Localization of a substrate binding site on the FeMo-cofactor in nitrogenase: Trapping propargyl alcohol with an α-70-substituted MoFe protein

Biochemistry

Volumn 42, Issue 30, 2003, Pages 9102-9109

  Benton, Paul M C ^a   Laryukhin, Mikhail ^b   Mayer, Suzanne M ^c   Hoffman, Brian M ^b   Dean, Dennis R ^c   Seefeldt, Lance C ^a  

^a UTAH STATE UNIVERSITY   (United States)

^b NORTHWESTERN UNIVERSITY   (United States)

^c VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PARAMAGNETIC RESONANCE; PROTEINS; REDUCTION; SUBSTITUTION REACTIONS;

ISOTROPIC HYPERFINE COUPLINGS;

BIOCHEMISTRY;

ALANINE; ALCOHOL DERIVATIVE; ALKYNE; CARBON 13; GLYCINE; MOLYBDENUM IRON PROTEIN; NITROGENASE; PROPARGYL ALCOHOL; UNCLASSIFIED DRUG; VALINE;

ALPHA HELIX; AMINO ACID SUBSTITUTION; ARTICLE; BINDING SITE; CARBON NUCLEAR MAGNETIC RESONANCE; CONCENTRATION RESPONSE; CONTROLLED STUDY; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME SUBSTRATE COMPLEX; ISOTOPE LABELING; MICROWAVE RADIATION; NONHUMAN; PRIORITY JOURNAL; REDUCTION; TEMPERATURE;

ALANINE; ALKYNES; AMINO ACID SUBSTITUTION; AZOTOBACTER VINELANDII; BINDING SITES; CARBON ISOTOPES; ELECTRON SPIN RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLYBDOFERREDOXIN; NITROGENASE; OXIDATION-REDUCTION; PROPANOLS; SPIN TRAPPING; SUBSTRATE SPECIFICITY; VALINE;

SIGANUS;

EID: 0043167784     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi034595x     Document Type: Article

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