-
3
-
-
7244234296
-
-
(c) Gambarotta, S.; Scott, J. Angew. Chem., Int. Ed. 2004, 43, 5298-5308.
-
(2004)
Angew. Chem., Int. Ed.
, vol.43
, pp. 5298-5308
-
-
Gambarotta, S.1
Scott, J.2
-
10
-
-
84902434526
-
Nitrogen Fixation
-
McCleverty, J.; Meyer, T. J., Eds. Elsevier: Oxford
-
(f) Holland, P. L., "Nitrogen Fixation," in Comprehensive Coordination Chemistry II, McCleverty, J.; Meyer, T. J., Eds. Elsevier: Oxford, 2004; Vol. 8, pp 569-599.
-
(2004)
Comprehensive Coordination Chemistry II
, vol.8
, pp. 569-599
-
-
Holland, P.L.1
-
11
-
-
0022622042
-
-
Iron-vanadium nitrogenase: (a) Robson, R. L.; Eady, R. R.; Richardson, T. H.; Miller, R. W.; Hawkins, M.; Postgate, J. R. Nature 1986, 322, 388-390.
-
(1986)
Nature
, vol.322
, pp. 388-390
-
-
Robson, R.L.1
Eady, R.R.2
Richardson, T.H.3
Miller, R.W.4
Hawkins, M.5
Postgate, J.R.6
-
12
-
-
0023099758
-
-
(b) Arber, J. M.; Dobson, B. R.; Eady, R. R.; Stevens, P.; Hasnain, S. S.; Garner, C. D.; Smith, B. E. Nature 1987, 325, 372-374.
-
(1987)
Nature
, vol.325
, pp. 372-374
-
-
Arber, J.M.1
Dobson, B.R.2
Eady, R.R.3
Stevens, P.4
Hasnain, S.S.5
Garner, C.D.6
Smith, B.E.7
-
14
-
-
0023647093
-
-
(d) Morningstar, J. E.; Johnson, M. K.; Case, E. E.; Hales, B. J. Biochemistry 1987, 26, 1795-1800.
-
(1987)
Biochemistry
, vol.26
, pp. 1795-1800
-
-
Morningstar, J.E.1
Johnson, M.K.2
Case, E.E.3
Hales, B.J.4
-
15
-
-
0024969858
-
-
(e) Arber, J. M.; Dobson, B. R.; Eady, R. R.; Hasnain, S. S.; Garner, C. D.; Matsushita, T.; Nomura, M.; Smith, B. E. Biochem. J. 1989, 258, 733-737.
-
(1989)
Biochem. J.
, vol.258
, pp. 733-737
-
-
Arber, J.M.1
Dobson, B.R.2
Eady, R.R.3
Hasnain, S.S.4
Garner, C.D.5
Matsushita, T.6
Nomura, M.7
Smith, B.E.8
-
16
-
-
0001219252
-
-
(f) Eady, R. R. Chem. Rev. 1996, 96, 3013-3030.
-
(1996)
Chem. Rev.
, vol.96
, pp. 3013-3030
-
-
Eady, R.R.1
-
19
-
-
0026508184
-
-
Iron-only nitrogenase: (a) Müller, A.; Schneider, K.; Knüttel, K.; Hagen, W. R. FEBS Lett. 1992, 303, 36-40.
-
(1992)
FEBS Lett.
, vol.303
, pp. 36-40
-
-
Müller, A.1
Schneider, K.2
Knüttel, K.3
Hagen, W.R.4
-
20
-
-
0030896140
-
-
(b) Schneider, K.; Gollan, U.; Dröttboom, M.; Selsemeier-Voigt, S.; Müller, A. Eur. J. Biochem. 1997, 244, 789-800.
-
(1997)
Eur. J. Biochem.
, vol.244
, pp. 789-800
-
-
Schneider, K.1
Gollan, U.2
Dröttboom, M.3
Selsemeier-Voigt, S.4
Müller, A.5
-
21
-
-
0036229471
-
-
(c) Siemann, S.; Schneider, K.; Drottboom, M.; Muller, A. Eur. J. Biochem. 2002, 269, 1650-1661.
-
(2002)
Eur. J. Biochem.
, vol.269
, pp. 1650-1661
-
-
Siemann, S.1
Schneider, K.2
Drottboom, M.3
Muller, A.4
-
22
-
-
0036358695
-
-
(d) Krahn, E.; Weiss, B. J. R.; Krockel, M.; Groppe, J.; Henkel, G.; Cramer, S. P.; Trautwein, A. X.; Schneider, K.; Muller, A. J. Biol. Inorg. Chem. 2002, 7, 37-45.
-
(2002)
J. Biol. Inorg. Chem.
, vol.7
, pp. 37-45
-
-
Krahn, E.1
Weiss, B.J.R.2
Krockel, M.3
Groppe, J.4
Henkel, G.5
Cramer, S.P.6
Trautwein, A.X.7
Schneider, K.8
Muller, A.9
-
23
-
-
0037031703
-
-
Einsle, O.; Tezcan, F. A.; Andrade, S. L. A.; Schmid, B.; Yoshida, M.; Howard, J. B.; Rees, D. C. Science 2002, 297, 1696-1700.
