The strongest isolable acid

Angewandte Chemie - International Edition

Volumn 43, Issue 40, 2004, Pages 5352-5355

  Juhasz, Mark ^a   Hoffmann, Stephan ^a   Stoyanov, Evgenii ^b   Kim, Kee Chan ^a   Reed, Christopher A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

Author keywords

Acids; Basicity suppression; Br nsted acids; Carboranes; IR spectroscopy

Indexed keywords

CARBON; CHEMICAL BONDS; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

BRONSTED ACIDS; CARBORANE ACIDS;

ORGANIC ACIDS;

ACID; CARBORANE DERIVATIVE; LEWIS ACID;

ACIDITY; ALKALINITY; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; DECOMPOSITION; HYDROGEN BOND; LOW TEMPERATURE; MOLECULAR STABILITY; OLIGOMERIZATION; PROTON TRANSPORT; QUALITATIVE ANALYSIS; ROOM TEMPERATURE; SOLVATION; TECHNIQUE; TEMPERATURE DEPENDENCE;

ACIDS; BINDING SITES; BORANES; DIMETHYLAMINES; HEXANONES; HYDROGEN; HYDROGEN-ION CONCENTRATION; MAGNETIC RESONANCE SPECTROSCOPY; NITROGEN; OXIDATION-REDUCTION; PHOTONS; QUATERNARY AMMONIUM COMPOUNDS;

EID: 7244229664     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460005     Document Type: Article

References (22)

1. C. A. Reed, K.-C. Kim, R. D. Bolskar, L. Mueller, Science 2000, 289, 101.
2. D. M. Brouwer, E. L. Mackor, C. MacLean in Carbonium Ions, Vol. 1 (Eds.: G. A. Olah, P. v. R. Schleyer), Wiley-Interscience, New York, 1970, p. 837.
3. C. A. Reed, K.-C. Kim, E. S. Stoyanov, D. Stasko, F. S. Tham, L. J. Mueller, P. D. W. Boyd, J. Am. Chem. Soc. 2003, 125, 1796.
4. T. Kato, C. A. Reed, Angew. Chem. 2004, 116, 2967-2971; Angew. Chem. Int. Ed. 2004, 43, 2907-2911.
5. T. Kato, C. A. Reed, Angew. Chem. 2004, 116, 2967-2971; Angew. Chem. Int. Ed. 2004, 43, 2907-2911.
6. G. A. Olah, G. K. S. Prakash, J. Sommer, Superacids, Wiley, New York, 1985.
7. I. A. Koppel, P. Burk, I. Koppel, I. Leito, T. Sonoda, M. Mishima, J. Am. Chem. Soc. 2000, 122, 5114.
8. D. Fǎrcaşiu, A. Ghenciu, J. Am. Chem. Soc. 1993, 115, 10901.
9. C. Fischer, H. Wagner, V. V. Bagreev, E. S. Stoyanov, J. Inorg. Nucl. Chem. 1977, 39, 513.
10. M. M. Davis, Acid-Base Behavior in Aprotic Organic Solvents, Department of Commerce, National Bureau of Standards, Washington, DC, 1968, 113.
11. W. E. Farneth, R. J. Gorte, Chem. Rev. 1995, 95, 615.
12. R. A. v. Santen, G. J. Kramer, Chem. Rev. 1995, 95, 637.
13. D. Fǎrcaşiu, D. Hâncu, Catal. Lett. 1998, 53, 3.
14. A. V. Iogansen in The Hydrogen Bond (Ed.: N. D. Sokolov), Nauka, Moscow, 1981, pp. 112-155.
15. M. D. Joesten, R. S. Drago, J. Am. Chem. Soc. 1962, 84, 3817.
16. E. M. Arnett, L. Joris, E. Mitchell, T. S. S. R. Murty, T. M. Gorrie, P. v. R. Schleyer, J. Am. Chem. Soc. 1970, 92, 2365.
17. R. S. Drago, N. O'Bryan, G. C. Vogel, J. Am. Chem. Soc. 1970, 92, 3924.
18. A. D. Sherry, K. F. Purcell, J. Am. Chem. Soc. 1972, 94, 1853.
19. D. Stasko, C. A. Reed, J. Am. Chem. Soc. 2002, 124, 1148.
20. Z. Xie, C.-W. Tsang, E. T.-P. Sze, Q. Yang, D. T. W. Chan, T. C. W. Mak, Inorg. Chem. 1998, 37, 6444.
21. -1) is even higher than that of the carborane salts.
22. C. A. Reed, N. L. P. Fackler, K.-C. Kim, D. Stasko, D. R. Evans, P. D. W. Boyd, C. E. F. Rickard, J. Am. Chem. Soc. 1999, 121, 6314.