Energy transfer pathways in dinuclear heteroleptic polypyridyl complexes: Through-space vs through-bond interaction mechanisms

Inorganic Chemistry

Volumn 43, Issue 14, 2004, Pages 4471-4481

  Weldon, Frances ^a   Hammarström, Leif ^b   Mukhtar, Emad ^b   Hage, Ronald ^c   Gunneweg, Eric ^d   Haasnoot, Jaap G ^d   Reedijk, Jan ^d   Browne, Wesley R ^a,e   Guckian, Adrian L ^a   Vos, Johannes G ^a  

^a DUBLIN CITY UNIVERSITY   (Ireland)

^b UPPSALA UNIVERSITY   (Sweden)

^c UNILEVER RESEARCH VLAARDINGEN   (Netherlands)

^d LEIDEN UNIVERSITY   (Netherlands)

^e UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

1,2,4 TRIAZOLE DERIVATIVE; 1,3 BIS[5 (2 PYRIDYL) 1H 1,2,4 TRIAZOL 3 YL]BENZENE; 1,4 BIS[5 (2 PYRIDYL) 1H 1,2,4 TRIAZOL 3 YL]BENZENE; BENZENE DERIVATIVE; LIGAND; METAL COMPLEX; OSMIUM DERIVATIVE; PYRIDINE DERIVATIVE; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; DIPOLE; ELECTROCHEMISTRY; ENERGY TRANSFER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LUMINESCENCE; MASS SPECTROMETRY; MOLECULAR INTERACTION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 3142661836     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049896p     Document Type: Article

References (96)