-
(2002)
Science
, vol.297
, pp. 1696-1700
-
-
Einsle, O.1
Tezcan, F.A.2
Andrade, S.L.A.3
Schmid, B.4
Yoshida, M.5
Howard, J.B.6
Rees, D.C.7
-
24
-
-
0001179260
-
-
(a) Yoo, S. J.; Angove, H. C.; Papaefthymiou, V.; Burgess, B. K.; Münck, E. J. Am. Chem. Soc. 2000, 122, 4926-4936.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 4926-4936
-
-
Yoo, S.J.1
Angove, H.C.2
Papaefthymiou, V.3
Burgess, B.K.4
Münck, E.5
-
25
-
-
0141480187
-
-
(b) Vrajmasu, V.; M̈nck, E.; Bominaar, E. L. Inorg. Chem. 2003, 42, 5974-5988.
-
(2003)
Inorg. Chem.
, vol.42
, pp. 5974-5988
-
-
Vrajmasu, V.1
M̈nck, E.2
Bominaar, E.L.3
-
26
-
-
0037423428
-
-
Calculations support the idea that X is a nitrogen atom: (a) Dance, I. Chem. Commun. 2003, 324-325.
-
(2003)
Chem. Commun.
, pp. 324-325
-
-
Dance, I.1
-
28
-
-
0037668080
-
-
(c) Lovell, T.; Liu, T.; Case, D. A.; Noodleman, L. J. Am. Chem. Soc. 2003, 125, 8377-8383.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 8377-8383
-
-
Lovell, T.1
Liu, T.2
Case, D.A.3
Noodleman, L.4
-
29
-
-
0347625745
-
-
(d) Schimpl, J.; Petrilli, H. M.; Blöchl, P. E. J. Am. Chem. Soc. 2003, 125, 15772-15778.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 15772-15778
-
-
Schimpl, J.1
Petrilli, H.M.2
Blöchl, P.E.3
-
30
-
-
1542276760
-
-
(e) Huniar, U.; Ahlrichs, R.; Coucouvanis, D. J. Am. Chem. Soc. 2004, 126, 2588-2601.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 2588-2601
-
-
Huniar, U.1
Ahlrichs, R.2
Coucouvanis, D.3
-
32
-
-
25144493215
-
-
However, recent ENDOR and ESEEM studies argue strongly against nitrogen as X: Yang, T.-C.; Maeser, N. K.; Laryukhin, M.; Lee, H.-I.; Dean, D. R.; Seefeldt, L. C.; Hoffman, B. M. J. Am. Chem. Soc. 2005, 127, 12804-12805.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 12804-12805
-
-
Yang, T.-C.1
Maeser, N.K.2
Laryukhin, M.3
Lee, H.-I.4
Dean, D.R.5
Seefeldt, L.C.6
Hoffman, B.M.7
-
33
-
-
0023516820
-
-
(a) Thomann, H.; Morgan, T. V.; Jin, H.; Burgmayer, S. J. N.; Bare, R. E.; Stiefel, E. I. J. Am. Chem. Soc. 1987, 109, 7913-7914.
-
(1987)
J. Am. Chem. Soc.
, vol.109
, pp. 7913-7914
-
-
Thomann, H.1
Morgan, T.V.2
Jin, H.3
Burgmayer, S.J.N.4
Bare, R.E.5
Stiefel, E.I.6
-
34
-
-
0038701797
-
-
(b) Lee, H.-I.; Benton, P. M. C.; Laryukhin, M.; Igarashi, R. Y.; Dean, D. R.; Seefeldt, L. C.; Dean, D. R. J. Am. Chem. Soc. 2003, 125, 5604-5605.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 5604-5605
-
-
Lee, H.-I.1
Benton, P.M.C.2
Laryukhin, M.3
Igarashi, R.Y.4
Dean, D.R.5
Seefeldt, L.C.6
Dean, D.R.7
-
39
-
-
0035780979
-
-
(a) Christiansen, J.; Dean, D. R.; Seefeldt, L. C. Annu. Rev. Plant Physiol. Plant Mol. Biol. 2001, 52, 269-295.
-
(2001)
Annu. Rev. Plant Physiol. Plant Mol. Biol.
, vol.52
, pp. 269-295
-
-
Christiansen, J.1
Dean, D.R.2
Seefeldt, L.C.3
-
40
-
-
0035923457
-
-
(b) Benton, P. M. C.; Mayer, S. M.; Shao, J.; Hoffman, B. M.; Dean, D. R.; Seefeldt, L. C. Biochemistry 2001, 40, 13816-13825.
-
(2001)
Biochemistry
, vol.40
, pp. 13816-13825
-
-
Benton, P.M.C.1
Mayer, S.M.2
Shao, J.3
Hoffman, B.M.4
Dean, D.R.5
Seefeldt, L.C.6
-
41
-
-
0035819978
-
-
(c) Benton, P. M. C.; Christiansen, J.; Dean, D. R.; Seefeldt, L. C. J. Am. Chem. Soc. 2001, 123, 1822-1827.
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 1822-1827
-
-
Benton, P.M.C.1
Christiansen, J.2
Dean, D.R.3
Seefeldt, L.C.4
-
43
-
-
0043167784
-
-
(e) Benton, P. M. C.; Laryukhin, M.; Mayer, S. M.; Hoffman, B. M.; Dean, D. R.; Seefeldt, L. C. Biochemistry 2003, 42, 9102-9109.
