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84906372716
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note
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U, lifetime) as well as a nonadjacent uncoordinated zinc porphyrin to which it can transfer energy via a superexchange mechanism with a rate ∼10-fold less than transfer to an adjacent chromophore.
-
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-
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61
-
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84906401525
-
-
note
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2 = 0.25 has been used. This value is appropriate for energy transfer from a bookend porphyrin to the guest porphyrin assuming (1) free rotation of the guest relative to the host during the lifetime of the donor excited state (dynamically averaged limit) and (2) the transition-dipole direction in the guest porphyrin lies along the N-N axis.
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62
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