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Volumn 24, Issue 20, 2005, Pages 4721-4728

Simultaneous observation of doubly and triply chloride bridged isomers of an electron-rich ruthenium dimer: Role of dimer geometry in determining reactivity

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CARBONYLATION; ISOMERS; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS; RUTHENIUM COMPOUNDS; X RAY CRYSTALLOGRAPHY;

EID: 26644455050     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050195p     Document Type: Article
Times cited : (13)

References (69)
  • 37
    • 26644458286 scopus 로고    scopus 로고
    • note
    • 6). Isomer 4a does not isomerize within 24 h in these solvents.
  • 41
    • 26644470756 scopus 로고    scopus 로고
    • note
    • 31P NMR singlet at 20 ppm. (Observation of this byproduct in aromatic solvents precludes assignment as a solvento species such as 5; vide infra.)
  • 42
    • 26644440611 scopus 로고    scopus 로고
    • note
    • 31P NMR chemical shift, which affords a useful spectroscopic handle for structural elucidation and assignment.
  • 48
    • 26644465032 scopus 로고    scopus 로고
    • note
    • 35 again pointing toward the thermodynamic stability of the face-bridged structural motif.
  • 50
    • 26644446650 scopus 로고    scopus 로고
    • note
    • The EXSY experiment also reveals site exchange between the inequivalent phosphines of 3c, probably owing to motion of the flexible dcypb backbone.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.