-
(2003)
Biochemistry
, vol.42
, pp. 9102-9109
-
-
Benton, P.M.C.1
Laryukhin, M.2
Mayer, S.M.3
Hoffman, B.M.4
Dean, D.R.5
Seefeldt, L.C.6
-
44
-
-
3543112704
-
-
(f) Lee, H.-I.; Igarashi, R. Y.; Laryukhin, M.; Doan, P. E.; Dos Santos, P. C.; Dean, D. R.; Seefeldt, L. C.; Hoffman, B. M. J. Am. Chem. Soc. 2004, 126, 9563-9569.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 9563-9569
-
-
Lee, H.-I.1
Igarashi, R.Y.2
Laryukhin, M.3
Doan, P.E.4
Dos Santos, P.C.5
Dean, D.R.6
Seefeldt, L.C.7
Hoffman, B.M.8
-
45
-
-
4544311893
-
-
(g) Igarashi, R. Y.; Dos Santos, P. C.; Niehaus, W. G.; Dance, I. G.; Dean, D. R.; Seefeldt, L. C. J. Biol. Chem. 2004, 279, 34770-34775.
-
(2004)
J. Biol. Chem.
, vol.279
, pp. 34770-34775
-
-
Igarashi, R.Y.1
Dos Santos, P.C.2
Niehaus, W.G.3
Dance, I.G.4
Dean, D.R.5
Seefeldt, L.C.6
-
46
-
-
11144229617
-
-
(h) Barney, B. M.; Igarashi, R. Y.; Dos Santos, P. C.; Dean, D. R.; Seefeldt, L. C. J. Biol. Chem. 2004, 279, 53621-53624.
-
(2004)
J. Biol. Chem.
, vol.279
, pp. 53621-53624
-
-
Barney, B.M.1
Igarashi, R.Y.2
Dos Santos, P.C.3
Dean, D.R.4
Seefeldt, L.C.5
-
47
-
-
15244343409
-
-
(i) Dos Santos, P. C.; Igarashi, R. Y.; Lee, H.-I.; Hoffman, B. M.; Seefeldt, L. C.; Dean, D. R. Acc. Chem. Res. 2005, 38, 208-214.
-
(2005)
Acc. Chem. Res.
, vol.38
, pp. 208-214
-
-
Dos Santos, P.C.1
Igarashi, R.Y.2
Lee, H.-I.3
Hoffman, B.M.4
Seefeldt, L.C.5
Dean, D.R.6
-
48
-
-
20144378589
-
-
(j) Barney, B. M.; Laryukhin, M.; Igarashi, R. Y. Lee, H.-I.; Dos Santos, P. C.; Yang, T.-C.; Hoffman, B. M.; Dean, D. R. Seefeldt, L. C. Biochemistry 2005, 44, 8030-8037.
-
(2005)
Biochemistry
, vol.44
, pp. 8030-8037
-
-
Barney, B.M.1
Laryukhin, M.2
Igarashi, R.Y.3
Lee, H.-I.4
Dos Santos, P.C.5
Yang, T.-C.6
Hoffman, B.M.7
Dean, D.R.8
Seefeldt, L.C.9
-
49
-
-
18244372970
-
-
(k) Igarashi, R. Y. Laryukhin, M.; Dos Santos, P. C.; Lee, H.-I.; Dean, D. R.; Seefeldt, L. C. Hoffman. B. M. J. Am. Chem. Soc. 2005, 127, 6231-6241.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 6231-6241
-
-
Igarashi, R.Y.1
Laryukhin, M.2
Dos Santos, P.C.3
Lee, H.-I.4
Dean, D.R.5
Seefeldt, L.C.6
Hoffman, B.M.7
-
50
-
-
1142275465
-
-
Seefeldt, L. C.; Dance, I. G.; Dean, D. R. Biochemistry 2004, 43, 1401-1409.
-
(2004)
Biochemistry
, vol.43
, pp. 1401-1409
-
-
Seefeldt, L.C.1
Dance, I.G.2
Dean, D.R.3
-
51
-
-
21744441467
-
-
The role of X may be to reversibly coordinate to iron in the native form but release low-coordinate iron in reduced forms of the cofactor: Holland, P. L. Can. J. Chem. 2005, 83, 296-301.
-
(2005)
Can. J. Chem.
, vol.83
, pp. 296-301
-
-
Holland, P.L.1
-
53
-
-
27544492629
-
-
Barney, B. M.; Yang, T.-C.; Igarashi, R. Y.; Dos Santos, P. C.; Laryukhin, M.; Lee, H.-I.; Hoffman, B. M.; Dean, D. R.; Seefeldt, L. C. J. Am. Chem. Soc. 2005, 127, 14960-14961.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 14960-14961
-
-
Barney, B.M.1
Yang, T.-C.2
Igarashi, R.Y.3
Dos Santos, P.C.4
Laryukhin, M.5
Lee, H.-I.6
Hoffman, B.M.7
Dean, D.R.8
Seefeldt, L.C.9
-
54
-
-
0032563811
-
-
Brandes, J. A.; Boctor, N. Z.; Cody, G. D.; Cooper, B. A.; Hazen, R. M.; Yoder, H. S. Nature 1998, 395, 365-367.
