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84944648082
-
-
For covalent radii
-
For ionic radii, see: (a) Shannon, R. D. Acta Crystallogr. 1976, A32, 751-767. For covalent radii, see:
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(1976)
Acta Crystallogr.
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, pp. 751-767
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-
Shannon, R.D.1
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75
-
-
0003944545
-
-
HarperCollins: New York
-
(b) Huheey, J. E.; Keiter, E. A.; Keiter, R. L. In Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed.; HarperCollins: New York, 1993.
-
Inorganic Chemistry: Principles of Structure and Reactivity, 4th Ed.
, pp. 1993
-
-
Huheey, J.E.1
Keiter, E.A.2
Keiter, R.L.3
-
76
-
-
33745749873
-
-
note
-
1c,9a, 24
-
-
-
-
77
-
-
0032963263
-
-
- anion: (a) Watanabe, M.; Sato, M.; Nagasawa, A.; Kai, M.; Motoyama, I.; Takayama, T. Bull. Chem. Soc. Jpn. 1999, 72, 715.
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(1999)
Bull. Chem. Soc. Jpn.
, vol.72
, pp. 715
-
-
Watanabe, M.1
Sato, M.2
Nagasawa, A.3
Kai, M.4
Motoyama, I.5
Takayama, T.6
-
78
-
-
0033579109
-
-
(b) Akiba, K.; Yamashita, M.; Yamamoto, Y.; Nagase, S. J. Am. Chem. Soc. 1999, 121, 10644.
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(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 10644
-
-
Akiba, K.1
Yamashita, M.2
Yamamoto, Y.3
Nagase, S.4
-
79
-
-
0001036201
-
-
(c) Braunstein, P.; Douce, L.; Fischer, J.; Craig, N. C.; Goetz-Grandmont, G.; Matt, D. Inorg. Chim. Acta 1992, 194, 151.
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(1992)
Inorg. Chim. Acta
, vol.194
, pp. 151
-
-
Braunstein, P.1
Douce, L.2
Fischer, J.3
Craig, N.C.4
Goetz-Grandmont, G.5
Matt, D.6
-
80
-
-
0042480517
-
-
A neutral, structurally asymmetric (fluoro)borabicyclononane dimer with one tetrahedral B and one planar B atom has also been reported: Koster, R.; Schussler, W.; Boese, R. Chem. Ber. 1990, 123, 1945.
-
(1990)
Chem. Ber.
, vol.123
, pp. 1945
-
-
Koster, R.1
Schussler, W.2
Boese, R.3
-
81
-
-
33947477928
-
-
-, with F-Al = 1.80(6) Å, see: Natta, G.; Allegra, G.; Perego, G.; Zambelli, A. J. Am. Chem. Soc. 1961, 83, 5033.
-
(1961)
J. Am. Chem. Soc.
, vol.83
, pp. 5033
-
-
Natta, G.1
Allegra, G.2
Perego, G.3
Zambelli, A.4
-
82
-
-
33748500592
-
-
A similar M-F-M-F-M arrangement has been observed in a Bi system. For a recent review of such metal fluorides, see: Roesky, H. W.; Haiduc, I. J. Chem. Soc., Dalton Trans. 1999, 14, 2249-2264.
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(1999)
J. Chem. Soc., Dalton Trans.
, vol.14
, pp. 2249-2264
-
-
Roesky, H.W.1
Haiduc, I.2
-
83
-
-
33745758202
-
-
note
-
8 at 23°C are as follows: δ -120.72 (s, 3 F, F-3), -139.52 (s, 3 F, F-6), -141.48 (s, 6 F, F-2′VF-6′), -156.55 (t, 3 F, F-4), -157.22 (s, 3 F, F-4′), -158.46 (t, 3 F, F-5), -165.20 (s, 6 F, F-37F-5′), -175.02 (s, br, 1 F, Al-F).
-
-
-
-
84
-
-
0000225295
-
-
The Al-F-Al bond angle in both complexes is ∼180°. (a) For R = Me: Allegra, G.; Perego, G. Acta Crystallogr. 1963, 16, 185.
-
(1963)
Acta Crystallogr.
, vol.16
, pp. 185
-
-
Allegra, G.1
Perego, G.2
-
86
-
-
33745753356
-
-
Pure orange complex 20 can be isolated; however, thermal decomposition in the solid state slowly occurs at room temperature.
-
Pure orange complex 20 can be isolated; however, thermal decomposition in the solid state slowly occurs at room temperature.
-
-
-
-
87
-
-
0034510217
-
-
Mes = mesityl. See: Schrock, R. R.; Casado, A. L.; Goodman, J. T.; Liang, L.-C.; Bonitatebus, P. J., Jr.; Davis, W. M. Organometallics 2000, 19, 5325-5341.
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(2000)
Organometallics
, vol.19
, pp. 5325-5341
-
-
Schrock, R.R.1
Casado, A.L.2
Goodman, J.T.3
Liang, L.-C.4
Bonitatebus Jr., P.J.5
Davis, W.M.6
-
88
-
-
0035972356
-
-
2). See: Duncan, A. P.; Mullins, S. M.; Arnold, J.; Bergman, R. G. Organometallics 2001, 20, 1808-1819.
