d. "Artificial Lotus leaf" prepared using a 1945 patent and a commercial textile. Langmuir 22:5998-6000.
47. R=180°/180°). J Am Chem Soc 128:9052-9053.
48. Gau H, Herminghaus S, Lenz P, Lipowsky R. 1999. Liquid morphologies on structured surfaces: from microchannels to microchips. Science 283:46-49.
49. Genzer J. 2002. Molecular gradients: formation and applications in soft condensed matter science. In: Buschow KHJ, Cahn RW, Flemings MC, Ilschner B, Kramer EJ, Mahajan S, editors. Encyclopedia of Materials: Science & Engineering. Amsterdam: Elsevier. pp 1-8.
50. Genzer J. 2005. Templating surfaces with gradient assemblies. J Adhesion 81:417-435.
51. Genzer J, Efimenko K. 2000. On designing and creating long-lived superhydrophobic surfaces through mechanically assembled monolayers (MAMs). Science 290:2130-2133.
52. Genzer J, Bhat RR, Wu T, Efimenko K. 2003. Molecular gradient nanoassemblies. In: Nalwa HS, editor. Encyclopedia of Nanoscience & Nanotechnology. Valencia, CA: American Scientific Publishers, Vol. 5. pp 663-674.
53. Gudipati CS, Greenlieaf CM, Johnson JA, Pornpimol P, Wooley KL. 2004. Hyperbranched fluoropolymer and linear poly(ethylene glycol) based amphiphilic crosslinked networks as efficient antifouling coatings: an insight into the surface compositions, topographies, and morphologies. J Polymer Sci: A Polymer Chem 42:6193-6208.
54. Gudipati CS, Finlay JA, Callow JA, Callow ME, Wooley KL. 2005. The antifouling and fouling-release performance of hyperbranched fluoropolymer (HBFP)-poly(ethylene glycol) (PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga Ulva. Langmuir 21:3044-3053.
55. Guo C, Feng L, Zhai J, Wang G, Song Y, Jiang L, Zhu D. 2004. Large-area fabrication of a nanostructure-induced hydrophilic surface from a hydrophilic polymer. Chem Phys Chem 5:750-753.
56. Hare EF, Shafrin EG, Zisman WA. 1954. Properties of films of adsorbed fluorinated acids. J Phys Chem 58:236-239.
57. He B, Patankar NA, Lee J. 2003. Multiple equilibrium droplet shapes and design criterion for rough hydrophobic surfaces. Langmuir 19:4999-5003.
58. Herminghaus S. 2000. Roughness-induced non-wetting. Europhys Lett 52:165-170.
59. Hoipkemeier-Wilson L, Schumacher J, Carman M, Gibson A, Feinberg A, Callow M, Finlay J, Callow J, Brennan A. 2004. Antifouling potential of lubricious, micro-engineered, PDMS elastomers against zoospores of the green fouling alga Ulva (Enteromorpha). Biofouling 20:53-63.
60. Holland R, Dugdale TM, Wetherbee R, Brennan AB, Finlay JA, Callow JA, Callow ME. 2004. Adhesion and motility of fouling diatoms on a silicone slastomer. Biofouling 20:323-329.
61. Ichimura K, Oh SK, Nakagawa M. 2000. Light-driven motion of liquids on a photoresponsive surface. Science 288:1624-1626.
62. Ista LK, López GP. 1998. Lower critical solubility temperature materials as biofouling release agents. J Ind Microbiol Biotechnol 20(121):125.
63. Ista LK, Pérez-Luna VH, López GP. 1999. Surface-grafted, environmentally sensitive polymers for biofilm release. Appl Environ Microbiol 65:1603-1609.
64. Ista LK, Fan H, Baca O, López GP. 1996. Attachment of bacteria to model solid surfaces: oligo (ethylene glycol) surfaces inhibit bacterial attachment. FEMS Microbiol Lett 142: 59-63.
