tert-amyl compounds of aluminum and gallium: Halides, hydroxides, and chalcogenides

Organometallics

Volumn 15, Issue 26, 1996, Pages 5479-5488

  Harlan, C Jeff ^a   Gillan, Edward G ^a   Bott, Simon G ^b   Barron, Andrew R ^a  

^a RICE UNIVERSITY   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001330064     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9605185     Document Type: Article

References (74)

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6. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
7. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
8. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
9. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
10. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
11. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
12. For examples of monomeric aluminum trialkyl compounds, see: (a) Eisch, J. J.; Biedermann, J. M. J. Organomet. Chem. 1971, 30, 167. (b) Kroll, W. R.; Hudson, B. E., Jr. J. Organomet. Chem. 1971, 28, 205. (c) Moriarty, R. M.; Chin, A. J. Chem. Soc., Chem. Commun. 1972, 1300. (d) Haaland, A.; Weidlein, J. J. Organomet. Chem. 1972, 40, 29. (e) Owens, M. R. J. Organomet. Chem. 1973, 55, 237. (f) Starowieyski, K. B.; Bandlow, C.; Haage, K. J. Organomet. Chem. 1976, 117, 215. (g) Jerius, J. J.; Hahn, J. M.; Rahman, A. F. M.; Mols, O.; Ilsley, W. H.; Oliver, J. P. Organometallics 1986, 5, 1812.
13. 3, Z = 4, λ(Mo-Kα) = 0.710 73 Å (graphite monochromator), T = 214 K.
14. Acetonitrile complexes of aluminum alkyls have been previously reported; see: (a) Jennings, J. R.; Lloyd, J. E.; Wade, K. J. Chem. Soc. 1965, 5083. (b) Healy, M. D.; Ziller, J. W.; Barron, A. R. Organometallics 1991, 10, 597.
15. Acetonitrile complexes of aluminum alkyls have been previously reported; see: (a) Jennings, J. R.; Lloyd, J. E.; Wade, K. J. Chem. Soc. 1965, 5083. (b) Healy, M. D.; Ziller, J. W.; Barron, A. R. Organometallics 1991, 10, 597.
16. The formation of an anionic Lewis base complex is commonly observed whenever ionic salts react with aluminum alkyls; see: (a) Sneddon, G. J. Chem. Ind. (London) 1961, 1492. (b) Zakharkin, L. I.; Gavrilenko, V. V. J. Gen. Chem. USSR (Engl. Transl.) 1962, 688. (c) Ziegler, K.; Köster, R.; Lehmkuhl, H.; Reinert, K. Justus Liebigs Ann. Chem. 1960, 629, 33. (d) Ziegler, K.; Lehmkuhl, H.; Linder, E. Chem. Ber. 1959, 92, 2320.
17. The formation of an anionic Lewis base complex is commonly observed whenever ionic salts react with aluminum alkyls; see: (a) Sneddon, G. J. Chem. Ind. (London) 1961, 1492. (b) Zakharkin, L. I.; Gavrilenko, V. V. J. Gen. Chem. USSR (Engl. Transl.) 1962, 688. (c) Ziegler, K.; Köster, R.; Lehmkuhl, H.; Reinert, K. Justus Liebigs Ann. Chem. 1960, 629, 33. (d) Ziegler, K.; Lehmkuhl, H.; Linder, E. Chem. Ber. 1959, 92, 2320.
18. The formation of an anionic Lewis base complex is commonly observed whenever ionic salts react with aluminum alkyls; see: (a) Sneddon, G. J. Chem. Ind. (London) 1961, 1492. (b) Zakharkin, L. I.; Gavrilenko, V. V. J. Gen. Chem. USSR (Engl. Transl.) 1962, 688. (c) Ziegler, K.; Köster, R.; Lehmkuhl, H.; Reinert, K. Justus Liebigs Ann. Chem. 1960, 629, 33. (d) Ziegler, K.; Lehmkuhl, H.; Linder, E. Chem. Ber. 1959, 92, 2320.
19. The formation of an anionic Lewis base complex is commonly observed whenever ionic salts react with aluminum alkyls; see: (a) Sneddon, G. J. Chem. Ind. (London) 1961, 1492. (b) Zakharkin, L. I.; Gavrilenko, V. V. J. Gen. Chem. USSR (Engl. Transl.) 1962, 688. (c) Ziegler, K.; Köster, R.; Lehmkuhl, H.; Reinert, K. Justus Liebigs Ann. Chem. 1960, 629, 33. (d) Ziegler, K.; Lehmkuhl, H.; Linder, E. Chem. Ber. 1959, 92, 2320.
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26. 5
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28. 3, Z = 8, λ(Mo-Kα) = 0.71073 Å (graphite monochromator), T = 214 K.
29. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
30. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
31. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
32. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
33. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
34. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
35. See for example: (a) Brauer, D. J.; Stucky, G. D. J. Am. Chem. Soc. 1969, 91, 5462. (b) Haaland, A.; Stokkeland, O.; Weidlein, J. J. Organomet. Chem. 1975, 94, 353. (c) Shakir, R.; Zaworotko, M. J.; Atwood, J. L. J. Organomet. Chem. 1979, 171, 9. (d) Boardman, A.; Small, R. W. H.; Worrall, I. J., Inorg. Chim. Acta 1986, 120, L23. (e) Kumar, R.; de Mel, V. C. J.; Oliver, J. P. Organometallics 1989, 8, 2488. (f) de Mel, V. C. J.; Kumar, R.; Oliver, J. P. Organometallics 1990, 9, 1303. (g) Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
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