Evidence for C-H cleavage by an iron-superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase

Proceedings of the National Academy of Sciences of the United States of America

Volumn 103, Issue 16, 2006, Pages 6130-6135

  Xing, Gang ^a   Diao, Yinghui ^a   Hoffart, Lee M ^a   Barr, Eric W ^a   Prabhu, K Sandeep ^a   Arner, Ryan J ^a   Reddy, C Channa ^a   Krebs, Carsten ^a   Bollinger Jr , J Martin ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

Mixed valent; Nonheme diiron enzymes; Oxygen activation; Superoxo intermediate

Indexed keywords

CARBON; COORDINATION COMPOUND; CYCLOHEXAN 1,2,3,4,5,6 OL; CYCLOHEXANOL DERIVATIVE; GLUCURONIC ACID; GLYCOL; HYDROGEN; INOSITOL; INOSITOL OXYGENASE; IRON; IRON 57; IRON COMPLEX; OXYGEN; OXYGENASE; SUPEROXIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONTROLLED STUDY; ELECTRON; ELECTRON SPIN RESONANCE; KINETIC ISOTOPE EFFECT; LYSIS; NONHUMAN; OXIDATION; PRIORITY JOURNAL;

ANIMALS; CARBON; CATALYSIS; ELECTRON SPIN RESONANCE SPECTROSCOPY; GLYCOLS; HYDROGEN; INOSITOL; INOSITOL OXYGENASE; MICE; PHOTOLYSIS; SUPEROXIDES;

EID: 33646555501     PISSN: 00278424     EISSN: None     Source Type: Journal    
DOI: 10.1073/pnas.0508473103     Document Type: Article

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