Chalcogen-containing oxazolines in the palladium-catalyzed asymmetric allylic alkylation

Journal of the Brazilian Chemical Society

Volumn 17, Issue 1, 2006, Pages 11-15

  Braga, Antonio L ^a   Lüdtke, Diogo S ^a   Alberto, Eduardo E ^a  

^a FEDERAL UNIVERSITY OF SANTA MARIA   (Brazil)

Author keywords

Asymmetric allylic alkylation; Oxazolines; Palladium; Selenium; Tellurium

Indexed keywords

EID: 32444450704     PISSN: 01035053     EISSN: 01035053     Source Type: Journal    
DOI: 10.1590/S0103-50532006000100002     Document Type: Article

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59. 4, the solvent was evaporated and the crude product was purified by flash chromatography eluting with hexane/ethyl acetate (98/2). Enantiomeric excess was determined by chiral HPLC (Chiralcel OD column. 0.5 mL min-1, hexane:2-propanol 99:1, 254 nm). The optical rotation of the product was compared with literature data to assign the absolute configuration (R).
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