Activation of Ti-F Bonds in [{(C5Me5)TiOF}4] and [{(C5Me4Et)TiOF}4] with AlMe3

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 16, 1997, Pages 1766-1767

  Yu, Peihua ^a   Roesky, Herbert W ^a   Demsar, Alojz ^a   Albers, Thomas ^a   Schmidt, Hans Georg ^a   Noltemeyer, Mathias ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Aluminum; Fluorine; Titanium

Indexed keywords

EID: 0030853663     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199717661     Document Type: Article

References (13)

1. H. Plenio, R. Diodone, J. Am. Chem. Soc. 1996, 118, 356, contains numerous references on C-F-metal ion contacts.
2. S. Walter, U. Klingebiel, Coord. Chem. Rev. 1994, 130, 481.
3. M. Driess, U. Winkler, W. Imhof, L. Zsolnai, G. Huttner, Chem. Ber. 1994, 127, 1031.
4. H.-H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger, R. Waymouth, Angew. Chem. 1995, 107, 1255; Angew. Chem. Int. Ed. Engl. 1995, 34, 1143.
5. H.-H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger, R. Waymouth, Angew. Chem. 1995, 107, 1255; Angew. Chem. Int. Ed. Engl. 1995, 34, 1143.
6. Y.-X. Chen, C. L. Stern, S. Yang, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 12451.
7. H. W. Roesky, I. Leichtweis, M. Noltemeyer, Inorg. Chem. 1993, 32, 5102.
8. A. Herzog, F.-Q. Liu, H. W. Roesky, A. Demsar, K. Keller, M. Noltemeyer, F. Pauer, Organometallics 1994, 13, 1257.
9. R. Andrés, M. V. Galakhov, A. Martín, M. Mena, C. Santamaria, Organometallics 1994, 13, 2159; P. Gómez-Sal, A. Martin, M. Mena, C. Yélamos, Inorg. Chem. 1996, 35, 242.
10. R. Andrés, M. V. Galakhov, A. Martín, M. Mena, C. Santamaria, Organometallics 1994, 13, 2159; P. Gómez-Sal, A. Martin, M. Mena, C. Yélamos, Inorg. Chem. 1996, 35, 242.
11. F.-Q. Liu, H. Gornitzka, D. Stalke, H. W. Roesky, Angew. Chem. 1993, 105, 447; Angew. Chem. Int. Ed. Engl. 1993, 32, 442.
12. F.-Q. Liu, H. Gornitzka, D. Stalke, H. W. Roesky, Angew. Chem. 1993, 105, 447; Angew. Chem. Int. Ed. Engl. 1993, 32, 442.
13. κα) = 0.71073 Å, T = 203 K. 8936 independent reflections were used for the structure solution and refinement. R = 0.0423, wR = 0.0966. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100134. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road. Cambridge CB2 1EZ, UK (fax: int. code +(1223) 336-033; e-mail: deposit@chemcrys.cam.ac.uk).