65. Ista LK, Callow ME, Finlay JA, Coleman SE, Bolasco AC, Simons RH, Callow JA, López GP. 2004. Effects of substratum surface chemistry and surface energy on attachment of marine bacteria and algal spores. Appl Environ Microbiol 70: 4151-4157.
66. Jiang L, Zhao Y, Zhai J. 2004. A Lotus-leaf-like superhydrophobic surface: a porous microsphere/nanofiber composite films prepared by electrohydrodynamics. Angew Chem Int Ed 43: 4338-4341.
67. Jhon YK, Bhat RR, Jeong C, Rojas OJ, Szleifer I, Genzer J. 2006. Salt-induced depression of lower critical solution temperature in surface-grafted neutral thermoresponsive polymer. Macromol Rapid Commun 27:698-702.
68. Koberstein JT. 2004. Molecular design of functional polymer surfaces. J Polymer Sci Part B Polymer Phys 42:2942-2956.
69. Kong HJ, Liu J, Riddle K, Matsumoto T, Leach K, Mooney DJ. 2005. Non-viral gene delivery regulated by stiffness of cell adhesion substrate. Nature Mater 4:460-464.
70. Krasovitski B, Marmur A. 2005. Drops down the hill: theoretical study of limiting contact angles and the hysteresis range on a tilted plate. Langmuir 21:3881-3885.
71. Krishnan S, Ayothi R, Hezemer A, Finlay JA, Sohn KE, Perry R, Ober CK, Kramer EJ, Callow ME, Callow JA, Fischer DA. 2006. Anti-fouling properties of comblike block copolymers with amphiphilic side chains. Langmuir 22:5075-5086.
72. Krupenkin TN, Taylor JA, Schneider TM, Yang S. 2004. From rolling ball to complete wetting: the dynamic tuning of liquids on nanostructured surfaces. Langmuir 20:3823-3827.
73. Kwok DY, Neumann AW. 2000. Contact angle interpretation: re-evaluation of existing contact angle data. Colloids Surf A 161:49-62.
74. Lafuma A, Quéré D. 2003. Superhydrophobic states. Nature Mater 2:457-460.
75. Lahann J, Mitragorti S, Tran TN, Kaido H, Sundaram J, Choi IS, Hoffer S, Somorjai GA, Langer R. 2003. A reversibly switching surface. Science 299:371-374.
76. Latour RA. 2004. Biomaterials: protein-surface interactions. In: Bowlin GL, Wnek G, editors. Encyclopedia of biomaterials and biomedical engineering. New York: Marcel Dekker.
77. Li F, Li S, Li H, Zhai J, Song Y, Jiang L, Zhu D. 2002. Superhydrophobic surface of aligned polyacrylonitrile nanofibers. Angew Chem Int Ed 41:1221-1223.
78. Li H, Wang X, Song Y, Liu Y, Li Q, Jiang L, Zhu D. 2001. Super-"amphiphobic" aligned carbon nanotube films. Angew Chem Int Ed 40:1743-1746.
79. Lippmann MG. 1875. Relations entre les phénoménes e Électriques et capillaries. Ann Chim Phys 5:494-549.
80. Liu H, Feng L, Zhai J, Jiang L, Zhu D. 2004. Reversible wettability of a chemical vapor deposition prepared ZnO films between superhydrophobicity and superhydrophilicity. Langmuir 20:5659-5661.
81. Lord MS, Stenzel MH, Simmons A, Milthorpe BK. 2006a. The effect of charged groups on protein interaction with poly (HEMA) hydrogels. Biomaterials 27:567-575.
82. Lord SM, Stenzel MH, Simmons A, Milthorpe BK. 2006b. Lysozyme interaction with poly(HEMA)-based hydrogels. Biomaterials 27:1341-1345.
83. Luzinov I, Minko S, Tsukruk, VV. 2004. Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers. Prog Polymer Sci 29:635-698.
