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3
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9
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33744805515
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note
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The STM is a variation of the one described in (26).
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11
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4544370376
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S. W. Wu, G. V. Nazin, X. Chen, X. H. Qiu, W. Ho, Phys. Rev. Lett. 93, 236802 (2004).
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12
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0003641908
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K. M. Kadish, K. M. Smith, R. Guilard, Eds., (Academic Press, New York)
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K. M. Kadish, K. M. Smith, R. Guilard, Eds., The Porphyrin Handbook (Academic Press, New York, 2000).
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13
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3242752628
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J. Repp, G. Meyer, F. E. Olsson, M. Persson, Science 305, 493 (2004).
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Repp, J.1
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14
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33744816352
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note
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The tunneling electron-induced fluorescence was observed from the same configuration (tip/vacuum/MgP/ oxide/NiAl) but for a different type of molecular adsorption than the one discussed here. The radiative transition from LUMO+1 to LUMO occurs at about 800 nm.
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16
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33744787486
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note
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We have carried out the DFT calculations on a free, planar MgP by using HyperChem 7.0. The results are identical to those for ZnP.
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17
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33847089265
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D. Spangler, G. M. Maggiora, L. L. Shipman, R. E. Christoffersen, J. Am. Chem. Soc. 99, 7478 (1977).
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Christoffersen, R.E.4
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18
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33744806229
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note
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In principle, the level of LUMO+1 is not tied to the Fermi levels as a result of the distribution of voltage drops in the double-barrier junction (11). However, because the ratio of the voltage drop is large (∼7) and the bias applied across the junction is small, the level shift of the LUMO+1 with respect to the Fermi level of the NiAl substrate for different biases is negligible.
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19
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18144386607
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J. Repp, G. Meyer, S. M. Stojkovic, A. Gourdon, C. Joachim, Phys. Rev. Lett. 94, 026803 (2005).
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Joachim, C.5
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23
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0000735187
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T. H. Oosterkamp, L. P. Kouwenhoven, A. E. A. Koolen, N. C. van der Vaart, C. J. P. M. Harmans, Phys. Rev. Lett. 78, 1536 (1997).
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Harmans, C.J.P.M.5
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27
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0028269587
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J. K. Trautman, J. J. Macklin, L. E. Brus, E. Betzig, Nature 369, 40 (1994).
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29
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33744800148
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note
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From molecule to molecule, the onset varies (within 0.15 V) for the lowest unoccupied state (LUMO-α) of the neutral molecule. The onset of all the other unoccupied states varies approximately with the LUMO-α.
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30
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33744812867
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note
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Each data point (150 cycles) took about 80 min to measure. The reason for taking 150 cycles is to reduce the data fluctuation due to the blinking effect similar to that observed in (27, 28).
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31
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33744788488
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note
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Supported by the Chemical Science, Geo- and Bioscience Division, Office of Science, U.S. Department of Energy, under grant DE-FG02-04ER1595. The California Institute for Telecommunication and Information Technology at University of California-lrvine provided a fellowship to N.O.
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