Energy Transfer in Rigid Ru(II)/Os(II) Dinuclear Complexes with Biscyclometalating Bridging Ligands Containing a Variable Number of Phenylene Units

Inorganic Chemistry

Volumn 35, Issue 1, 1996, Pages 136-142

  Barigelletti, Francesco ^a   Flamigni, Lucia ^a   Guardigli, Massimo ^a   Juris, Alberto ^b   Beley, Marc ^c   Chodorowski Kimmes, Sandrine ^c   Collin, Jean Paul ^c   Sauvage, Jean Pierre ^c  

^a Istituto di Fotochimica e Radiazioni d'Alta Energia   (Italy)

^b UNIVERSITY OF BOLOGNA   (Italy)

^c UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002909554     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9503085     Document Type: Article

References (91)

1. (a) Gust, D., Moore, T. A., Eds. Tetrahedron 1989, 45 (special issue).
2. (b) Fox, M. A., Chanon, M., Eds. Photoinduced Electron Transfer; Elsevier: New York, 1988; Parts A-D.
3. (c) Mattay, J., Ed. Top. Curr. Chem. 1990, 156; 1990, 158; 1991, 159.
4. (c) Mattay, J., Ed. Top. Curr. Chem. 1990, 156; 1990, 158; 1991, 159.
5. (c) Mattay, J., Ed. Top. Curr. Chem. 1990, 156; 1990, 158; 1991, 159.
6. (d) Balzani, V.; De Cola, L., Eds. Supramolecular Chemistry; Kluwer: Dordrecht, The Netherlands, 1992.
7. (a) Gust, D.; Moore, T. Science 1989, 244, 35.
8. (b) Feher, G.; Allen, J. P.; Okamura, M. Y.; Rees, D. C. Nature 1989, 339, 111.
9. (c) Moser, C. C.; Keske, J. M.; Warncke, K.; Farid, R. S.; Dutton, P. L. Nature 1992, 355, 796.
10. (d) Gust, D.; Moore, T. A.; Moore, A. L. Acc. Chem. Res. 1993, 26, 198.
11. Balzani, V., Scandola, F. Supramolecular Photochemistry; Horwood: Chichester, U.K., 1991.
12. (a) Meyer, T. J. Pure Appl. Chem. 1986, 58, 1193.
13. (b) Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
14. (c) Meyer, T. J. Acc. Chem. Res. 1989, 22, 163.
15. (d) Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: London. 1991.
16. (e) Kalyanasundaram, K., Grätzel, M., Eds. Photosensitization and Phatocatalysis Using Inorganic and Organometallic Compounds; Kluwer: Dordrecht, The Netherlands, 1993.
17. (f) Sauvage, J.-P.; Collin, J.-P.; Chambron, J.-C.; Guillerez, S.; Coudret C.; Balzani, V.; Barigelletti, F.; De Cola, L.; Flamigni, L. Chem. Rev. 1994, 94, 993.
18. A review covering photoinduced processes in polynuclear complexes: Scandola, F.; Indelli, M. T.; Chiorboli, C.; Bignozzi, C. A. Top. Curr. Chem. 1990, 158, 63. For a selection of recent papers dealing with polynuclear complexes, see ref 7.
19. (a) Ohno, T.; Nozaki, K.; Haga, M. Inorg. Chem. 1992, 31, 548.
20. (b) Ohno, T.; Nozaki, K.; Haga, M. Inorg. Chem. 1992, 31, 4256.
21. (c) Bommarito, S. L.; Lowery-Bretz, S. P.; Abruña, H. D. Inorg. Chem. 1992, 31, 502.
22. (d) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1992, 31, 1594.