84. Makal U, Wynne KJ. 2005. Water induced hydrophobic surface. Langmuir 21:3742-3745.
85. Marmur A. 2003. Wetting on hydrophobic rough surfaces: to be heterogeneous on not to be? Langmuir 19:8343-8348.
86. Marmur A. 2004. The Lotus effect: superhydrophobicity and metastability. Langmuir 20:3517-3519.
87. Marmur A. 2006a. Underwater superhydrophobicity: theoretical feasibility. Langmuir 22:1400-1402.
88. Marmur A. 2006b. Soft contact: measurement and interpretation of contact angles. Soft Mater 2:12-17.
89. Marmur A. 2006c. Super-hydrophobicity fundamentals: implications to biofouling prevention. Biofouling 22:107-115.
90. Minko S. 2005. Responsive polymer materials. Oxford, UK: Blackwell Publishing.
91. Mrksich M, Whitesides GM. 1996. Using self-assembled monolayers to understand the interactions of man-made surfaces with proteins and cell. Annu Rev Biophys Biomolec Struct 25:55-78.
92. Nakajima A, Hashimoto K, Watanabe T. 2001. Recent studies on super-hydrophobic films. Monatsh Chem 132:31-41.
93. Neinhuis C, Barthlott W. 1997. Characterization and distribution of water-repellent, self-cleaning plant surfaces. Ann Bot 79: 667-677.
94. 3 alignment. Langmuir 15:4321-4323.
95. Norde W. 1996. Driving forces for protein adsorption at solid surfaces. Macromol Symp 103:5-18.
96. Onda T, Shibuichi S, Satoh N, Tsuji K. 1996. Super-water-repellent fractal surfaces. Langmuir 12:2125-2127.
97. Öner D, McCarthy TJ. 2000. Ultrahydrophobic surfaces: effects of topography length scales on wettability. Langmuir 16:7777-7782.
98. Otten A, Herminghaus S. 2004. How plants keep dry: a physicist's point of view. Langmuir 20:2405-2408.
99. Patankar NA. 2003. On the modeling of hydrophobic contact angles on rough surfaces. Langmuir 19:1249-1253.
100. Quéré D, Lafuma A, Bico J. 2003. Slippy and sticky microtextured solids. Nanotechology 14:1109-1112.
101. Robinson A. 2006. The last man who knew everything. New York: Pi Press.
102. Ruardy TG, Schakenraad JM, van der Mei HC, Busscher HJ. 1997. Preparation and characterization of chemical gradient surfaces and their application for the study of cellular interaction phenomena. Surf Sci Rep 29:1-30.
103. Russell TP. 2002. Surface-responsive materials. Science 297: 964-967.
104. Scardino AJ, deNys R. 2004. Fouling deterrence on the bivalve shell Mytilus galloprovincialis: a physical phenomenon? Biofouling 20:249-257.
105. Scardino AJ, Harvey E, de Nys R. 2006. Testing attachment point theory: diatom attachment on microtextured polyimide biomimics. Biofouling 22:55-60.
106. Schild HG. 1992. Poly(n-isopropylacrylamide) - experiment, theory and application. Prog Polymer Sci 17:163-249.
107. Schmidt DL, Brady RF, Lam K, Schmidt DC, Chaudhury MK. 2004. Contact angle hysteresis, adhesion, and marine biofouling. Langmuir 20:2830-2836.
108. Schrader ME. 1982. On Adhesion of biological substances to low energy solid surfaces. J Colloid Interface Sci 88:296-297.
109. Shibuichi S, Onda T, Satoh N, Tsuji K. 1996. Super water-repellent surfaces resulting from fractal structure. J Phys Chem 100:19512-19517.
110. Smith AM, Callow JA, editors. 2006. Biological adhesives. Berlin Heidelberg: Springer-Verlag. 284 pp.
111. Sorongon ML, Bloodgood RA, Burchard RP. 1991. Hydrophobicity, adhesion and surface-exposed proteins of gliding bacteria. Appl Environ Microbiol 57:3193-3199.