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(2001)
Organometallics
, vol.20
, pp. 1808-1819
-
-
Duncan, A.P.1
Mullins, S.M.2
Arnold, J.3
Bergman, R.G.4
-
89
-
-
0343597460
-
-
- has been characterized (PPN = bis-(triphenylphosphine)nitrogen). See the following, for example, (a) R = tert-butyl, see: Harlan, C. J.; Bott. S. G.; Barron, A. R. J. Am. Chem. Soc. 1995, 117, 6465-6474.
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(1995)
Am. Chem. Soc.
, vol.117
, pp. 6465-6474
-
-
Harlan, C.J.1
Bott, S.G.2
Barron, A.R.J.3
-
90
-
-
0001330064
-
-
2Et), see: Harlan, C. J.; Gillan, E. G.; Bott, S. G.; Barron, A. R. Organometallics 1996, 15, 5479-5488.
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(1996)
Organometallics
, vol.15
, pp. 5479-5488
-
-
Harlan, C.J.1
Gillan, E.G.2
Bott, S.G.3
Barron, A.R.4
-
91
-
-
33745762446
-
-
- has also been characterized crystallographically; see: Atwood, J. L.; Rodgers, R. D.; Hrncir, D. C.; Zaworotko, M. J.; Hunter, W. E. Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Crystallogr. 1981, C83.
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(1981)
Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Crystallogr.
, vol.83
-
-
Atwood, J.L.1
Rodgers, R.D.2
Hrncir, D.C.3
Zaworotko, M.J.4
Hunter, W.E.5
-
93
-
-
0037454816
-
-
+ is the countercation; see: Vohs, J. K.; Downs, L. E.; Barfield, M. E.; Latibeaudiere, K. L.; Robinson, G. H. J. Organomet. Chem. 2003, 666, 7-13.
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(2003)
J. Organomet. Chem.
, vol.666
, pp. 7-13
-
-
Vohs, J.K.1
Downs, L.E.2
Barfield, M.E.3
Latibeaudiere, K.L.4
Robinson, G.H.5
-
96
-
-
84858922228
-
-
3, see
-
3, see:
-
-
-
-
97
-
-
0001057555
-
-
(d) Churchill, M. R.; Wasserman, H. J.; Turner, H. W.; Schrock, R. R. J. Am. Chem. Soc. 1982, 104, 1710-1716.
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(1982)
J. Am. Chem. Soc.
, vol.104
, pp. 1710-1716
-
-
Churchill, M.R.1
Wasserman, H.J.2
Turner, H.W.3
Schrock, R.R.4
-
99
-
-
0037120823
-
-
see: (f) Sugiyama, H.; Aharonian, G.; Gambarotta, S.; Yap, G. P. A.; Budzelaar, P. H. M. J. Am. Chem. Soc. 2002, 124, 12268-12274.
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(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 12268-12274
-
-
Sugiyama, H.1
Aharonian, G.2
Gambarotta, S.3
Yap, G.P.A.4
Budzelaar, P.H.M.5
-
100
-
-
0000990422
-
-
3, see: Coles, S. J.; Hursthouse, M. B.; Kelly, D. G.; Walker, N. M. J. Organomet. Chem. 1999, 580, 304.
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(1999)
J. Organomet. Chem.
, vol.580
, pp. 304
-
-
Coles, S.J.1
Hursthouse, M.B.2
Kelly, D.G.3
Walker, N.M.4
-
101
-
-
0034319448
-
-
(a) Klosin, J.; Roof, G. R.; Chen, E. Y.-X.; Abboud, K. A. Organometallics 2000, 19, 4684.
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(2000)
Organometallics
, vol.19
, pp. 4684
-
-
Klosin, J.1
Roof, G.R.2
Chen, E.Y.-X.3
Abboud, K.A.4
-
102
-
-
0037423440
-
-
(b) Hair, G. S.; Cowley, A. H.; Gorden, J. D.; Jones, J. N.; Jones, R. A.; Macdonald, C. L. B. Chem. Commun. 2003, 3, 424-425.
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, vol.3
, pp. 424-425
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Hair, G.S.1
Cowley, A.H.2
Gorden, J.D.3
Jones, J.N.4
Jones, R.A.5
Macdonald, C.L.B.6
-
103
-
-
0000851827
-
-
For recent examples of organogallium-F complexes, see: (a) Werner, B.; Krauter, T.; Neumüller, B. Organometallics 1996, 15, 3746-3751.
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(1996)
Organometallics
, vol.15
, pp. 3746-3751
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-
Werner, B.1
Krauter, T.2
Neumüller, B.3
-
104
-
-
33745745874
-
-
See ref 30a for examples of nonlinear fluoro-bridged Ga complexes
-
(b) See ref 30a for examples of nonlinear fluoro-bridged Ga complexes.
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-
-
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