23. (e) Howard, C. A.; Ward, M. D. Angew. Chem., Int. Ed. Engl. 1992, 31, 1028.
24. (f) Hage, R.; Haasnoot, J. G.; Reedijk, J.; Vos, J. G. Chemtracts: Inorg. Chem. 1992, 4, 75.
25. (g) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 2827.
26. (h) Jones, E. W., Jr.; Baxter, S. M.; Strouse, G. F.; Meyer, T. J. J. Am. Chem. Soc. 1993, 115, 7363.
27. (i) Hughes, H. P.; Martin, D.; Bell, S.; McGarvey, J. J., Vos, J. G. Inorg. Chem. 1993, 32, 4402.
28. (j) Roffia, S.; Marcaccio, M.; Paradisi, C.; Paolucci, F.; Balzani, V.; Denti, G.; Serroni, S.; Campagna, S. Inorg. Chem. 1993, 32, 3003.
29. (k) Thummel, R. P.; Williamson, D.; Hery, C. Inorg. Chem. 1993, 32, 1587.
30. (1) Arana, C. A.; Abruna, H. D. Inorg. Chem. 1993, 32, 194.
31. Giuffrida, G.; Calogero, G.; Guglielmo, G.; Ricevuto, V.; Ciano, M.; Campagna, S. Inorg. Chem. 1993, 32, 1179.
32. (n) Jones, W. E., Jr.; Bignozzi, C. A.; Chen, P.; Meyer, T. J. Inorg. Chem. 1993, 32, 1167.
33. (o) Indelli, M. T.; Bignozzi, C. A.; Harriman, A.; Schoonover, J. R.; Scandola, F. J. Am. Chem. Soc. 1994, 116, 3768.
34. (p) Sutter, J.-P.; Grove, D. M.; Beley, M.; Collin, J.-P.; Veldman, N.; Spek, A. L.; Sauvage, J.-P.; van Koten, G. Angew. Chem., Int. Ed. Engl. 1994, 33, 1282.
35. (q) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S ; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491.
36. (a) Furue, M.; Yoshidzumi, T.; Kinoshita, S.; Kushida, T.; Nozakura, S.; Kamachi, M Bull. Chem. Soc. Jpn. 1991, 64, 1632.
37. (b) Yonemoto, E. H.; Riley, R. L.; Il Kim, Y.; Atherton, S. J.; Schmehl, R. H.; Mallouk, T. E. J. Am. Chem. Soc. 1992, 114, 8081.
38. (c) Song, X.; Lei, Y.; Van Wallendal, S.; Perkovic, M. W.; Jackman, D. C.; Endicott, J. F.; Rillema, D. P. J. Phys, Chem. 1993, 97, 3225.
39. (d) Van Wallendael, S.; Perkovic, M. W.; Rillema, D. P. Inorg. Chim. Acta 1993, 213. 253.
40. (e) Yonemoto, E. H.; Saupe, G. B.; Schmehl, R. H.; Hubig, S M.; Riley, R. L.; Iverson, B. L.; Mallouk, T. E. J. Am. Chem. Soc. 1994, 116, 4786.
41. (a) Bignozzi, C. A.; Argazzi, R.; Schoonover, J. R.; Gordon, K. C.; Dyer, R. B.; Scandola, F. Inorg. Chem. 1992, 31, 5260.
42. (b) Bignozzi, C. A.; Argazzi, R.; Garcia, C. G ; Scandola, F. J. Am. Chem. Soc. 1992, 114, 8727.
43. (c) Indelli, M. T.; Scandola, F. J. Phys. Chem. 1993, 97, 3328.
44. (d) Bignozzi, C. A.; Argazzi, R.; Chiorboli, C.; Scandola, F.; Dyer, R. B.; Schoonover, J. R.; Meyer, T. J. Inorg. Chem. 1994, 33, 1652.
45. Boyde, S.; Strouse, G. F.; Jones, W. E., Jr.; Meyer, T. J. J. Am. Chem. Soc. 1990, 112, 7395.
46. Shaw, J. R.; Webb, R. T.; Schmehl, R. H. J. Am. Chem. Soc. 1990, 112, 1117.