-
(1998)
Nature
, vol.395
, pp. 365-367
-
-
Brandes, J.A.1
Boctor, N.Z.2
Cody, G.D.3
Cooper, B.A.4
Hazen, R.M.5
Yoder, H.S.6
-
55
-
-
0038649226
-
-
Dörr, M.; Käbbohrer, J.; Grunert, R.; Kreisel, G.; Brand, W. A.; Werner, R. A.; Geilmann, H.; Apfel, C.; Robl, C.; Weigand, W. Angew. Chem., Int. Ed. 2003, 42, 1540-1543.
-
(2003)
Angew. Chem., Int. Ed.
, vol.42
, pp. 1540-1543
-
-
Dörr, M.1
Käbbohrer, J.2
Grunert, R.3
Kreisel, G.4
Brand, W.A.5
Werner, R.A.6
Geilmann, H.7
Apfel, C.8
Robl, C.9
Weigand, W.10
-
57
-
-
0001144357
-
-
(a) Dumesic, J. A.; Topsøe, H.; Boudart, M. J. Catal. 1975, 37, 513-522.
-
(1975)
J. Catal.
, vol.37
, pp. 513-522
-
-
Dumesic, J.A.1
Topsøe, H.2
Boudart, M.3
-
58
-
-
0001608950
-
-
(b) Spencer, N. D.; Schoonmaker, R. C.; Somorjai, G. J. Catal. 1982, 74, 129-135.
-
(1982)
J. Catal.
, vol.74
, pp. 129-135
-
-
Spencer, N.D.1
Schoonmaker, R.C.2
Somorjai, G.3
-
60
-
-
4243259304
-
-
(a) Grunze, M.; Golze, M.; Hirschwald, W.; Freund, H. J.; Pulm, H.; Seip, U.; Tsai, M. C.; Ertl, G.; Kueppers, J. Phys. Rev. Lett. 1984, 53, 850-853.
-
(1984)
Phys. Rev. Lett.
, vol.53
, pp. 850-853
-
-
Grunze, M.1
Golze, M.2
Hirschwald, W.3
Freund, H.J.4
Pulm, H.5
Seip, U.6
Tsai, M.C.7
Ertl, G.8
Kueppers, J.9
-
61
-
-
0009662961
-
-
(b) Freund, H. J.; Bartos, B.; Messmer, R. P.; Grunze, M.; Kuhlenbeck, H.; Neumann, M. Surf. Sci. 1987, 185, 187-202.
-
(1987)
Surf. Sci.
, vol.185
, pp. 187-202
-
-
Freund, H.J.1
Bartos, B.2
Messmer, R.P.3
Grunze, M.4
Kuhlenbeck, H.5
Neumann, M.6
-
62
-
-
31544436826
-
-
(a) Borodko, Y. G.; Broitman, M. O.; Kachapina, L. M.; Shilov, A. E.; Ukhin, L. Y. J. Chem. Soc. D, Chem. Commun. 1971, 1185-1186.
-
(1971)
J. Chem. Soc. D, Chem. Commun.
, pp. 1185-1186
-
-
Borodko, Y.G.1
Broitman, M.O.2
Kachapina, L.M.3
Shilov, A.E.4
Ukhin, L.Y.5
-
63
-
-
0040563491
-
-
(b) Bazhenova, T. A.; Ivleva, I. N.; Kachapina, L. M.; Shilova, A. K.; Shilov, A. E.; Tchoubar, B. J. Organomet. Chem. 1985, 296, 95-101.
-
(1985)
J. Organomet. Chem.
, vol.296
, pp. 95-101
-
-
Bazhenova, T.A.1
Ivleva, I.N.2
Kachapina, L.M.3
Shilova, A.K.4
Shilov, A.E.5
Tchoubar, B.6
-
64
-
-
0041157623
-
-
(c) Bazhenova, T. A.; Kachapina, L. M.; Shilov, A. E.; Antipin, M. Y.; Struchkov, Y. T. J. Organomet. Chem. 1992, 428, 107-123.
-
(1992)
J. Organomet. Chem.
, vol.428
, pp. 107-123
-
-
Bazhenova, T.A.1
Kachapina, L.M.2
Shilov, A.E.3
Antipin, M.Y.4
Struchkov, Y.T.5
-
65
-
-
0012397046
-
-
Yamamoto, A.; Miura, Y.; Ito, T.; Chen, H.-L.; Iri, K.; Ozawa, F.; Miki, K.; Sei, T.; Tanaka, N.; Kasai, N. Organometallics 1983, 2, 1429-1436.
-
(1983)
Organometallics
, vol.2
, pp. 1429-1436
-
-
Yamamoto, A.1
Miura, Y.2
Ito, T.3
Chen, H.-L.4
Iri, K.5
Ozawa, F.6
Miki, K.7
Sei, T.8
Tanaka, N.9
Kasai, N.10
-
66
-
-
0342370221
-
-
(a) Hughes, D. L.; Leigh, G. J.; Jimenez-Tenorio, M.; Rowley, A. T. J. Chem. Soc., Dalton Trans. 1993, 75-82.