1. (a) Worl, L. A.; Strouse, G. F.; Younathan, J. N.; Baxter, S. M.; Meyer, T. J. J. Am. Chem. Soc. 1990, 112, 7571.
2. (b) Balzani, V. Tetrahedron 1992, 48, 10443.
3. (c) Balzani, V.; Campagna, S.; Denti, G.; Juris, A.; Serroni, S.; Venturi, M. Acc. Chem. Res. 1998, 31, 26.
4. (d) Balzani, V.; Scandola, F. Supramolecular Photochemistry; Horwood: Chichester, U.K., 1991.
5. (e) Scandola, F.; Indelli, M. T.; Chiorboli, C.; Bignozzi, C. A. Top. Curr. Chem. 1990, 158, 73.
6. (a) Kalyanasundaram, K. Coord. Chem. Rev. 1982, 46, 159.
7. (b) Lehn, J. M. Angew. Chem., Int. Ed. Engl. 1988, 27, 89.
8. (c) Balzani, V.; Campagna, S.; Denti, G.; Juris, A.; Serroni, S.; Ventura, M. Coord. Chem. Rev. 1994, 132, 1.
9. (d) Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni, S. Chem. Rev. 1996, 96, 759.
10. (e) Slate, C. A.; Striplin, D. R.; Moss, J. A.; Chen, P.; Erickson, B. W.; Meyer, T. J. J. Am. Chem. Soc. 1998, 120, 4885.
11. (f) Hu, Y.-Z.; Tsukiji, S.; Shinkai, S.; Oishi, S.; Hamachi, I. J. Am. Chem. Soc. 2000, 122, 241.
12. (g) Sauvage, J.-P.; Collin, J.-P.; Chambron, J.-C.; Guillerez, S.; Coudret, C.; Balzani, V.; Bargelletti, F.; De Cola, L.; Flamigni, L. Chem. Rev. 1994, 94, 993.
13. (h) Carraway, E. R.; Demas, J. N.; DeGraff, B. A. Anal. Chem. 1991, 63, 332.
14. (a) Balzani, V. Ed. Supramolecular Photochemistry; Reidel: Dordrecht, 1997.
15. (b) Lehn, J.-M. Supramolecular Chemistry; Wiley-VCH: Weinheim, 1995.
16. (a) Beer, P. D.; Szemes, F.; Balzani, V.; Salà, C. M.; Drew, M. G. B.; Dent, S. W.; Maestri, M. J. Am. Chem. Soc. 1997, 119, 11864.
17. (b) Barigelletti, F.; Flamigni, L.; Collin, J.-P.; Sauvage, J.-P. Chem. Commun. 1997, 333.
18. (c) Waldmann, O.; Hassmann, J.; Müller, P.; Hanan, G. S.; Volkmer, D.; Schubert, U. S.; Lehn, J.-M. Phys. Rev. Lett, 1997, 78, 3390.
19. (d) Zahavy, E.; Fox, M. A. Chem. Eur. J. 1998, 4, 1647.
20. (e) Balzani, V.; Credi, A.; Venturi, M. Curr. Opin. Chem. Biol. 1997, 1, 506.
21. Welter, S.; Brunner, K.; Hofstraat, J. W.; De Cola, L. Nature 2003, 421, 54.
22. (a) Barigelletti, F.; Flamigni, L.; Balzani, V.; Collin, J.-P.; Sauvage, J.-P.; Sour, A.; Constable, E. C.; Cargill Thompson, A. M. W. J. Chem. Soc., Chem. Commun. 1993, 942.
23. (b) Kim, Y.; Lieber, C. M. Inorg. Chem. 1989, 28, 3990.
24. (a) Haga, M.; Ano, T.; Kano, K.; Yamabe, S. Inorg. Chem. 1991, 30, 3843.
25. (b) Haga, M. A.; Ishizuya, M.; Kanesugi, T.; Yubaka, T.; Sakiyama, D.; Fees, J.; Kaim, W. Indian J. Chem. A 2003, 42, 2290.
26. (c) Haga, M.; Takasugi, T.; Tomie, A.; Ishizuga, M.; Yamada, T.; Hossain, M. D.; Inoue, M. Dalton 2003, 2069.
27. (d) Hossain, M. D.; Haga, M.; Gholamkhass, B.; Nozaki, K.; Tsushima, M.; Ikeda, N.; Ohno, T. Collect. Czech. Chem. Commun. 2001, 66, 307.
28. (e) Hossain, M. D.; Ueno, R.; Haga, M. Inorg. Chem. Commun. 2000, 3, 35.
29. (f) Ali, M.; Sato, H.; Haga, M. A.; Tanaka, K.; Yoshimura, A.; Ohno, T. Inorg. Chem. 1998, 37, 6176.
30. (g) Haga, M.; Ali, M. M.; Sato, H.; Monojushiro, H.; Nozaki, K.; Kano, K. Inorg. Chem. 1998, 37, 2320.
31. (h) Mizushima, K.; Nakaura, M.; Park, S. B.; Nishiyama, H.; Monjushiro, H.; Haraja, K.; Haga, M. Inorg. Chim. Acta 1997, 261, 175.
32. (i) Haga, M. A.; Ali, M. M.; Koseki, S.; Fujimoto, K.; Yoshimura, A.; Nozaki, K.; Ohno, T.; Nakajima, K. Inorg. Chem. 1996, 35, 3335.
33. (j) Haga, M. A.; Ali, M.; Arakawa, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 76.
34. (a) Su, H. Q.; Kincaid, J. R. J. Raman Spectrosc. 2003, 34, 907.
35. (b) Marcaccio, M.; Paolucci, F.; Paradisi, C.; Roffia, S.; Fontanesi, C.; Yellowlees, L. J.; Serroni, S.; Campagna, S.; Denti, G.; Balzani, V. J. Am. Chem. Soc. 1999, 121, 10081.
36. (c) Loiseau, F.; Serroni, S.; Campagna, S. Collect. Czech. Chem. Commun. 2003, 68, 1677.
