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Volumn 128, Issue 3, 2006, Pages 756-769

Studies of low-coordinate iron dinitrogen complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METALS; BENZENE; CHEMICAL BONDS; IRON; OXIDATION; PHOSPHORUS COMPOUNDS; X RAY CRYSTALLOGRAPHY;

EID: 31544454723     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja052707x     Document Type: Article
Times cited : (287)

References (132)
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  • 26
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    • Calculations support the idea that X is a nitrogen atom: (a) Dance, I. Chem. Commun. 2003, 324-325.
    • (2003) Chem. Commun. , pp. 324-325
    • Dance, I.1
  • 51
    • 21744441467 scopus 로고    scopus 로고
    • The role of X may be to reversibly coordinate to iron in the native form but release low-coordinate iron in reduced forms of the cofactor: Holland, P. L. Can. J. Chem. 2005, 83, 296-301.
    • (2005) Can. J. Chem. , vol.83 , pp. 296-301
    • Holland, P.L.1
  • 74
    • 5244268272 scopus 로고    scopus 로고
    • and references therein as implemented within the Spartan package Spartan, Wavefunction, Inc., 18401 Von Karman Ave., Ste. 370, Irvine, CA 92612
    • MM calculations were carried out with the MMFF94 force field (Halgren, T. A. J. Comput. Chem. 1996, 17, 616-641 and references therein) as implemented within the Spartan package (Spartan, Wavefunction, Inc., 18401 Von Karman Ave., Ste. 370, Irvine, CA 92612; http://www. wavefun.com).
    • (1996) J. Comput. Chem. , vol.17 , pp. 616-641
    • Halgren, T.A.1
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    • For recent applications of this methodology to transition metal chemistry see: (a) Aikens, C. M.; Gordon, M. S. J. Phys. Chem. A 2003, 107, 104-114.
    • (2003) J. Phys. Chem. A , vol.107 , pp. 104-114
    • Aikens, C.M.1    Gordon, M.S.2
  • 80
    • 31544459169 scopus 로고    scopus 로고
    • note
    • 2) is 3.934 versus the ideal value of 3.750.
  • 81
    • 31544446813 scopus 로고    scopus 로고
    • note
    • We define τ as a normalized measure of trigonal distortion of a tetrahedral structure, with τ = 0 representing tetrahedral geometry and τ = 1 representing a trigonal pyramid in which the metal lies in the plane formed by the three basal ligands. For details, see ref 26.
  • 88
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    • note
    • A full list of these complexes may be found in the Supporting Information.
  • 101
  • 107
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    • There are a few other synthetic complexes known with end-on binding to a late transition metal and side-on binding to an alkali metal: (a) Jonas, K. Angew. Chem. 1973, 85, 1050.
    • (1973) Angew. Chem. , vol.85 , pp. 1050
    • Jonas, K.1
  • 122
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    • Que, L., Jr., Ed.; University Science Books: Sausalito
    • Ming, L.-J. In Physical Methods in Bioinorganic Chemistry; Que, L., Jr., Ed.; University Science Books: Sausalito, 2000; pp 375-464.
    • (2000) Physical Methods in Bioinorganic Chemistry , pp. 375-464
    • Ming, L.-J.1
  • 128
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    • Schrödinger, 1500 S. W. First Avenue, Suite 1180, Portland, OR 97201
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.