-
(1993)
J. Chem. Soc., Dalton Trans.
, pp. 75-82
-
-
Hughes, D.L.1
Leigh, G.J.2
Jimenez-Tenorio, M.3
Rowley, A.T.4
-
69
-
-
25344444043
-
-
(a) George, T. A.; Rose, D. J.; Chang, Y.; Chen, Q.; Zubieta, J. Inorg. Chem. 1995, 34, 1295-1298.
-
(1995)
Inorg. Chem.
, vol.34
, pp. 1295-1298
-
-
George, T.A.1
Rose, D.J.2
Chang, Y.3
Chen, Q.4
Zubieta, J.5
-
70
-
-
22944442305
-
-
(b) Gilbertson, J. D.; Szymczak, N. K.; Tyler, D. R. J. Am. Chem. Soc. 2005, 127, 10184-10185.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 10184-10185
-
-
Gilbertson, J.D.1
Szymczak, N.K.2
Tyler, D.R.3
-
72
-
-
0035913726
-
-
Smith, J. M.; Lachicotte, R. J.; Pittard, K. A.; Cundari, T. R.; Lukat-Rodgers, G.; Rodgers, K. R.; Holland, P. L. J. Am. Chem. Soc. 2001, 123, 9222-9223.
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 9222-9223
-
-
Smith, J.M.1
Lachicotte, R.J.2
Pittard, K.A.3
Cundari, T.R.4
Lukat-Rodgers, G.5
Rodgers, K.R.6
Holland, P.L.7
-
73
-
-
1842731813
-
-
Vela, J.; Stoian, S.; Flaschenriem, C. J.; Münck, E.; Holland, P. L. J. Am. Chem. Soc. 2004, 126, 4522-4523.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 4522-4523
-
-
Vela, J.1
Stoian, S.2
Flaschenriem, C.J.3
Münck, E.4
Holland, P.L.5
-
74
-
-
5244268272
-
-
and references therein as implemented within the Spartan package Spartan, Wavefunction, Inc., 18401 Von Karman Ave., Ste. 370, Irvine, CA 92612
-
MM calculations were carried out with the MMFF94 force field (Halgren, T. A. J. Comput. Chem. 1996, 17, 616-641 and references therein) as implemented within the Spartan package (Spartan, Wavefunction, Inc., 18401 Von Karman Ave., Ste. 370, Irvine, CA 92612; http://www. wavefun.com).
-
(1996)
J. Comput. Chem.
, vol.17
, pp. 616-641
-
-
Halgren, T.A.1
-
75
-
-
0037021483
-
-
(a) Holland, P. L.; Cundari, T. R.; Perez, L. L.; Eckert, N. A.; Lachicotte, R. J. J. Am. Chem. Soc. 2002, 124, 14416-14424.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 14416-14424
-
-
Holland, P.L.1
Cundari, T.R.2
Perez, L.L.3
Eckert, N.A.4
Lachicotte, R.J.5
-
76
-
-
8344267913
-
-
(b) Vela, J.; Vaddadi, S.; Cundari, T. R.; Smith, J. M.; Gregory, E. A.; Lachicotte, R. J.; Flaschenriem, C. J.; Holland, P. L. Organometallics 2004, 23, 5226-5239.
-
(2004)
Organometallics
, vol.23
, pp. 5226-5239
-
-
Vela, J.1
Vaddadi, S.2
Cundari, T.R.3
Smith, J.M.4
Gregory, E.A.5
Lachicotte, R.J.6
Flaschenriem, C.J.7
Holland, P.L.8
-
77
-
-
0037426930
-
-
For recent applications of this methodology to transition metal chemistry see: (a) Aikens, C. M.; Gordon, M. S. J. Phys. Chem. A 2003, 107, 104-114.
-
(2003)
J. Phys. Chem. A
, vol.107
, pp. 104-114
-
-
Aikens, C.M.1
Gordon, M.S.2
-
79
-
-
31544480022
-
-
manuscript in preparation
-
Stoian, S.; Smith, J. M.; Holland, P. L.; Bominaar, E. L.; Münck, E., manuscript in preparation.
-
-
-
Stoian, S.1
Smith, J.M.2
Holland, P.L.3
Bominaar, E.L.4
Münck, E.5
-
80
-
-
31544459169
-
-
note
-
2) is 3.934 versus the ideal value of 3.750.
-
-
-
-
81
-
-
31544446813
-
-
note
-
We define τ as a normalized measure of trigonal distortion of a tetrahedral structure, with τ = 0 representing tetrahedral geometry and τ = 1 representing a trigonal pyramid in which the metal lies in the plane formed by the three basal ligands. For details, see ref 26.
-
-
-
-
82
-
-
19744376115
-
-
Vela, J.; Smith, J. M.; Yu, Y.; Ketterer, N. A.; Flaschenriem, C. J.; Lachicotte, R. J.; Holland, P. L. J. Am. Chem. Soc. 2005, 127, 7857-7870.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 7857-7870
-
-
Vela, J.1
Smith, J.M.2
Yu, Y.3
Ketterer, N.A.4
Flaschenriem, C.J.5
Lachicotte, R.J.6
Holland, P.L.7
-
84
-
-
0037437343
-
-
Brown, S. D.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 322-323.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 322-323
-
-
Brown, S.D.1
Betley, T.A.2
Peters, J.C.3
-
85
-
-
22544462525
-
-
tBuFe-(HCCPh) using Mössbauer and EPR spectroscopy: Stoian, S. A.; Yu, Y.; Smith, J. M.; Holland, P. L.; Bominaar, E. L.; Münck, E. Inorg. Chem. 2005, 44, 4915-4922.