37. (d) Marcaccio, M.; Paolucci, F.; Paradisi, C.; Carano, M.; Roffia, S.; Fontanesi, C.; Yellowlees, L. J.; Serroni, S.; Campagna, C.; Balzani, V. J. Electroanal. Chem. 2002, 532, 99.
38. (e) Campagna, S.; Serroni, S.; Puntoriero, F.; Loiseau, F.; De Cola, L.; Kleverlaan, C. J.; Becher, J.; Sorenson, A. P.; Hascoat, P.; Thorup, N. Chem. Eur. J. 2002, 8, 4461.
39. (f) Swavey, S.; Brewer, K. J. Inorg. Chem. 2002, 41, 4044.
40. (g) Baudin, H. B.; Davidsson, J.; Serroni, S.; Juris, A.; Balzani, V.; Campagna, S.; Hammarstrom, L. J. Phys. Chem. A 2002, 106, 4312.
41. (h) Seneviratne, D. S.; Uddin, J.; Swayambunathan, V.; Schegel, H. B.; Endicott, T. F. Inorg. Chem. 2002, 41, 1502.
42. (i) Constable, E. C.; Eriksson, H.; Housecroft, C. E.; Kariuki, B. M.; Nordlander, E.; Olsson, J. Inorg. Chem. Commun. 2001, 4, 749.
43. (j) Carano, M.; Ceroni, P.; Fontanesi, C.; Marcaccio, M.; Paolucci, F.; Paradisi, C.; Roffia, S. Electrochim. Acta 2001, 46, 3199.
44. (k) Puntoriero, F.; Serroni, S.; Licciardello, A.; Venturi, M.; Juris, A.; Ricevutto, V.; Campagna, S. Dalton 2001, 1035.
45. (a) Fraysse, S.; Coudret, C.; Launay, J. P. J. Am. Chem. Soc. 2003, 125, 5880.
46. (b) Hortholary, C.; Coudret, C. J. Org. Chem. 2003, 68, 2167.
47. (c) Hortholary, C.; Minc, F.; Coudret, C.; Bonvoisin, J.; Launay, J.-P. Chem. Commun. 2002, 1932.
48. (d) Launay, J. P. Chem. Soc. Rev. 2001, 30, 386.
49. (e) Launay, J. P.; Fraysse, S.; Coudret, C. Mol. Cryst. Liq. Cryst. 2000, 344, 125.
50. (f) Fraysse, S.; Coudret, C.; Launay, J. P. Eur. J. Inorg. Chem. 2000, 1581.
51. (g) Patoux, C.; Launay, J. P.; Beley, M.; Chodorowski-Kimmes, S.; Collin, J.-P.; James, S.; Sauvage, J.-P. J. Am. Chem. Soc. 1998, 120, 3717.
52. (a) Hage, R.; Prins, R.; Haasnoot, J. G.; Reedijk, J.; Vos, J. G. J. Chem. Soc., Dalton Trans. 1987, 1389.
53. (b) Nieuwenhuis, H. A.; Haasnoot, J. G.; Hage, R.; Reedijk, J.; Snoeck, T. L.; Stufkens, D. J.; Vos, J. G. Inorg. Chem. 1991, 30, 48.
54. (c) Buchanan, B. E.; Wang, R.; Vos, J. G.; Hage, R.; Haasnoot, J. G.; Reedijk, J. Inorg. Chem. 1990, 29, 3263.
55. (d) Browne, W. R.; O'Connor, C. M.; Villani, C.; Vos, J. G. Inorg. Chem. 2001, 40, 5461.
56. (e) Hage, R.; Haasnoot, J. G.; Nieuwenhuis, H. A.; Reedijk, J.; de Ridder, D. J. A.; Vos, J. G. J. Am. Chem. Soc. 1990, 112, 9245.
57. (f) de Wolf, J. M.; Hage, R.; Haasnoot, J. G.; Reedijk, J.; Vos, J. G. New J. Chem. 1991, 15, 501.
58. (g) Hage, R.; Dijkhuis, A. H. J.; Haasnoot, J. G.; Prins, R.; Reedijk, J.; Buchanan, B. E.; Vos, J. G. Inorg. Chem. 1988, 27, 2185.
59. (h) Mehmetaj, B.; Haasnoot, J. G.; De Cola, L.; van Albada, G. A.; Mutikainen, I.; Turpeinen, U.; Reedijk, J. Eur. J. Inor. Chem 2002, 1765.
60. (a) Barigelletti, F.; De Cola, L.; Balzani, V.; Hage, R.; Haasnoot, J. G.; Reedijk, J.; Vos, J. G. Inorg. Chem. 1989, 28, 4344.
61. (b) van Diemen, J. H.; Hage, R.; Haasnoot, J. G.; Lempers, H. E. B.; Reedijk, J.; Vos, J. G.; de Cola, L.; Barigelletti, F.; Balzani, V. Inorg. Chem. 1992, 31, 3518.
62. (c) Barigelletti, F.; De Cola, L.; Balzani, V.; Hage, R.; Haasnoot, J. G.; Reedijk, J.; Vos, J. G. Inorg. Chem. 1991, 30, 641.
63. Browne, W. R.; Weldon, F.; Guckian, A.; Vos, J. G. Collect. Czech. Chem. Commun. 2003, 68, 1467.
64. Passaniti, P.; Browne, W. R.; Lynch, F. C.; Hughes, D.; Nieuwenhuyzen, M.; James, P.; Maestri, M.; Vos, J. G. Dalton 2002, 1740.
65. Sullivan, B. P.; Salmon, D. J.; Meyer, T. J. Inorg. Chem. 1978, 17, 3334.
66. Buckingham, D. A.; Dwyer, F. P.; Goodwin, H. A.; Sargeson, A. M. Aust. J. Chem. 1964, 17, 325.
67. Fanni, S.; Weldon, F. M.; Hammarström, L.; Mukhtar, E.; Browne, W. R.; Keyes, T. E.; Vos, J. G. Eur. J. Inorg. Chem. 2001, 529.
68. Förster, Th. Discuss. Faraday Soc. 1959, 27, 7.
69. Chang, J. P.; Fung, E. Y.; Curtis, J. C. Inorg. Chem. 1986, 25, 4233.
70. Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877.