112. Sun M, Luo C, Xu L, Ji H, Ouyang Q, Yu D, Chen Y. 2005b. Artificial lotus leaf by nanocasting. Langmuir 21:8978-8981.
113. 2 thin films. J Phys Chem B 105:1984-1990.
114. Sun T, Geng L, Gao X, Kiang L. 2005a. Bioinspired surfaces with special wettability. Acc Chem Res 38:644-652.
115. Sun T, Wang G, Feng L, Liu B, Ma Y, Jiang L, Zhu D. 2004a. Reversible switching between superhydrophilicity and superhydrophobicity. Angew Chem Int Ed 43:357-360.
116. Sun Y, Guo, S, Walker GC, Kavanagh CJ, Swain GW. 2004b. Surface elastic modulus of barnacle adhesive and release characteristics from silicone surfaces. Biofouling 20:279-289.
117. Teshima K, Sugimura H, Inoue Y, Takai O, Takano A. 2003. Ultra-water-repellent poly(ethyleneterephthalate) substrates. Langmuir 19:10624-10627.
118. Vallet M, Vallade M, Berge B. 1999. Limiting phenomena for the spreading of water on polymer films by electrowetting. Eur Phy J B11:583-591.
119. Wahl M. 1989. Marine epibiosis: I. Fouling and antifouling: some basic aspects. Mar Ecol Prog Ser 58:175-189.
120. Wang R, Hashimoto K, Fujishima A, Chikuni M, Kojima E, Kitamura A, Shimohigoshi M, Watanabe T. 1997. Light-induced amphiphilic surfaces. Nature (Lond) 388:431-432.
121. Wendt DE, Kowalke GL, Kim J, Singer IL. 2006. Factors that influence coatings performance: the effect of coating thickness on basal plate morphology, growth and critical removal stress of the barnacle Balanus amphitrite. Biofouling 22:1-9.
122. Wenzel RN. 1936. Resistance of solid surfaces to wetting by water. Ind Eng Chem Res 28:988-994.
123. Whitesides GM, Love JC. 2001. The art of building small. Sci Am 285:39-47.
124. Wiencek KM, Fletcher M. 1995. Bacterial adhesion to hydroxyand methyl-terminated alkanethiol self-assembled monolayers. J Bacteriol 177:1959-1966.
125. Wu T, Efimenko, K, Genzer J. 2002. Multivariant investigation of the mushroom-to-brush transition in surface-anchored poly(acrylamide). J Am Chem Soc 124:9394-9395.
126. Wu X, Zheng L, Wu D. 2005. Fabrication of superhydrophobic surfaces from microstructured ZnO-based surfaces via a wet-chemical route. Langmuir 21:2665-2667.
127. Xia Y, Whitesides GM. 1998a. Soft lithography. Annu Rev Mater Sci 28:153-184.
128. Xia Y, Whitesides GM. 1998b. Soft lithography. Angew Chem Int Ed 37:551-575.
129. Xia Y, Rogers JA, Paul KE, Whitesides GM. 1999. Unconventional methods for fabricating and patterning nanostructures. Chem Rev 99:1823-1848.
130. Xie Q, Xu J, Feng L, Jiang L, Tang W, Luo X, Han CC. 2004. Facile creation of a super-hydrophobic coating surface with bionic microsctructure. Adv Mater 16:302-305.
131. Yoshimitsu Z, Nakajima A, Watanabe T, Hashimoto K. 2002. Effects of surface structure on the hydrophobicity and sliding behavior of water droplets. Langmuir 18:5818-5822.
132. Zhai L, Berg MC, Cebeci FÇ, Kim Y, Milwid JM, Rubner MF, Cohen RE. 2006. Patterned superhydrophobci surfaces: toward mimic of the Namib Desert Beetle. Nano Lett 6: 1213-1217.
133. Zhang X, Shi F, Tu X, Liu H, Fu Y, Wang Z, Jiang L, Li X. 2004. Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: towards super-hydrophobic surface. J Am Chem Soc 126:3064-3065.