Synthesis of 2,4,6-tri-substituted-1,3,5-triazines

Molecules

Volumn 11, Issue 1, 2006, Pages 81-102

  Afonso, Carlos A M ^a   Lourenço, Nuno M T ^b   De Rosatella, Andreia A ^b  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^b UNIVERSIDADE NOVA DE LISBOA   (Portugal)

Author keywords

1,3,5 triazine; Cyanuric chloride; Melamine derivatives; S triazine

Indexed keywords

EID: 33644797421     PISSN: 14203049     EISSN: 14203049     Source Type: Journal    
DOI: 10.3390/11010081     Document Type: Article

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85. 2S: 128.0408, found: 128.0410.
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87. 2: 230.211, found: 230.212.
88. In the case of the preparation of 1,3,5-triazines containing the dimethylamino group dimethylammonium chloride (1.0 mol eq.) and diisopropylethylamine (3.2 mol eq.) were used.
89. 18NO: 180.1388, found: 180.1380. A mixture of the above compound (198.9 mg, 1.11 mmol) and Pd/C (10 %) (73 mg) in ethanol (6 mL) under hydrogen atmosphere (balloon) was strongly stirred at room temperature during 1.5 hr (complete reaction by TLC). Argon atmosphere was introduced and the mixture was used directly to the next step.
90. In the other examples, pure amines were added to the reaction mixture.