-
(2005)
Inorg. Chem.
, vol.44
, pp. 4915-4922
-
-
Stoian, S.A.1
Yu, Y.2
Smith, J.M.3
Holland, P.L.4
Bominaar, E.L.5
Münck, E.6
-
86
-
-
0034735152
-
-
Siemeling, U.; Vorfeld, U.; Neumann, B.; Stammler, H.-G. Inorg. Chem. 2000, 39, 5159-5160.
-
(2000)
Inorg. Chem.
, vol.39
, pp. 5159-5160
-
-
Siemeling, U.1
Vorfeld, U.2
Neumann, B.3
Stammler, H.-G.4
-
88
-
-
31544455480
-
-
note
-
A full list of these complexes may be found in the Supporting Information.
-
-
-
-
89
-
-
0032538475
-
-
Tuczek, F.; Lehnert, N. Angew. Chem., Int. Ed. 1998, 37, 2636-2638.
-
(1998)
Angew. Chem., Int. Ed.
, vol.37
, pp. 2636-2638
-
-
Tuczek, F.1
Lehnert, N.2
-
90
-
-
31544433064
-
-
Pearce, R. A. R.; Levin, I. W.; Harris, W. C. J. Chem. Phys. 1973, 59, 1209-1216.
-
(1973)
J. Chem. Phys.
, vol.59
, pp. 1209-1216
-
-
Pearce, R.A.R.1
Levin, I.W.2
Harris, W.C.3
-
91
-
-
84982055801
-
-
(a) Berke, H.; Bankhardt, W.; Huttner, G.; Von Seyerl, J.; Zsolnai, L. Chem. Ber. 1981, 114, 2754-2768.
-
(1981)
Chem. Ber.
, vol.114
, pp. 2754-2768
-
-
Berke, H.1
Bankhardt, W.2
Huttner, G.3
Von Seyerl, J.4
Zsolnai, L.5
-
92
-
-
84989558503
-
-
(b) Kandler, H.; Gauss, C.; Bidell, W.; Rosenberger, S.; Buergi, T.; Eremenko, I. L.; Veghini, D.; Orama, O.; Burger, P.; Berke, H. Chem. Eur. J. 1995, 1, 541-548.
-
(1995)
Chem. Eur. J.
, vol.1
, pp. 541-548
-
-
Kandler, H.1
Gauss, C.2
Bidell, W.3
Rosenberger, S.4
Buergi, T.5
Eremenko, I.L.6
Veghini, D.7
Orama, O.8
Burger, P.9
Berke, H.10
-
93
-
-
0030936513
-
-
(a) O'Donoghue, M. B.; Zanetti, N. C.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 2753-2754.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 2753-2754
-
-
O'Donoghue, M.B.1
Zanetti, N.C.2
Davis, W.M.3
Schrock, R.R.4
-
94
-
-
0000527069
-
-
(b) O'Donoghue, M. B.; Davis, W. M.; Schrock, R. R.; Reiff, W. M. Inorg. Chem. 1999, 38, 243-252.
-
(1999)
Inorg. Chem.
, vol.38
, pp. 243-252
-
-
O'Donoghue, M.B.1
Davis, W.M.2
Schrock, R.R.3
Reiff, W.M.4
-
96
-
-
0037196309
-
-
2PPh), which leads to complexes that do not react with dinitrogen. See: Fryzuk, M. D.; Kozak, C. M.; Mehrkhodavandi, P.; Morello, L.; Patrick, B. O.; Rettig, S. J. J. Am. Chem. Soc. 2002, 124, 516-517.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 516-517
-
-
Fryzuk, M.D.1
Kozak, C.M.2
Mehrkhodavandi, P.3
Morello, L.4
Patrick, B.O.5
Rettig, S.J.6
-
97
-
-
0346994923
-
-
Smith, J. M.; Lachicotte, R. J.; Holland, P. L. J. Am. Chem. Soc. 2003, 125, 15752-15753.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 15752-15753
-
-
Smith, J.M.1
Lachicotte, R.J.2
Holland, P.L.3
-
98
-
-
0031039732
-
-
Fryzuk, M. D.; Love, J. B.; Rettig, S. J.; Young, V. G. Science 1997, 275, 1445-1447.
-
(1997)
Science
, vol.275
, pp. 1445-1447
-
-
Fryzuk, M.D.1
Love, J.B.2
Rettig, S.J.3
Young, V.G.4
-
99
-
-
0000697898
-
-
(a) Ho, J.; Drake, R. J.; Stephan, D. W. J. Am. Chem. Soc. 1993, 115, 3792-3793.
