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Volumn 6, Issue 21, 2000, Pages 3871-3886

Hierarchical Self-Organization of Perylene Bisimide - Melamine Assemblies to Fluorescent Mesoscopic Superstructures

Author keywords

Dyes; Fluorescence; Nanostructures; Noncovalent interactions; Supramolecular chemistry

Indexed keywords

CHLOROPHYLL; DYE; HYDROGEN; IMIDE; MELAMINE; PERYLENE; POLYMER; SOLVENT; TRIAZINE DERIVATIVE;

EID: 85046527666     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20001103)6:21<3871::AID-CHEM3871>3.3.CO;2-W     Document Type: Article
Times cited : (234)

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    • A recent crystal structure of a related dye revealed a torsion angle of 25° for the central ring which agrees favorably with AM1 calculations: F. Wurthner, A. Sautter, C. Thalacker, Angew. Chem. 2000, 112, 1298-1301; Angew. Chem. Int. Ed. 2000, 39, 1243-1245.
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    • In principle, thermodynamic parameters ΔH and ΔS are accessible from this analysis. However, because of the rather arbitrary choice of the model no values will be given in this paper.
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    • -1 solutions of pure dialkylmelamine 8c in methylcyclohexane suggest that already in the absence of bisimide dyes large-sized colloidal particles are formed.
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    • A structurally related system where the solvent used for the staining procedure had a substantial effect on superstructure formation is described in ref. [4j].
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    • A rod-like helical structure has been suggested for a melamine-naphthalene bisimide system. See ref. [4d].
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