47. De Cola, L.; Balzani, V.; Barigelletti, F.; Flamigni, L.; Belser, P.; von Zelewsky, A.; Frank, M.; Vögtle, F. Inorg. Chem. 1993, 32, 5228.
48. Vögtle, F.; Frank, M.; Nieger, M.; Belser, P.; von Zelewsky, A.; Balzani, V.; Barigelletti, F.; De Cola, L.; Flamigni, L. Angew. Chem., Int. Ed. Engl. 1993, 32, 1643.
49. Benniston, A. C.; Grosshenny, V.; Harriman, A.; Ziessel, R. Angew. Chem., Int Ed. Engl. 1994, 33, 1884.
50. Benniston, A. C.; Goulle, V.; Harriman, A.; Lehn, J.-M.; Marczinke, B. J. Phys. Chem. 1994, 98, 7798.
51. (a) Barigelletti, F.; Flamigni, L.; Balzani, V.; Collin, J.-P.; Sauvage, J.-P.; Sour, A.; Constable, E. C.; Cargill Thompson, A. M. W. J. Chem. Soc., Chem. Commun. 1993, 942.
52. (b) Bangelleni, F.; Flamigni, L.; Balzani, V.; Collin, J.-P.; Sauvage, J.-P.; Sour, A.; Constable, E. C.; Cargill Thompson, A. M. W. J. Am. Chem. Soc. 1994, 116, 7692.
53. Barigelletti, F.; Flamigni, L.; Balzani, V.; Collin, J.-P.; Sauvage, J.-P.; Sour, A. Submitted for publication.
54. (a) Jordan, K. D.; Paddon-Row, M. N. Chem. Rev. 1992, 92, 395.
55. (b) Warman, J. M.; Smit, K. J.; Jonker, S. A.; Verhoeven, J. W.; Oevering, H.; Kroon, J.; Paddon-Row, M. N.; Oliver, A. Chem. Phys. 1993, 170, 359.
56. (c) Kroon, J.; Oevering, J. W.; Verhoeven, J. W.; Warman, J. M.; Oliver, A. M.; Paddon-Row, M. N. J. Phys. Chem. 1993, 97, 5065.
57. (d) Paddon-Row, M. N.; Shephard, M. J.; Jordan, K. D. J. Phys. Chem. 1993, 97, 1743.
58. (e) Paddon-Row, M. N. Acc. Chem. Res. 1994, 27, 18.
59. The geometrical advantages of employing tridentate tpy-type ligands are discussed in ref 5f.
60. (a) Watts, R. J. Comments Inorg. Chem. 1991, 11, 303.
61. (b) Maestri, M.; Balzani, V.; Deuschel-Cornioley, Ch.; von Zelewsky, A. Adv. Photochem. 1992, 17, 1.
62. Beley, M.; Chodorowsky, S.; Collin. J.-P.; Sauvage, J.-P.; Flamigni, L.; Barigelletti, F. Inorg. Chem. 1994, 33, 2543.
63. -1 for n = 0-2, respectively; see ref 23.
64. Collin, J.-P.; Lainé, P.; Launay, J.-P.; Sauvage, J.-P.; Sour, A. J. Chem. Soc., Chem Commun. 1993, 434.
65. Beley, M.; Chodorowski, S.; Collin, J.-P.; Sauvage, J.-P. Tetrahedron Lett. 1993, 34, 2933.
66. Collin, J.-P.; Guillerez, S.; Sauvage, J.-P.; Barigelletti, F.; De Cola, L.; Flamigni, L.; Balzani, V. Inorg. Chem. 1991, 30, 4230.
67. Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 3722.
68. (a) Beley, M.; Collin, J.-P.; Rémy, L.; Metz, B.; Sauvage, J.-P. J. Am. Chem. Soc. 1991, 113, 8521.
69. (b) Beley, M.; Collin, J.-P.; Sauvage, J.-P. Inorg. Chem. 1993, 32, 4539.
70. Beley, M.; Chodorowski-Kimmes, S.; Collin, J.-P.; Lainé, P.; Launay, J.-P.; Sauvage, J.-P. Angew. Chem., Int. Ed. Engl. 1994, 33, 1775.
71. Results obtained with QCPE Program No. 517 by considering a coplanar arrangement for BL. Interatomic distances were 1.49 and 1.36 Å for the C-C single bond and the C-C and C-N aromatic bonds, respectively.