-
(1993)
J. Am. Chem. Soc.
, vol.115
, pp. 3792-3793
-
-
Ho, J.1
Drake, R.J.2
Stephan, D.W.3
-
100
-
-
0000539370
-
-
(b) Bazhenova, T. A.; Kulikov, A. V.; Shestakov, A. F.; Shilov, A. E.; Antipin, M. Y.; Lyssenko, K. A.; Struchkov, Y. T.; Makhaev, V. D. J. Am. Chem. Soc. 1995, 117, 12176-12180.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 12176-12180
-
-
Bazhenova, T.A.1
Kulikov, A.V.2
Shestakov, A.F.3
Shilov, A.E.4
Antipin, M.Y.5
Lyssenko, K.A.6
Struchkov, Y.T.7
Makhaev, V.D.8
-
101
-
-
0000231310
-
-
However, lanthanides are capable of N-N bond weakening. Representative examples: (a) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877-6879.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 6877-6879
-
-
Evans, W.J.1
Ulibarri, T.A.2
Ziller, J.W.3
-
104
-
-
0035804395
-
-
(d) Ganesan, M.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. Engl. 2001, 40, 766-769.
-
(2001)
Angew. Chem., Int. Ed. Engl.
, vol.40
, pp. 766-769
-
-
Ganesan, M.1
Gambarotta, S.2
Yap, G.P.A.3
-
106
-
-
8444245229
-
-
(f) Evans, W. J.; Lee, D. S.; Lie, C.; Ziller, J. W. Angew. Chem., Int. Ed. 2004, 43, 5517-5519.
-
(2004)
Angew. Chem., Int. Ed.
, vol.43
, pp. 5517-5519
-
-
Evans, W.J.1
Lee, D.S.2
Lie, C.3
Ziller, J.W.4
-
107
-
-
31544466743
-
-
There are a few other synthetic complexes known with end-on binding to a late transition metal and side-on binding to an alkali metal: (a) Jonas, K. Angew. Chem. 1973, 85, 1050.
-
(1973)
Angew. Chem.
, vol.85
, pp. 1050
-
-
Jonas, K.1
-
108
-
-
33847798269
-
-
(b) Jonas, K.; Brauer, D. J.; Krüger, C.; Roberts, P. J.; Tsay, Y. H. J. Am. Chem. Soc. 1976, 98, 74.
-
(1976)
J. Am. Chem. Soc.
, vol.98
, pp. 74
-
-
Jonas, K.1
Brauer, D.J.2
Krüger, C.3
Roberts, P.J.4
Tsay, Y.H.5
-
109
-
-
84943689310
-
-
(c) Klein, H. F.; Hammer, R.; Wenninger, J.; Friedrich, P.; Huttner, G. Z. Naturforsch., B. 1978, 33, 1267.
-
(1978)
Z. Naturforsch., B.
, vol.33
, pp. 1267
-
-
Klein, H.F.1
Hammer, R.2
Wenninger, J.3
Friedrich, P.4
Huttner, G.5
-
111
-
-
0034685509
-
-
(e) Caselli, A.; Solan, E.; Scopelliti, R.; Floriani, C.; Re, N.; Rizzoli, C.; Chiesi-Villa, A. J. Am. Chem. Soc. 2000, 122, 3652-3670.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 3652-3670
-
-
Caselli, A.1
Solan, E.2
Scopelliti, R.3
Floriani, C.4
Re, N.5
Rizzoli, C.6
Chiesi-Villa, A.7
-
112
-
-
0035901679
-
-
(f) Bonomo, L.; Stern, C.; Solari, E.; Scopelliti, R.; Floriani, C. Angew. Chem., Int. Ed. Engl. 2001, 40, 1449-1452.
-
(2001)
Angew. Chem., Int. Ed. Engl.
, vol.40
, pp. 1449-1452
-
-
Bonomo, L.1
Stern, C.2
Solari, E.3
Scopelliti, R.4
Floriani, C.5
-
113
-
-
0001569030
-
-
and references therein
-
Whitman, L. J.; Bartosch, C. E.; Ho, W.; Strasser, G.; Grunze, M. Phys. Rev. Lett. 1986, 56, 1984-1987 and references therein.
-
(1986)
Phys. Rev. Lett.
, vol.56
, pp. 1984-1987
-
-
Whitman, L.J.1
Bartosch, C.E.2
Ho, W.3
Strasser, G.4
Grunze, M.5
-
114
-
-
4243259304
-
-
(a) Grunze, M.; Golze, M.; Hirschwald, W.; Freund, H. J.; Pulm, H.; Seip, U.; Tsai, M. C.; Ertl, G.; Kueppers, J. Phys. Rev. Lett. 1984, 53, 850-853.
-
(1984)
Phys. Rev. Lett.
, vol.53
, pp. 850-853
-
-
Grunze, M.1
Golze, M.2
Hirschwald, W.3
Freund, H.J.4
Pulm, H.5
Seip, U.6
Tsai, M.C.7
Ertl, G.8
Kueppers, J.9
-
115
-
-
0009662961
-
-
(b) Freund, H. J.; Bartos, B.; Messmer, R. P.; Grunze, M.; Kuhlenbeck, H.; Neumann, M. Surf. Sci. 1987, 185, 187-202.
-
(1987)
Surf. Sci.
, vol.185
, pp. 187-202
-
-
Freund, H.J.1
Bartos, B.2
Messmer, R.P.3
Grunze, M.4
Kuhlenbeck, H.5
Neumann, M.6
-
117
-
-
0011438965
-
-
Brookhart, M.; Grant, B.; Volpe, A. F., Jr. Organometallics 1992, 11, 3920-3922.