71. Serroni, S.; Campagna, S.; Puntoriero, F.; Di. Pietro, C.; McGlenaghan, N. D.; Loiseau, F. Chem. Soc. Rev. 2001, 30, 367.
72. Hage, R. Ph.D. Thesis, Leiden University, 1991.
73. Browne, W. R.; Hesek, D.; Gallagher, J. F.; O'Connor, C. M.; Killeen, J. S.; Aoki, F.; Ishid, H.; Inoue, Y.; Villani, C.; Vos, J. G. Dalton 2003, 2597.
74. Belser, P.; von Zelewsky, A. Helv. Chim. Acta 1980, 63, 1675.
75. Constable, E. C.; Lewis, J. Inorg. Chim. Acta 1983, 70, 251.
76. Ryan, E. M.; Wang, R.; Vos, J. G.; Hage, R.; Haasnoot, J. G. Inorg. Chim. Acta 1993, 208, 49.
77. Buchanan, B. E.; Vos, J. G.; Kaneko, M.; van der Putten, W. J. M.; Kelly, J. M.; Hage, R.; de Graaff, R. A. G.; Prins, R.; Haasnoot, J. G.; Reedijk, J. J. Chem. Soc., Dalton Trans. 1990, 2425.
78. Hage, R.; Haasnoot, J. G.; Reedijk, J.; Wang, R.; Ryan, E. M.; Vos, J. G.; Spek, A. L.; Duisenberg, A. J. M. Inorg. Chim. Acta 1996, 174, 77.
79. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
80. Goldsby, K. A.; Meyer, T. J. Inorg. Chem. 1984, 23, 3002
81. Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 2827.
82. III b
83. Duati, M.; Tasca, S.; Lynch, F. C.; Bohlen, H.; Vos, J. G.; Stagni, S.; Ward, M. D. Inorg. Chem. 2003, 42, 8377.
84. Haga, M.; Matsumura-Inoue, T.; Yamabe, S. Inorg. Chem. 1987, 26, 4148.
85. Browne, W. R.; O'Connor, C. M.; Hughes, H. P.; Hage, R.; Walter, O.; Doering, M.; Gallagher, J. F.; Vos, J. G. Dalton 2002, 4048.
86. For the mononuclear complexes it would be expected that a second deprotonation step (due to the unbound 1,2,4-triazole ring) would be observed at higher pH. However, the effect on the absorption spectrum of the complex of deprotonation of such a peripheral group would be expected to be negligible, considering the limited influence that substituents in the C3 position of the 1,2,4-triazole have on the electronic properties of this class of complexes.
87. Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 3722.
88. Wang, R.; Vos, J. G.; Schmehl, R. H.; Hage. R. J. Am Chem. Soc. 1992, 114, 1964.
89. Fanni, S.; Keyes, T. E.; O'Connor, C. M.; Hughes, H.; Wang, R.; Vos, J. G. Coord. Chem. Rev. 2000, 208, 77.
90. In protic media the rate of proton exchange is expected to be much faster than the lifetime of the excited state and hence an averaged lifetime is observed (i.e., single exponential) and hence addition of protic solvents to the acetonitrile solutions would be expected to result in a monoexponential lifetime being observed. The reduction in emission intensity in the presence of protic solvents, however, makes such experiments ambiguous.
91. Barigelletti, F.; Flamigni, L.; Guardigli, M.; Juris, A.; Beley, M.; Chodorowski Kimmes, S.; Collin, J.-P.; Sauvage, J.-P. Inorg. Chem. 1996, 35, 136.
92. Barigelletti, F.; Flamigni, L.; Collin, J.-P.; Sauvage, J.-P. Chem. Commun. 1997, 333.
93. For the deprotonated complexes, this emission lies in a region where the detector of the time-resolved single photon counting setup has a very low sensitivity. The Ru-based emission is also comparatively strong-in terms of number of photons per time unit-even in the farred part of the spectrum. Thus, it is not surprising that an Os-based emission, with a lifetime very similar to that of the Ru emission, cannot be resolved in pRuOs and mRuOs.
94. Barigelletti, F.; Flamigni, L.; Balzani, V.; Collin, J.-P.; Sauvage, J.-P.; Sour, A.; Constable, E. C.; Cargill Thompson, A. M. W. J. Am. Chem. Soc. 1994, 116, 7692.
95. EnT would then correspond to a <120 meV increase in driving force for the hopping. Clearly, the effect of protonation of the triazole on the energy difference between the MLCT states on the peripheral and the bridging ligands is much larger than both these estimates.
96. Liu, T.-Y.; Chen, Y. J.; Tai, C.-C.; Kwan, K. S. Inorg. Chem. 1999, 38, 674