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Volumn 44, Issue 14, 2005, Pages 4915-4922

Mössbauer, electron paramagnetic resonance, and crystallographic characterization of a high-spin Fe(I) diketiminate complex with orbital degeneracy

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EID: 22544462525     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050321h     Document Type: Article
Times cited : (80)

References (46)
  • 1
    • 0000574624 scopus 로고
    • Wilkinson, G., Grillard, R. D., McCleverty, J. A., Eds.; Pergamon: New York
    • Hawker, P. N.; Twigg, M. V. In Comprehensive Coordination Chemistry; Wilkinson, G., Grillard, R. D., McCleverty, J. A., Eds.; Pergamon: New York, 1987, Vol. 4, p 1179.
    • (1987) Comprehensive Coordination Chemistry , vol.4 , pp. 1179
    • Hawker, P.N.1    Twigg, M.V.2
  • 22
    • 0003998388 scopus 로고
    • CRC Press: Boca Raton, FL, Average crystallographic value for specific type of bond
    • CRC Handbook of Chemistry and Physics, 74th ed.; Lide, R. D., Ed.; CRC Press: Boca Raton, FL, 1993; Average crystallographic value for specific type of bond, p 9-1.
    • (1993) CRC Handbook of Chemistry and Physics, 74th Ed. , pp. 9-11
    • Lide, R.D.1
  • 35
    • 22544432988 scopus 로고    scopus 로고
    • note
    • On one occasion, the toluene sample (flame-sealed EPR tube) melted for a few seconds during transfer. Upon refreezing, microcrystals formed, which produced a multitude of single-crystal-type resonances down to at least g = 1; these resonances shifted when the sample tube was rotated in the EPR cavity. Thus, the feature at g = 8.6 belongs to a doublet that has g values extending to at least g = 1.
  • 37
    • 22544436235 scopus 로고    scopus 로고
    • note
    • i for the former case, would virtually yield indistinguishable results in magnetization studies. Such studies require levels of sample purity presently not attainable for 1.
  • 41
    • 22544480150 scopus 로고    scopus 로고
    • note
    • II contribution, introducing energy terms depending on Racah parameter C. This issue has not been further analyzed here.
  • 42
    • 22544469843 scopus 로고    scopus 로고
    • note
    • 2 → yz} excitation energy are too large in both complexes but are within the error margin reported for TD-DFT excitation energies.
  • 43
    • 22544451085 scopus 로고    scopus 로고
    • note
    • The degeneracies referred to here are obtained without spin-orbit coupling.
  • 46
    • 0041464227 scopus 로고    scopus 로고
    • (c) The wealth of computational work on metal-acetylene complexes has been reviewed recently: Frenking, G.; Fröhlich, N. Chem. Rev. 2000, 100, 717-774.
    • (2000) Chem. Rev. , vol.100 , pp. 717-774
    • Frenking, G.1    Fröhlich, N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.