-
(1992)
Organometallics
, vol.11
, pp. 3920-3922
-
-
Brookhart, M.1
Grant, B.2
Volpe Jr., A.F.3
-
118
-
-
0001271415
-
-
(a) Turner, H. W.; Fellmann, J. D.; Rocklage, S. M.; Schrock, R. R.; Churchill, M. R.; Wasserman, H. J. J. Am. Chem. Soc. 1980, 102, 7809-7811.
-
(1980)
J. Am. Chem. Soc.
, vol.102
, pp. 7809-7811
-
-
Turner, H.W.1
Fellmann, J.D.2
Rocklage, S.M.3
Schrock, R.R.4
Churchill, M.R.5
Wasserman, H.J.6
-
119
-
-
0000697474
-
-
(b) Rocklage, S. M.; Turner, H. W.; Fellmann, J. D.; Schrock, R. R. Organometallics 1982, 1, 703-707.
-
(1982)
Organometallics
, vol.1
, pp. 703-707
-
-
Rocklage, S.M.1
Turner, H.W.2
Fellmann, J.D.3
Schrock, R.R.4
-
120
-
-
0000604192
-
-
(c) Schrock, R. R.; Wesolek, M.; Liu, A. H.; Wallace, K. C.; Dewan, J. C. Inorg. Chem. 1988, 27, 2050-2054.
-
(1988)
Inorg. Chem.
, vol.27
, pp. 2050-2054
-
-
Schrock, R.R.1
Wesolek, M.2
Liu, A.H.3
Wallace, K.C.4
Dewan, J.C.5
-
122
-
-
0003988115
-
-
Que, L., Jr., Ed.; University Science Books: Sausalito
-
Ming, L.-J. In Physical Methods in Bioinorganic Chemistry; Que, L., Jr., Ed.; University Science Books: Sausalito, 2000; pp 375-464.
-
(2000)
Physical Methods in Bioinorganic Chemistry
, pp. 375-464
-
-
Ming, L.-J.1
-
123
-
-
4243538387
-
-
Baker, M. V.; Field, L. D.; Hambley, T. W. Inorg. Chem. 1988, 27, 7.
-
(1988)
Inorg. Chem.
, vol.27
, pp. 7
-
-
Baker, M.V.1
Field, L.D.2
Hambley, T.W.3
-
124
-
-
0001201073
-
-
Smith, J. M.; Lachicotte, R. J.; Holland, P. L. Organometallics 2002, 21, 4808.
-
(2002)
Organometallics
, vol.21
, pp. 4808
-
-
Smith, J.M.1
Lachicotte, R.J.2
Holland, P.L.3
-
126
-
-
2442620336
-
-
(b) Eckert, N. A.; Smith, J. M.; Lachicotte, R. J.; Holland, P. L. Inorg. Chem. 2004, 43, 3306-3321.
-
(2004)
Inorg. Chem.
, vol.43
, pp. 3306-3321
-
-
Eckert, N.A.1
Smith, J.M.2
Lachicotte, R.J.3
Holland, P.L.4
-
127
-
-
84893169025
-
-
Schmidt, M. W.; Baldridge, K. K.; Boatz, J. A.; Elbert, S. T.; Gordon, M. S.; Jensen, J. H.; Koseki, S.; Matsunaga, N.; Nguyen, K. A.; Su, S.; Windus, T. L.; Dupuis, M.; Montgomery, J. A. J. Comput. Chem. 1993, 14, 1347-1363.
-
(1993)
J. Comput. Chem.
, vol.14
, pp. 1347-1363
-
-
Schmidt, M.W.1
Baldridge, K.K.2
Boatz, J.A.3
Elbert, S.T.4
Gordon, M.S.5
Jensen, J.H.6
Koseki, S.7
Matsunaga, N.8
Nguyen, K.A.9
Su, S.10
Windus, T.L.11
Dupuis, M.12
Montgomery, J.A.13
-
128
-
-
14544296332
-
-
Schrödinger, 1500 S. W. First Avenue, Suite 1180, Portland, OR 97201
-
Jaguar, version 5.5, Schrödinger, 1500 S. W. First Avenue, Suite 1180, Portland, OR 97201, http://www.schrodinger.com.
-
Jaguar, Version 5.5
-
-
-
129
-
-
0001510524
-
-
Stevens, W. J.; Krauss, M.; Basch, H.; Jasien, P. G. Can. J. Chem. 1992, 70, 612-613.
-
(1992)
Can. J. Chem.
, vol.70
, pp. 612-613
-
-
Stevens, W.J.1
Krauss, M.2
Basch, H.3
Jasien, P.G.4
-
131
-
-
0345491105
-
-
Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789;
-
(1988)
Phys. Rev. B
, vol.37
, pp. 785-789
-
-
Lee, C.1
Yang, W.2
Parr, R.G.3
-
132
-
-
0000216001
-
-
Vosko, S. H.; Wilk, L.; Nusair, M. Can. J. Phys. 1980, 58, 1200-1211.
-
(1980)
Can. J. Phys.
, vol.58
, pp. 1200-1211
-
-
Vosko, S.H.1
Wilk, L.2
Nusair, M.3
|