72. (a) Games, G. L., III, O'Neil, M. P.; Svec, W. A.; Niemczik, M. P.; Wasielewski, M. R. J. Am. Chem. Soc. 1991, 113, 719.
73. (b) Jones, W. E., Jr.; Chen, P.; Meyer, T. J. J. Am. Chem. Soc. 1992, 114, 387.
74. Dexter, D. L. J. Chem. Phys. 1953, 21, 836.
75. (a) Forster, Th. Discuss. Faraday Soc. 1959, 27, 7.
76. (b) Förster, Th. In Modern Quantum Chemistry: Sinanoglu, O., Ed.; Academic Press: New York, 1965; Part III.
77. Higher order interactions are usually disregarded. For examples of more complete treatments, see: (a) Scholes, G. D.; Ghiggino, K. P. J. Photochem. Photobiol. A: Chem. 1994, 80, 355. (b) Scholes, G. D., Ghiggino, K. P.; Oliver, A. M.; Paddon-Row, M. N. J. Phys. Chem. 1993, 97, 11871.
78. Higher order interactions are usually disregarded. For examples of more complete treatments, see: (a) Scholes, G. D.; Ghiggino, K. P. J. Photochem. Photobiol. A: Chem. 1994, 80, 355. (b) Scholes, G. D., Ghiggino, K. P.; Oliver, A. M.; Paddon-Row, M. N. J. Phys. Chem. 1993, 97, 11871.
79. (a) Balzani, V.; Bolletta, F.; Scandola. F. J. Am. Chem. Soc. 1980, 102, 2552.
80. (b) Scandola, F.; Balzani, V. J. Chem. Educ. 1983, 60, 814.
81. P. Closs, G. L.; Miller, J. R. Science 1989, 244, 35
82. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
83. Sutin, N. Acc. Chem. Res. 1982, 15, 215.
84. Oevering, H.; Verhoeven, J. W.; Paddon-Row; Cotsaris, E. Chem. Phys. Lett. 1988, 143, 488.
85. (a) Helms, A.; Heiler, D.; McLendon, G. J. Am. Chem. Soc. 1992, 114, 6227.
86. (b) Helms, A.; Heiler, D.; McLendon, G. J. Am. Chem. Soc. 1991, 113, 4325.
87. The role of phenylene bridges as mediators of intercomponent interactions has been investigated by other groups. See for instance: (a) Kim, Y.; Lieber, C. M. Inorg. Chem. 1989, 28, 3990. (b) Osuka, A.; Nakajima, S.; Maruyama, K.; Mataga, N.; Asahi, T.; Yamazaki, L; Nishimura, Y.; Ohno, T.; Nozaki, K. J. Am. Chem. Soc. 1993, 115, 4577.
88. The role of phenylene bridges as mediators of intercomponent interactions has been investigated by other groups. See for instance: (a) Kim, Y.; Lieber, C. M. Inorg. Chem. 1989, 28, 3990. (b) Osuka, A.; Nakajima, S.; Maruyama, K.; Mataga, N.; Asahi, T.; Yamazaki, L; Nishimura, Y.; Ohno, T.; Nozaki, K. J. Am. Chem. Soc. 1993, 115, 4577.
89. Closs, G. L.; Johnson, M D.; Miller, J. R.; Piotrowiak, P. J. Am. Chem. Soc. 1989, 111, 3751.
90. Giuffrida, G.; Campagna, S. Coord. Chem. Rev. 1994, 135/136, 517 and references therein.
91. Similar results were obtained with Phbpy tridentate environments: Constable. E. C.; Cargill Thompsom, A. M. W.; Greulich, S. J. Chem. Soc., Chem. Commun. 1993, 1444.