EPR spin-trapping evidence for the direct, one-electron reduction of tert-butylhydroperoxide to the tert-butoxyl radical by copper(II): Paradigm for a previously overlooked reaction in the initiation of lipid peroxidation

Journal of the American Chemical Society

Volumn 125, Issue 23, 2003, Pages 6946-6954

  Jones, Clare M ^a   Burkitt, Mark J ^a  

^a MOUNT VERNON HOSPITAL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

PEROXIDATION;

DECOMPOSITION; ELECTRON SPIN RESONANCE SPECTROSCOPY; FATTY ACIDS; LIPIDS; OXIDATION; REDUCTION; THERMODYNAMICS;

HYDROGEN PEROXIDE;

5,5 DIMETHYL 1 PYRROLINE 1 OXIDE; COPPER; COPPER COMPLEX; IRON COMPLEX; METAL CHELATE; RADICAL; TERT BUTOXYL RADICAL; TERT BUTYL HYDROPEROXIDE; TERT BUTYLPEROXYL ADDUCT; UNCLASSIFIED DRUG;

ACCELERATION; ARTICLE; CHELATION; CHEMICAL REACTION; DECOMPOSITION; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; FATTY ACID METABOLISM; LIPID PEROXIDATION; OXIDATION; REACTION ANALYSIS; REDUCTION; SPECTROSCOPY; THERMODYNAMICS;

COPPER; CYCLIC N-OXIDES; ELECTRON SPIN RESONANCE SPECTROSCOPY; FATTY ACIDS, UNSATURATED; FERROUS COMPOUNDS; FREE RADICALS; LIPID PEROXIDATION; OXIDATION-REDUCTION; SPIN LABELS; TERT-BUTYLHYDROPEROXIDE;

EID: 0038581843     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja034416z     Document Type: Article

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